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http://dspace.bits-pilani.ac.in:8080/jspui/xmlui/handle/123456789/3387| Title: | Carbene-Mediated Transformations of 1-(Benzylideneamino)benzimidazoles |
| Authors: | Sakhuja, Rajeev |
| Keywords: | Chemistry Crystals Adducts Anions |
| Issue Date: | 11-Apr-2011 |
| Publisher: | ACS |
| Abstract: | Carbene-mediated transformations of N-(3-butylbenzimidazol-3-ium-1-yl)-1-arylmethanimine iodides with carbon disulfide and benzoyl isothiocyanate gave the corresponding NHC·CS2 betaines in 68−85% and benzoyl-[1-butyl-3-[(E)-(aryl)methyleneamino]benzimidazol-1-ium-2-carbothioyl]azanides, respectively, in 74−85% yields. However, reaction with excess isopropyl isothiocyanate in NaH/THF at room temperature yielded the 1-butyl-1′,3′-diisopropyl-3-[(E)-(aryl)methyleneamino]spiro[benzimidazole-2,5′-imidazolidine]-2′,4′-dithiones (74−77%). |
| URI: | https://pubs.acs.org/doi/10.1021/jo200088s http://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/3387 |
| Appears in Collections: | Department of Chemistry |
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