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http://dspace.bits-pilani.ac.in:8080/jspui/handle/123456789/3184| Title: | Proline catalyzed direct diastereoselective 6-enolexo aldolization: toward the synthesis of the imino sugar DNJ |
| Authors: | Kumar, Indresh |
| Keywords: | Chemistry Proline catalyzed Diastereoselective Synthesis |
| Issue Date: | Nov-2010 |
| Publisher: | Elsiever |
| Abstract: | A l-proline catalyzed direct diastereoselective 6-enolexo aldolization reaction of differentiating dialdehydes derived from tartaric acid is presented. This organocatalytic approach provides high levels of syn-selectivity (dr >10:1) with the stereocontrolled C–C bond formation between C4 and C5 intramolecularly, which can serve to synthesize imino-sugar skeleton quickly. |
| URI: | https://www.sciencedirect.com/science/article/pii/S0957416610007366?via%3Dihub http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/3184 |
| Appears in Collections: | Department of Chemistry |
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