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Electrochemical Synthesis of 2-Aryl-3-(2-aminoaryl)quinoxalines via Oxidative Dearomatization/Ring-Opening/Cyclization Cascade Sequence of 2-Arylindoles with 1,2-Diaminoarenes

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dc.contributor.author Kumar, Indresh
dc.date.accessioned 2024-09-12T04:10:42Z
dc.date.available 2024-09-12T04:10:42Z
dc.date.issued 2023-07
dc.identifier.uri https://pubs.acs.org/doi/10.1021/acs.joc.3c01092
dc.identifier.uri http://dspace.bits-pilani.ac.in:8080/jspui/xmlui/handle/123456789/15541
dc.description.abstract A straightforward method has been developed to synthesize 2-aryl-3-(2-aminoaryl) quinoxalines from 2-arylindoles and 1,2-diaminoarenes under mild electrochemical conditions. The reaction proceeds through in situ generations of 2-arylindole-3-ones under electrochemical oxidative dearomatization of 2-arylindoles, followed by a ring opening-cyclization sequence with 1,2-diaminoarenes. A series of 2-aryl-3-(2-aminoaryl) quinoxalines have been prepared with moderate to good yields (up to 75%). en_US
dc.language.iso en en_US
dc.publisher ACS en_US
dc.subject Chemistry en_US
dc.subject Atmospheric chemistry en_US
dc.subject Electrochemical synthesis en_US
dc.subject Electrodes en_US
dc.subject Fossil fuels en_US
dc.subject Purification en_US
dc.title Electrochemical Synthesis of 2-Aryl-3-(2-aminoaryl)quinoxalines via Oxidative Dearomatization/Ring-Opening/Cyclization Cascade Sequence of 2-Arylindoles with 1,2-Diaminoarenes en_US
dc.type Article en_US


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