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Please use this identifier to cite or link to this item: http://dspace.bits-pilani.ac.in:8080/jspui/xmlui/handle/123456789/3357
Title: Detection of Hg2+ ions in aqueous medium using an indole-based fluorescent probe: Experimental and theoretical investigations
Authors: Sakhuja, Rajeev
Pant, Debi D.
Keywords: Chemistry
Physics
Coumarin
Chemosensor
Fluorescence
Quenching
Issue Date: Dec-2017
Publisher: Elsiever
Abstract: Mercury pollution is a widespread danger to human health and environment. Due to limitations associated with the existing Hg2+ chemosensors, development of new, efficient and selective chemosensors capable of sensing mercury ions in aqueous medium remains a demanding area of research. In this regard, an indole-based fluorescent probe has been synthesized and characterized by detailed spectroscopic analysis. The probe showed a high selectivity and sensitivity towards Hg2+ by giving significant fluorescence quenching over other tested cations in H2O/DMF (7:3, v/v) medium. The association constant (Ka) was 6.4 × 103 M− 1 between sensor and Hg2+. The detection limit of sensor to Hg2+ was found to be 0.143 μM (143 nM). The experimental results have been verified with Density Functional Theory.
URI: https://www.sciencedirect.com/science/article/pii/S0167732217341867
http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/3357
Appears in Collections:Department of Chemistry

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