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Please use this identifier to cite or link to this item: http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/3142
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dc.contributor.authorLaskar, Inamur Rahaman-
dc.date.accessioned2021-10-27T04:26:21Z-
dc.date.available2021-10-27T04:26:21Z-
dc.date.issued2004-08-
dc.identifier.urihttps://www.sciencedirect.com/science/article/pii/S1388248104001523?via%3Dihub-
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/3142-
dc.description.abstractElectrogenerated chemiluminescence (ECL) studies have been performed for the iridium(III) cyclometalated L2Ir(acac) complexes with substituted 2-phenylbenzothiazole ligand L. Electron transfer (ET) generation of the excited 3*L2Ir(acac) has been studied using a triple-potential-step technique in acetonitrile–dioxane (1:1) solutions containing 0.1 M (n-C4H9)4NPF6 as the supporting electrolyte. ET reactions between electrochemically generated L2Ir(acac)+ and A− (radical anions of aromatic nitriles) species lead to very efficient generation of ECL emission. Extremely high ECL efficiencies (up to 0.40) close to the excited 3*L2Ir(acac) luminescence yields have been found.en_US
dc.language.isoenen_US
dc.publisherElsieveren_US
dc.subjectChemistryen_US
dc.subjectElectrogenerated chemiluminescenceen_US
dc.subjectIridium complexesen_US
dc.subjectMLCT excited stateen_US
dc.titleElectrochemiluminescence studies of the cyclometalated iridium(III) complexes with substituted 2-phenylbenzothiazole ligandsen_US
dc.typeArticleen_US
Appears in Collections:Department of Chemistry

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