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Browsing by Author "Maccoll, Allan"

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Chlorine Kinetic Isotope Effects Thermal Decomposition of 1-Chlorocthane and Evaluation of Possible Models of Activated Complex

Maccoll, Allan; Mruzek, Margaret N. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12), 1978)

Chlorine kinetic isotope effects have been investigated for the pyrolysis of 1-chloroethane in a static system in the temperature range 395–482°C. The temperature dependence of the kinetic isotope effects has been determined. ...
Heavy Atom Kinetic Isotope Effects: Part 1.—Liquid Phase Decarboxylation of Malonic Acid

Loudon, Alexander G.; Maccoll, Allan; Smith, David (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (5), 1973)

The 13C/12C isotope effects in the decomposition of all the mono-13C malonic acid species have been determined. Three rate constant ratios have been determined, and two of these are in good agreement with the values recorded ...
Heavy Atom Kinetic Isotope Effects: Part 2.—Nitrogen Isotope Effects in the Decomposition of Aqueous Aromatic Diazonium Salts

Loudon, Alexander G.; Maccoll, Allan; Smith, David (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (5), 1973)

The rate constant ratio l4k/l5k was determined for the decomposition of some diazonium fluoro- borates in aqueous solution in both the presence and absence of added salts. The implications of the results for the mechanism ...
Homogeneous Gas Phase Pyrolysis of 7V-t-Butylacetamide

Maccoll, Allan; Nagra, Surgit S. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (6), 1973)

The kinetics of the gas phase pyrolysis of N-t-butylacetamide have been studied in a static system over the temperature range 385–465°C. The decomposition occurs by two simultaneous, homogeneous and unimolecular processes. ...

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