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Title: | An Articulate Oxidative Transition-Metal-Free Homocoupling of Imidazo Heterocycles through C(sp2)–C(sp2) Bond Formation |
Authors: | Sakhuja, Rajeev |
Keywords: | Chemistry Homocoupling Imidazo Heterocycles through C(sp2)–C(sp2) Bond Formation |
Issue Date: | 13-Mar-2017 |
Publisher: | Wiley |
Abstract: | Direct oxidative homocoupling of 2-arylimidazo heterocycles was achieved by using a phenyliodine diacetate-mediated BF3·OEt2-accelerated protocol at room temperature. A series of biimidazo heterocycles were synthesized under ambient conditions without prior activation of the C(sp2)–H bond. The desired biimidazo heterocycles were also obtained by using catalytic amounts of iodobenzene and m-CPBA/AcOH in an organocatalytic fashion. |
URI: | https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/ejoc.201700238 http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/3360 |
Appears in Collections: | Department of Chemistry |
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