Journal Archive Collections: Recent submissions

  • Critical Reflection of Neutrons A New Technique for Investigating Interfacial Phenomena 
    Hayter, J. B; Highfield, R. R; Pullman, B. J (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1981, 77 (06), 1981)
    The possibility of using neutron critical reflection for investigating interfacial phenomena is assessed. Calculations of the reflectivity of neutrons as a function of angle of incidence have been made for a variety of ...
  • Triplet State of 5-Nitro-2-furoic acid by Laser Flash Photolysis Spectrum, Lifetime and Reactivity 
    Kemp, Terence J; Martins, Luis J. A (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1981, 77 (06), 1981)
    Nanosecond laser flash photolysis (347.1 nm) of 5-nitro-2-furoic acid (NFA) in both polar and non-polar solvents at 295 K shows a transient absorption centred at 490 ± 5 nm with εca. 2 × 104 dm3 mol–1 cm–1 which is assigned ...
  • Adsorption of Methane + Ethane and Methane +Carbon Monoxide on Molecular Sieves 
    Veyssiere, Marie-Claude; Clavaud, Christian; Cartraud, Pierre; Cointot, Andre (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1981, 77 (06), 1981)
    Experimental sorption isotherms are obtained for methane, ethane and carbon monoxide in three molecular sieves (two zeolitic and one carbon). Pressures from a few millibar absolute to as high as 30 bar are covered. Sorption ...
  • Kinetic Studies of Photoinduced Methyl Viologen Reduction with Ruthenium Complexes and Hydrogen Evolution from Water by Hydrogenase 
    Okura, Ichiro; Kim-Thuan, Nguyen (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1981, 77 (06), 1981)
    Highly active photoinduced systems for methyl viologen reduction have been developed by using ruthenium complexes with long lifetimes in the photoexcited state. The order of activities is as follows: Ru(dime-phen)2+3 > ...
  • Study of Charge-transfer Interaction in Biomolecules 
    Lahiri, Jyotirmay; Basu, Rama (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1981, 77 (06), 1981)
    The interaction of the antibiotic drugs tetracycline and oxytetracycline with purines, pyrimidines and amino acids were studied spectrophotometrically in water, ethylene glycol and propylene glycol. In each case a new ...
  • Cooperative Interactions and Two-dimensional Ordering in the Adsorption of HBr on KBr 
    Harrison, Lionel G; Koga, Yoshikata; Lassau, Troy (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1981, 77 (06), 1981)
    Adsorption isotherms of HBr gas on high surface area KBr have markedly non-ideal shapes. These are analysed using a two-layer model with repulsive interactions between molecules in the first layer. An earlier report from ...
  • Vapour-phase Exciplex Formation between 1,4-Dicyanonaphthalene and 2,5-Dimethyl-2,4-hexadiene 
    Abbott, Geoffrey D; O’CoNNOR, Desmond V; Phillips, David (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1981, 77 (06), 1981)
    Fluorescence has been observed from the exciplex formed between electronically excited 1,4-dicyanonaphthalene and 2,5-dimethyl-2,4-hexadiene in the vapour phase and the kinetics of exciplex formation studied. The enthalphy ...
  • Adsorption of Binary Gas Mixtures in Ion-exchanged Forms of Mordenite 
    Vansant, Etienne F; Voets, Raf (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1981, 77 (06), 1981)
    Pure-component adsorption isotherms of CO, CO2, N2 and CH4 and multicomponent isotherms of CO + CO2, CO2+ N2 and CO2+ CH4 on mordenite were measured at 273, 258 and 243 K. No evidence of enhanced sorption of one component ...
  • Theory of Compartmentalised Free-radical Polymerisation Reactions Part 5 
    Birtwistle, David T; Blackley, David C (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1981, 77 (06), 1981)
    An iterative procedure has been developed for the numerical solution of the exact Smith–Ewart differential difference equations for a compartmentalised free-radical polymerisation reaction in the non-steady state. The ...
  • Solute Interactions in Dilute Aqueous Solutions Part 4.—Microcalorimetric Study of Ternary Mixtures of Urea and Hydrophobic Species 
    Franks, Felix; Pedley, Michael D (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1981, 77 (06), 1981)
    Heats of dilution of urea, acetone, ethylmethyl ketone and tetrahydrofuran, and heats of mixing of urea with each of the other solutes have been measured at 25°C; the urea + acetone system was also studied at 5°C. The ...
  • Isotopic Exchange of Deuterium in Zeolites 
    Novakova, Jana; Kubelkova, Ludmila; Jíru, Pavel (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1981, 77 (06), 1981)
    The information obtainable from the study of deuterium isotope exchange in zeolites by i.r. and m.s. methods is discussed. The conditions necessary for high sensitivity determination of OH groups by gas-phase analysis are ...
  • Comparative Study of Copper and Nickel Surfaces for the Decomposition of Methanol using Ultraviolet Photoelectron Spectroscopy 
    Kojima, Isao; Sugihara, Hiroshi; Miyazaki, Eizo; YASUMORI, IWAO (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1981, 77 (06), 1981)
    Ultraviolet photoelectron spectroscopy has been used in a comparative study of the catalytic properties of copper and nickel surfaces. Adsorption and decomposition of carbon monoxide, methanol, formaldehyde and methyl ...
  • Adsorption of Butenes on NaY and Dehydroxylated Y Zeolites Studies by Infrared Spectroscopy 
    Datka, Jerzy (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1981, 77 (06), 1981)
    Butene molecules adsorbed on NaY and dehydroxylated Y zeolites are bonded to electrophilic acid sites (Na+ ions or Lewis-acid sites) by their π electrons. The interaction of butene molecules with Lewis-acid sites results ...
  • Kinetics of Fatty Acid Adsorption from Non-aqueous Solutions onto Metal Surfaces Part 2.—Dilinoleic Acid 
    Dacre, Brian; Savory, Barbara; Wheeler, Phillip A (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1981, 77 (06), 1981)
    The kinetics of adsorption ofthe thermal dimer oflinoleic acid from dodecane onto three metal surfaces have been examined. The rate of desorption of the surface species into pure dodecane has also been investigated. A ...
  • Kinetics of Fatty Acid Adsorption from Non-aqueous Solutions onto Metal Surfaces Part 1.—Linoleic Acid 
    Dacre, Brian; Wheeler, Phillip A (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1981, 77 (06), 1981)
    The kinetics of adsorption of linoleic acid from dodecane onto three metal surfaces have been examined. Desorption into pure solvent has also been investigated. A Langmuir and a more general model have been formulated to ...
  • Application of Excess Adsorption Data Measured for Components of the Mobile Phase for Characterizing Chromatographic Systems 
    Jaroniec, Mieczyslaw; Oscik-Mendyk, Barbara (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1981, 77 (06), 1981)
    An analytical equation for the capacity ratio of a chromatographed substance in a multicomponent mobile phase, involving energetic heterogeneity of the adsorbent surface and differences in the molecular areas of solute and ...
  • Mass Action Kinetics and Equilibria of Reversible Aggregation 
    Bentz, Joe; Nir, Shlomo (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1981, 77 (06), 1981)
    The kinetics and equilibrium of particle aggregation are studied using the general mass action model. In this approach, the reversibility of aggregation is treated explicitly and yields a direct calculation of the equilibrium ...
  • Enthalpies of Solute Transfer into Nematic MBBA Long-range Disturbance of Order 
    Croucher, Melvin D; Patterson, Donald (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1981, 77 (06), 1981)
    Enthalpies, ΔHs(T → N), have been obtained at 25°C for the transfer of solute molecules (S) from a reference solvent toluene (T) into nematic (N)p-methoxybenzylidine-p-n-butyl-aniline (MBBA). Solutes include the normal ...
  • Molecular Structure and Orientational Order Effects in Enthalpies and Heat Capacities of Solute Transfer into n-C16 Part 1.—Normal and Branched Alkane Solutes 
    Kronberg, Bengt; Patterson, Donald (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1981, 77 (06), 1981)
    Enthalpies ΔH(b → n) and heat capacities ΔCp(b → n) have been obtained at 25°C for the transfer of solute molecules into normal-C16(n) from the highly-branched-C16, 2,2,4,4,6,8,8,-heptamethylnonane (b). Solutes include ...
  • Dipole Moments and Spectral Features of Some Phenol-Diethylamine Complexes 
    Oszust, Jadwiga; Ratajczak, Henryk (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1981, 77 (06), 1981)
    The dipole moments of molecular complexes of two types, AB and A2B2, formed between phenol derivatives with diethylamine in benzene solution have been determined. The polarity of the hydrogen bond, Δµ, in AB complexes ...

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