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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Laskar, Inamur Rahaman | - |
dc.date.accessioned | 2021-10-27T04:25:07Z | - |
dc.date.available | 2021-10-27T04:25:07Z | - |
dc.date.issued | 2017-04 | - |
dc.identifier.isbn | https://onlinelibrary.wiley.com/doi/10.1002/smll.201603780 | - |
dc.identifier.uri | http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/3122 | - |
dc.description.abstract | Aggregation-induced emission (AIE) is commonly observed in irregular bulk form. Herein, unique aggregation properties of an AIE-active complex into branched supramolecular wires are reported for the first time. Mono-cyclometalated Ir(III) complex shows in-plane J-aggregation at the air–water interface owing to the restriction of intramolecular vibration of bidentate phenylpyridinato and intramolecular rotations of monodentate triphenylphosphine ligands at air–water interface. As a consequence, a large enhancement of luminescence comparable to the solid state is obtained from the monolayers of supramolecular wires. This unique feature is utilized for the fabrication of light-emitting diodes with low threshold voltage using supramolecular wires as active layer. This study opens up the need of ordered assembly of AIE complexes to achieve optimal luminescence characteristics. | en_US |
dc.language.iso | en | en_US |
dc.publisher | Wiley | en_US |
dc.subject | Chemistry | en_US |
dc.subject | AIE-Active Mono-Cyclometalated Ir(III) | en_US |
dc.subject | Supramolecular Branched Wires | en_US |
dc.subject | Light-Emitting Diodes | en_US |
dc.title | Induced Aggregation of AIE-Active Mono-Cyclometalated Ir(III) Complex into Supramolecular Branched Wires for Light-Emitting Diodes | en_US |
dc.type | Article | en_US |
Appears in Collections: | Department of Chemistry |
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