The reaction of fluorine with CCl3F has been studied over the temperature range 491–586 K. The mechanism is identical to that found in Pyrex vessels except that the reaction is now a homogeneous gas phase one. The rate ...

Kinetic isotope effects for the hydrogen abstraction reactions of fluorine atoms with H2, CH and CHC13 have been measured by indirect competitive methods. The relative rate constants arc given by, The result for A(H2)/A(D2) ...