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Please use this identifier to cite or link to this item: http://dspace.bits-pilani.ac.in:8080/jspui/xmlui/handle/123456789/3387
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dc.contributor.authorSakhuja, Rajeev-
dc.date.accessioned2021-11-11T11:01:58Z-
dc.date.available2021-11-11T11:01:58Z-
dc.date.issued2011-04-11-
dc.identifier.urihttps://pubs.acs.org/doi/10.1021/jo200088s-
dc.identifier.urihttp://dspace.bits-pilani.ac.in:8080/xmlui/handle/123456789/3387-
dc.description.abstractCarbene-mediated transformations of N-(3-butylbenzimidazol-3-ium-1-yl)-1-arylmethanimine iodides with carbon disulfide and benzoyl isothiocyanate gave the corresponding NHC·CS2 betaines in 68−85% and benzoyl-[1-butyl-3-[(E)-(aryl)methyleneamino]benzimidazol-1-ium-2-carbothioyl]azanides, respectively, in 74−85% yields. However, reaction with excess isopropyl isothiocyanate in NaH/THF at room temperature yielded the 1-butyl-1′,3′-diisopropyl-3-[(E)-(aryl)methyleneamino]spiro[benzimidazole-2,5′-imidazolidine]-2′,4′-dithiones (74−77%).en_US
dc.language.isoenen_US
dc.publisherACSen_US
dc.subjectChemistryen_US
dc.subjectCrystalsen_US
dc.subjectAdductsen_US
dc.subjectAnionsen_US
dc.titleCarbene-Mediated Transformations of 1-(Benzylideneamino)benzimidazolesen_US
dc.typeArticleen_US
Appears in Collections:Department of Chemistry

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