Journal Archive Collections: Recent submissions

  • Quenching of Pyrene Sulphonate Fluorescence in Inverse Micelles 
    Miller, Dennis J; Klein, Uwe K. A; Hauser, Manfred (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (10), 1977)
    The fluorescence of 1-pyrene sodium sulphonate solubilised in benzene solutions of cetylbenzyl-dimethylammonium chloride/bromide is quenched by the bromide. The quenching constant is not markedly affected by the addition ...
  • Alternative to the Elovich Equation for the Kinetics of Adsorption of Gases on Solids 
    Ritchie, A. G. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (10), 1977)
    The Elovich equation has long been used to describe the kinetics of adsorption of gases on solids. It is shown here that many results which have been fitted to this equation can be more satisfactorily described in terms ...
  • Effect of Ethylene and Hydrogen Adsorption on the E.S.R. Spectra of Chromia-Alumina Catalysts 
    Ashmawy, Fathy M.; Steiner, Herbert M. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (10), 1977)
    The surface chemistry of Cr2+ and Cr3+ in chromia–alumina catalyst is investigated. Electron spin resonance studies revealed considerable changes in the behaviour of the signals ascribed to Cr3+(at g= 1.986) when exposed ...
  • Response of the Belousov-Zhabotinskii Oscillating Reaction to Addition of either Bromide or Cerium(IV) Ions 
    Blandamer, Michael J.; Roberts, David L (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (10), 1977)
    When the Belousov–Zhabotinskii oscillating reaction is perturbed by rapid addition of bromide ions, the oscillations disappear but then recover. The time taken for this recovery depends on the extent of concentration ...
  • Kinetics and Mechanism of the Quatemization of Poly(4-vinyl pyridine) with Ethyl, n-Propyl, n-Butyl, n-Hexyl and Benzyl Bromide in Sulpholane 
    Boucher, Ernest A.; Groves, John A.; Mollett, Christopher C.; Fletcher, Peter W. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (10), 1977)
    Kinetic results for quaternization reactions of four n-alkyl bromides (C2, C3, C4, C6) and benzyl bromide, with poly(4-vinyl pyridine) in sulpholane, at a variety of concentrations and temperatures, have been analysed ...
  • Proton Chemical Shifts of Hydrogen Bonded Complexes of Acetic Acid Electric Field Calculations for the Monomer-Dimer Shift and for Complexes with Fluoride or Acetate Anions 
    Akitt, J. W. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (10), 1977)
    The permanent electric moments and the mutual polarisation of two acetic acid molecules in the dimer configuration are sufficient to account for the gas phase 1H association shift of the hydroxyl proton. A cyclic trimer ...
  • Water in Homoionic and Heteroionic Mordenites. A Calorimetric Study Part 1.—Alkali and Alkaline Earth Metal Forms 
    Coughlan, Brendan; Carroll, William M.; McCann, William A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (10), 1977)
    Heats of immersion in liquid water of Na-Zeolon exchanged with alkali metal, alkaline earth, Ag+, Ti+ and Pb2+ ions are reported. The levels of ion exchange of Zeolon are shown to depend markedly on the degree of hydration ...
  • Dielectric Properties of Hydrated Proteins at 9.9 GHz 
    Bone, Stephen; Gascoyne, Peter R. C.; Pethig, Ronald (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (10), 1977)
    The complex dielectric permittivities of bovine serum albumin, cytochrome-c and lysozyme powders have been measured as a function of partial hydration at 9.9 GHz using a microwave cavity perturbation technique. By analysing ...
  • Determination of the Active Site and Mechanism for Alkene Isomerization in Cun Exchanged Y-Type Zeolite 
    John, Christopher S.; Leach, H. Frank (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (10), 1977)
    Reactions of CD2[double bond, length as m-dash]CH—CH3, but-1-ene and 3,3-dimethylbut-1-ene have been studied over a Y-type zeolite containing ∼4 CuII per unit cell. Kinetic induction periods, associated with the generation ...
  • Enthalpies of combustion of tris-(acetylacetonato) derivatives of aluminium(III), gallium(III) and indium(III) 
    Cavell, Kingsley J; Pilcher, Geoffrey (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (10), 1977)
    The enthalpies of combustion of the following tris-(acetylacetonato) derivatives have been measured and the standard enthalpies of formation at 298.15 K derived. –ΔH°c/kJ mol–1–ΔH°f/kJ mol–1 Al(C5H7O2)3(c) 7948.4 ± 1.1 ...
  • Inoperative Protonic Sites in Highly Exchanged L-Zeolites 
    Ballivet, Danielle; Barthomeuf, Denise (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (10), 1977)
    It has been shown that highly exchanged L zeolites have hydroxyls vibrating at 3740, 3730, 3680 and 3630 cm–1 and a large number of strongly interacting hydroxyls. The structural 3630 cm–1 hydroxyls, stable under the ...
  • Thermodynamics of Liquid Mixtures of Methane and Ethene 
    Calado, Jorge C. G.; Soares, VirgIlio A. M. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (09), 1977)
    The total vapour pressure of liquid mixtures of methane and ethene has been measured as a function of composition at 103.94 and 115.77 K. The results have been used to estimate the excess Gibbs energy GE at these temperatures. ...
  • Activities of Olefinic Derivatives as Components of Photoinitiating Systems based on Transition-Metal Carbonyls 
    Bamford, Clement H.; Mullik, S. U. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (09), 1977)
    The derivatives studied include carboxyl- and nitrile-substituted ethylenes, perfluoro-propylene, -butadiene, -benzene and -styrene, 1,1-difluoro-2,2-dichloroethylene and several chloroethylenes. The activity of each ...
  • Exchange of Alkylammonium Ions in the Zeolite-L 
    Vansant, Etienne F; Peeters, Guido (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (10), 1977)
    A study has been made of the ion-exchange equilibria of NH+4, CH3NH+3, C2H5NH+3, n-C3H7NH+3, n-C4H9NH+3, (CH3)2NH+2, (CH3)3NH+, (C2H5)2NH+2 and (C2H5)3NH+ by the zeolite L. None of the alkylammonium ions could effect a ...
  • Photochemistry of Michler’s Ketone in Cyclohexane and Alcohol Solvents 
    Brown, Robert G; Porter, Sir George (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (10), 1977)
    The triplet lifetime of Michler's ketone has been measured in cyclohexane, isopropanol and ethanol and has been found to vary only slightly between solvents. In the light of these results, the photoreactivity of the ketone ...
  • Interaction of Duroquinone Lowest Triplet with Amines 
    Amouyal, Edmond; Bensasson, Rene (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (10), 1977)
    The reaction of the lowest triplet of duroquinone, 3Q, with tertiary amines (triethylamine TEA, diethylaniline DEA, triphenylamine TPA) has been investigated by laser flash absorption spectroscopy in non-polar (cyclohexane ...
  • I.r. Spectroscopic Study of CO2 Adsorption onto q-Al2O3 
    Morterra, Claudio; Zecchina, Adriano; Coluccia, Salvatore; Chiorino, Anna (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (10), 1977)
    The adsorption of CO2 at room temperature onto η–Al2O3 dehydrated at various temperatures between 25 and 800°C was studied by i.r. and microgravimetric techniques. The following surface species are formed; three σ-coordinated ...
  • Oxidation of 1-Phenylethanol in the Presence of Cobalt Acetylacetonates 
    Vasvari, Gabor; Gal, Dezso (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (10), 1977)
    The oxidation of 1-phenylethanol has been investigated in the presence of Co(acac)2 and Co(acac)3. It is established that in the presence of Co(acac)2 the oxidation is preceded by the formation of a Co(acac)2—ROH complex ...
  • Absolute Rate of the Reaction of C1(2P) with Molecular Hydrogen from 200-500 K 
    Lee, Jai H.; Michael, Joe V; Payne, Walter A.; Stiee, Louis J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (10), 1977)
    Rate constants for the reaction of atomic chlorine with hydrogen have been measured from 200–500 K using the flash photolysis–resonance fluorescence technique. The rate constants obey the Arrhenius equation k=(2.66 ± 0.42)× ...
  • Infrared Study of the Adsorption of Water on to the Surface of Rutile 
    Griffiths, David M; Rochester, Colin H. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (10), 1977)
    Infrared spectra of the surface of three samples of rutile which had been (a) calcined in air at 723 K and heated in oxygen at 673 K, (b) calcined in air at 973 K and heated in oxygen at 673 K, and (c) calcined in air at ...

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