• Interaction of Oxygen with Zinc Surfaces 

  Bickley, Roger I.; Metcalfe, Leonard P. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (04), 1978)

  The interaction of oxygen with clean zinc surfaces has been investigated in the temperature range 78-493 K. Oxygen incorporation occurs extensively at 78 K, the limiting uptake being equivalent to ~ 6 monolayers of oxygen. ...
• Partial Molar Volumes of Organic Compounds in Water: Part 4.—Aminocarboxylic Acids 

  Shahidi, Fereidoon; Farrell, Patrick G. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (04), 1978)

  The partial molar volumes of the a,a>-aminocarboxylic acids up to 11-aminoundecanoic acid, together with those of a number of cyciopentane and cyclohexane analogues, have been measured in water at 25'C, and related to their ...
• Capillary Phenomena: Part 6—Behaviour Associated with the Flotation and Mechanical Manipulation of Solid Spheres at Fluid Interfaces 

  Boucher, Ernest A.; Kent, Henry J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (04), 1978)

  Solid sphere behaviour at the interface between two immiscible fluids will depend on whether or not it can float unaided, or, on the type of device used to manipulate it by an applied force. A thermodynamic treatment is ...
• Activity Coefficients for the System HCl+BaCl2+H2O at 298.15 K: Comparison of Scatchard’s and Pitzer’s Interpretations 

  Khoo, Kean H.; Chan, Chee-Yan; Lim, Tiong-Koon (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (04), 1978)

  Activity coefficients of hydrochloric acid in aqueous solutions of barium chloride have been measured at 298.15 K at constant total ionic strengths of 0.1, 0.5, 1.0, 2.0 and 3.0 mol kg-1 using hydrogen-silver-silver chloride ...
• Electron Transfer from Aromatic Molecules to Dimethylmercury via a Triplet Exciplex 

  Donckt, E. Vander; Vooren, C. Van (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (04), 1978)

  Whereas low concentrations of added dimcthylmcrcury [0 < (DMM) < 0.1-1 mol dm-3] increase the intersystem crossing rates of electronically excited aromatic molecules, higher concentrations of the fluorescence quencher ...
• Recoil Tritium Reactions with CH3SiD3: Pressure Dependent Yields 

  Volpe, Paolo; Casuglion, Mario (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (04), 1978)

  The T + CH3S1D3 system has been studied to evaluate the effect of reactant pressure on parent-T yield. The substitution yields for C—H and Si—D bonds have been found to be in the ratio 1 : 1.7. The decomposition rate of ...
• Energy Distribution and Mechanism in 3-Chloro-3-methyldiazirine Photolysis 

  Figuera, Juan M.; Perez, Juan M.; Tobar, Aurora (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (04), 1978)

  Gas-phase photolysis of pure 3-chloro-3-methyldiazirine over a wide range of pressure (133- 1.015 x 105 N m~2) was performed at 334 and 313 nm. The reaction produces “ hot ” vinyl chloride with enough energy to subsequently ...
• Structural Analysis of Some Molten Materials by X-ray Diffraction: Part 3.—MnCl2 

  Ohno, Hideo; Furukawa, Kazuo; Tanemoto, Kei; Tagaki, Yoshiki; Nakamura, Tetsuro (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (04), 1978)

  The structure of molten MnCl2 has been examined by consideration of the radial distribution function. The nearest Mn-Cl distance is 2.51 A and the coordination number of manganese is 4.0. An f.c.c. structural model with ...
• Structural Analysis of Some Molten Materials by X-ray Diffraction: Part 2.—Li2SO4, Na2SO4 and the Mixed System 

  Ohno, Hideo; Furukawa, Kazuo (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (04), 1978)

  The structures of molten Li2SO4, Na2SO4 and their mixtures have been examined by co nsideration of the radial distribution function and the molar volume. The existence of tetrahedral su phate ions in these molten salts has ...
• Flow Equation for Coagulated Suspensions 

  Cooper, Peter G.; Rayner, John G.; Nicol, Stuart K. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (04), 1978)

  From analysis of the coagulation-redispcrsion kinetics of a sheared suspension an equation for the viscosity at any shear rate is developed. The use of an analogy with chemical reaction kinetics attributes some physical ...
• Cyclisation in the Gas Phase Photolysis of Neopentyl Bromide 

  Bayliss, Stuart G.; Failes, Robert L.; Shapiro, Jacob S. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (04), 1978)

  Gas phase photolysis of neopentyl bromide was studied over the temperature range 478-564 K. The major products were hydrogen bromide, 1,1-dimethylcyclopropane, with smaller amounts of methylbutenes and neopentane. Above ...
• Rate Constants for the Removal of Radicals at the Wall in Linearly Branched or Terminated Chain Reactions 

  Blackmore, David R. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (04), 1978)

  The effect of the removal of radicals by the wall is described for reacting systems linear in radical concentration. Exact expressions are derived for the surface rate constant ksurf, defined in terms of the mean radical ...
• Study of Surface Atom Behaviour on Pt/SiO2 and Pt/Al2O3 Catalysts by Isotopic Exchange of Oxygen from CO2 

  Ducarme, Valentin; Vedrine, Jacques C. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (02), 1978)

  Isotopic exchange of oxygen from CO2 was used to study and characterize the lability of oxygen species at the surface of a catalyst. The catalysts were Pt supported on silica or alumina with several Pt loadings. Pt dispersion ...
• Role of Breasted Acid Centres for Alkene Double Bond Migration over Alumina at Temperatures above 450 K 

  John, Christopher S.; Tada, Akio; Kennedy, Lois V. F. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (02), 1978)

  Water was added to alumina samples following their activation in vacuo at both 723 and 1023 K. Reactions of [2Ho]propene and of CD2=CH—CH2 were then studied on these catalysts. Adsorption of water (2.7 x 1018 molecule m-2) ...
• Diffusion in Binary Liquid Mixtures of non Electrolytes 

  Barrie, James A.; Dawson, Ray B.; Sheppard, Richard N. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (02), 1978)

  Self diffusion coefficients at 25 'C for octamethylcyclotetrasiloxanc in binary mixtures with benzene and carbon tetrachloride have been measured by pulsed field gradient pulsed n.m.r. A comparison is made of the diffusion ...
• Stability Constants for Cadmium Iodide Complexes in Aqueous Cadmium Iodide (298.15 K) 

  Lutfullah; Paterson, Russell (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (02), 1978)

  In order to interpret the transport properties of aqueous cadmium iodide, the concentrations of free ions and complexes (CdU'n; n = 1,2, 3,4) were required. For this method the method of Reilly and Stokes was used. ...
• Location of Cations in Synthetic Zeolites-X and -Y: Part 6.—Influence of X-ray Irradiation on the Location of Exchangeable Cations 

  Costenoble, Martin L.; Mortier, Wilfried J.; Uytterhoeven, Jan B. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (02), 1978)

  The X-ray irradiation of a scries of Ca- and La-Y zeolites, pretreated at different temperatures results in the formation of oxides (CaO and La2O3) in the sodalite cage, and in a depopulation of the hexagonal prisms. The ...
• Thermal Stability and Chemical Reactivity of (02-)s Species Adsorbed on MgO Surfaces 

  Cordischi, Dante; Indovina, Valerio; Occhiuzzi, Manlio (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (02), 1978)

  The thermal stability and the chemical reactivity of (O2)s species adsorbed on a MgO surface have been studied by e.s.r. spectroscopy over a wide range of experimental conditions. The (O2)s radicals (0.4-3.3 x 1015 spins ...
• Viscoelectric Coefficient for Water 

  Hunter, Robert J.; Leyendekkers, J. V. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (02), 1978)

  An estimate is made of the viscoelectric coefficient of water from measurements of the viscosity of water retained between parallel sheets of montmorillonite at various separations. The observed results can be explained ...
• X-ray Photoelectron Spectroscopy Study of Pd and Pt Ions in Type Y-Zeolite: Electron Transfer between Metal Aggregates and the Support as Evidenced by X-ray Photoelectron Spectroscopy and Electron Spin Resonance 

  Vedrine, Jacques C.; Dufaux, Michel; Naccache, Claude; Imelik, Boris (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (02), 1978)

  Spectroscopic study by ESCA and e.s.r. techniques was performed for Pt and Pd ions in type Y-zeolites. Pt and Pd ions were found to be ionically bonded to lattice oxygen ions. Atomically dispersed PtO and Pd° were shown ...

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