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Please use this identifier to cite or link to this item: http://dspace.bits-pilani.ac.in:8080/jspui/xmlui/handle/123456789/3360
Title: An Articulate Oxidative Transition-Metal-Free Homocoupling of Imidazo Heterocycles through C(sp2)–C(sp2) Bond Formation
Authors: Sakhuja, Rajeev
Keywords: Chemistry
Homocoupling
Imidazo Heterocycles through C(sp2)–C(sp2)
Bond Formation
Issue Date: 13-Mar-2017
Publisher: Wiley
Abstract: Direct oxidative homocoupling of 2-arylimidazo heterocycles was achieved by using a phenyliodine diacetate-mediated BF3·OEt2-accelerated protocol at room temperature. A series of biimidazo heterocycles were synthesized under ambient conditions without prior activation of the C(sp2)–H bond. The desired biimidazo heterocycles were also obtained by using catalytic amounts of iodobenzene and m-CPBA/AcOH in an organocatalytic fashion.
URI: https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/ejoc.201700238
http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/3360
Appears in Collections:Department of Chemistry

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