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Please use this identifier to cite or link to this item: http://dspace.bits-pilani.ac.in:8080/jspui/xmlui/handle/123456789/3163
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dc.contributor.authorKumar, Indresh-
dc.date.accessioned2021-10-27T04:27:24Z-
dc.date.available2021-10-27T04:27:24Z-
dc.date.issued2018-06-
dc.identifier.urihttps://pubs.acs.org/doi/10.1021/acs.joc.8b01232-
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/3163-
dc.description.abstractAn efficient protocol for the catalytic asymmetric synthesis of new dibenzo[b,f][1,4]-oxazepine-fused 1,2-dihydropyridines (DHPs) has been described under metal-free conditions. This reaction proceeds through proline-catalyzed direct Mannich/cyclization between seven-membered dibenzo[b,f][1,4]-oxazepine-imines and aqueous glutaraldehyde, followed by IBX-mediated site-selective dehydrogenative oxidation in one-pot operation with high yields (up to 92%) and excellent enantioselectivity (up to >99:1 er).en_US
dc.language.isoenen_US
dc.publisherACSen_US
dc.subjectChemistryen_US
dc.subjectCatalystsen_US
dc.subjectOxidationen_US
dc.subjectReaction productsen_US
dc.titleOne-Pot Synthesis of Chiral Tetracyclic Dibenzo[ b, f][1,4]oxazepine-Fused 1,2-Dihydropyridines (DHPs) under Metal-Free Conditionsen_US
dc.typeArticleen_US
Appears in Collections:Department of Chemistry

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