dc.contributor.author |
Dalvi, Anshuman |
|
dc.date.accessioned |
2024-01-25T09:01:43Z |
|
dc.date.available |
2024-01-25T09:01:43Z |
|
dc.date.issued |
2017-11 |
|
dc.identifier.uri |
https://www.sciencedirect.com/science/article/pii/S016727381730365X |
|
dc.identifier.uri |
http://dspace.bits-pilani.ac.in:8080/jspui/xmlui/handle/123456789/13984 |
|
dc.description.abstract |
Structural, thermal and electrical transport in PEO-LiCF3SO3 solid polymer electrolyte dispersed with Li+-NASICON crystallites has been assessed. Fine submicron crystallites of LiTi2(PO4)3 (LTP) were added in appropriate amount during solution casting of the polymer films. Thus the compositions 95[PEO1 − x-LTPx]-5LiCF3SO3 have been synthesized for a wide range of LTP content (x = 0–0.9). Electrical conductivity increases with LTP content monotonically. Highest room temperature conductivity of ~ 7 × 10− 5 Ω− 1 cm− 1 has been obtained for the sample with x = 0.9 of LTP which is ~ 43 times higher than that of the sample with no LTP content. FE-SEM investigations performed on pellets with higher LTP content suggest uniform distribution of LTP particles in the polymer matrix. Preliminary investigations reveal that mechanism of electrical transport in SPE-LTP hybrid composites is greatly influenced by LTP content. |
en_US |
dc.language.iso |
en |
en_US |
dc.publisher |
Elsevier |
en_US |
dc.subject |
Physics |
en_US |
dc.subject |
Solid polymer electrolytes |
en_US |
dc.subject |
Ionic conductivity |
en_US |
dc.subject |
Polymer composite |
en_US |
dc.subject |
Filler addition |
en_US |
dc.title |
Li+-NASICON crystallites in PEO-LiCF3SO3 matrix: Characterization of a novel hybrid electrolyte |
en_US |
dc.type |
Article |
en_US |