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http://dspace.bits-pilani.ac.in:8080/jspui/xmlui/handle/123456789/3293| Title: | Cyclization of Oxa-Bicyclic Alkenes with β-Iodo-(Z)-propenoates and o-Iodobenzoate Catalyzed by Nickel Complexes: A Simple Efficient Route to Annulated Coumarins |
| Authors: | Shukla, Paritosh |
| Keywords: | Chemistry Hydrocarbons Aromatic compounds Amides |
| Issue Date: | 2003 |
| Publisher: | ACS |
| Abstract: | In the presence of Ni(dppe)Br2 and Zn powder in acetonitrile at 80 °C, oxa-bicyclic olefins undergo cyclization with o-iodobenzoate and with β-iodo-(Z)-propenoates to give the benzocoumarin derivatives in moderate to good yields. This methodology offers a simple efficient way for the synthesis of structurally complicate coumarins in one pot. |
| URI: | https://pubs.acs.org/doi/10.1021/ol036027f http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/3293 |
| Appears in Collections: | Department of Chemistry |
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