| dc.contributor.author | Kumar, Anil | |
| dc.date.accessioned | 2024-09-11T03:50:37Z | |
| dc.date.available | 2024-09-11T03:50:37Z | |
| dc.date.issued | 2021-11 | |
| dc.identifier.uri | https://pubs.acs.org/doi/10.1021/acs.joc.1c02202 | |
| dc.identifier.uri | http://dspace.bits-pilani.ac.in:8080/jspui/xmlui/handle/123456789/15517 | |
| dc.description.abstract | A series of indolyl or imidazo[1,2-a]pyridinyl-substituted para-quinone methides (p-QMs) is prepared by a metal-free, TEMPO-mediated cross-dehydrogenative coupling of butylated hydroxytoluene (BHT) with indoles or imidazo[1,2-a]pyridines in good to high yields. Broad substrate scope with respect to indoles and imidazo[1,2-a]pyridines, good functional group tolerance, and acid/base-free conditions are advantageous feature of the developed protocol. The method was amenable for scale-up on the gram scale. Based on control experiments, a reaction mechanism is proposed to describe this transformation. | en_US |
| dc.language.iso | en | en_US |
| dc.publisher | ACS | en_US |
| dc.subject | Chemistry | en_US |
| dc.subject | Column chromatography | en_US |
| dc.subject | Gels | en_US |
| dc.subject | Indoles | en_US |
| dc.subject | Mixtures | en_US |
| dc.subject | Silica Nanoparticles (SiNP) | en_US |
| dc.title | TEMPO-Mediated Synthesis of Indolyl/Imidazo[1,2-a]pyridinyl-Substituted para-Quinone Methides from Butylated Hydroxytoluene | en_US |
| dc.type | Article | en_US |
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