Asymmetrically β-Substituted Porphyrins and Chlorins: Synthesis, Spectroscopic, and Electrochemical Redox Properties

dc.contributor.author	Grover, Nitika
dc.date.accessioned	2024-08-10T05:21:31Z
dc.date.available	2024-08-10T05:21:31Z
dc.date.issued	2015
dc.identifier.uri	https://iopscience.iop.org/article/10.1149/06616.0011ecst
dc.identifier.uri	http://dspace.bits-pilani.ac.in:8080/jspui/xmlui/handle/123456789/15198
dc.description.abstract	Asymmetrically β-substituted chlorins, viz. 2,3-bis(dicyanomethyl)-meso-tetraphenylchlorin (1), diethoxycarbonylcyclopropano-meso-tetraphenylchlorin (2) and 2-ethylacetoacetanato-meso-tetraphenylporphyrin (3), and their metal (Ni(II), Cu(II) and Zn(II)) complexes have been synthesized and characterized by various spectroscopic techniques. Cyclic voltammetric (CV) studies were carried out for these porphyriniods in CH2Cl2 containing TBAPF6 as supporting electrolyte. The first ring redox potentials of 1, 2 and their metal complexes are anodically shifted (0.58 - 0.30 V) as compared to meso-tetraphenylchlorin (H2TPC) due to electron withdrawing nature of malononitrile and diethyl malonate substituents. Notably, Ni(II) complex of 3 exhibited metal centered oxidation (NiII/NiIII) due to extended conjugation and electronic nature of β-subtituent.	en_US
dc.language.iso	en	en_US
dc.publisher	IOP	en_US
dc.subject	Chemistry	en_US
dc.subject	Porphyrins	en_US
dc.subject	Chlorins	en_US
dc.subject	Synthesis	en_US
dc.subject	Spectroscopic	en_US
dc.title	Asymmetrically β-Substituted Porphyrins and Chlorins: Synthesis, Spectroscopic, and Electrochemical Redox Properties	en_US
dc.type	Article	en_US

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