Abstract:
The theory of finite-strain elasticity is applied to the phenomenon of cavitation observed in polymer gels following liquid-liquid phase separation of the solvent, which opens a fascinating window on the role of finite-strain elasticity theory in soft materials in general. We show that compressibility effects strongly enhance cavitation in simple materials that obey neo-Hookean elasticity. On the other hand, cavitation phenomena in gels of flexible polymers in a binary solvent that phase separates are surprisingly similar to those of incompressible materials. We find that, as a function of the interfacial energy between the two solvent components, there is a sharp transition between cavitation and classical nucleation and growth. Next, biopolymer gels are characterized by strain hardening and even very low levels of strain hardening turn out to suppress cavitation in polymer gels that obey Flory-Huggins theory in the absence of strain hardening. Our results indicate that cavitation is, in essence, not possible for polymer networks that show strain hardening.