Cis–trans isomerism in nickel(II)–diamine nitrite: synthesis and single crystal structure of an unusual cis-dinitronickel(II) complex, [NiL2(NO2)2] (L=1,2-diamino-2-methylpropane)

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DC Field	Value	Language
dc.contributor.author	Laskar, Inamur Rahaman	-
dc.date.accessioned	2021-10-27T04:26:44Z	-
dc.date.available	2021-10-27T04:26:44Z	-
dc.date.issued	2000-04-30	-
dc.identifier.uri	https://www.sciencedirect.com/science/article/pii/S027753870000365X?via%3Dihub	-
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/3149	-
dc.description.abstract	The complexes [NiL3](NO2)2·2H2O (violet, 1) and cis-[NiL2(NO2)2]·0.5H2O (pink, 1b) (L=1,2-diamino-2-methylpropane) have been synthesized from solution. The X-ray single crystal structure analysis of compound 1b has been carried out, but the presence of a water molecule cannot be detected. Upon heating, complex 1b undergoes dehydration followed by an endothermic phase transition to produce trans-[NiL2(NO2)2] (1d). The violet species (1) also undergoes dehydration upon heating with deamination resulting (1d).	en_US
dc.language.iso	en	en_US
dc.publisher	Elsiever	en_US
dc.subject	Chemistry	en_US
dc.subject	Cis–trans isomerism	en_US
dc.subject	Crystal structures	en_US
dc.subject	1,2-Diamino-2-methylpropane	en_US
dc.title	Cis–trans isomerism in nickel(II)–diamine nitrite: synthesis and single crystal structure of an unusual cis-dinitronickel(II) complex, [NiL2(NO2)2] (L=1,2-diamino-2-methylpropane)	en_US
dc.type	Article	en_US
Appears in Collections:	Department of Chemistry

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