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http://dspace.bits-pilani.ac.in:8080/jspui/xmlui/handle/123456789/3291| Title: | Facile β-Alkyl and β-Hydride Elimination in the Nickel-Catalyzed Annulation of o-Iodophenyl Ketones and Aldehydes with Bicyclic Alkenes |
| Authors: | Shukla, Paritosh |
| Keywords: | Chemistry Hydrocarbons Annulations Reaction products |
| Issue Date: | 26-May-2006 |
| Publisher: | ACS |
| Abstract: | o-Iodoaryl aldehydes react with bicyclic alkenes in the presence of NiBr2(dppe) and Zn powder in acetonitrile at 80 °C undergoing annulation to give polycyclic ketone derivatives. Surprisingly, o-iodoaryl alkyl ketones also react with bicyclic alkenes to form polycyclic ketones with structures the same as those from the corresponding o-iodoaryl aldehydes. |
| URI: | https://pubs.acs.org/doi/10.1021/ol061051p http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/3291 |
| Appears in Collections: | Department of Chemistry |
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