Journal Archive Collections: Recent submissions

  • Interpretation of the “Intermediate Frequency” Dielectric Spectra of Synthetic Zeolites X 
    Ravalitera, Guy; Carru, Jean-Claude; Chapoton, Alain (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (06), 1977)
    The dielectric spectra of synthetic zeolites X (13X and 10X) were studied in the frequency range 1 Hz-4 GHz at T=+ 25°C on samples hydrated at various rates. They all showed a distributed “intermediate frequency” relaxation ...
  • Determination of Electronic Transference Numbers of Polymers 
    Petit, Michel A.; Jozefowicz, Marcel (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (06), 1977)
    Liang's method has been employed under new conditions to determine electronic transference numbers of polymers using the sandwich cell (Ag–AgI–polymer–graphite). In this cell, when the graphite electrode is polarized by a ...
  • Physico-Chemical Studies in Nonaqueous Solvents Part 13.—Thermochemical Studies of some 1; 1 electrolytes in Tetramethylurea 
    Paul, Jauhar, Surinder P. Ram C.; Banait, Narula, Suraj P. Jagtar S. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (06), 1977)
    Heats of solution of alkali metal, ammonium and substituted ammonium perchlorates, lithium and sodium bromides and sodium and potassium thiocyanates have been measured in the concentration range 1.75-67.7×10−3 mol dm−3 in ...
  • Solute interactions in dilute aqueous solutions. Part 3.—Volume changes associated with the hydrophobic interaction 
    Franks, Felix (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (05), 1977)
    Second virial coefficients in the excess volume equation have been evaluated for BuOH, BuiOH, BusOH and ButOH in dilute aqueous solution at several temperatures. The coefficients are negative and decrease in magnitude with ...
  • Ring-disc electrodes. Part 17.—Ring response to periodic disc electrode forcing functions 
    Bruckenstein, Stanley; Tokuda, Koichi; Albery, W. John (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (05), 1977)
    The theory of ring electrode response to any periodic forcing function at the disc electrode of a ring-disc electrode has been derived and varified for a square wave current function using the ferri–ferrocyanide system.
  • Dissociation of 2-methylbut-1-ene and the resonance energy of the 2-methyl allyl radical 
    Trenwith, Antony B.; Wrigley, Stephen P. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (05), 1977)
    The pyrolysis of 2-methylbut-1-ene has been investigated over the temperature range 671–722 K and pressures between 50 and 500 Torr. Values for the limiting high pressure rate constant of the dissociation reaction ...
  • Comparison of the mechanisms of the thermal decompositions of 2,2′-azisobutane and azoisopropane 
    McKay, Gordon; Turner, James M. C.; Zaré, Farhad (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (05), 1977)
    The gas phase pyrolyses of 2,2′-azoisobutane and azoisopropane have been investigated in the temperature range 471–573 K. The products of 2,2′-azoisobutane (AIB) decomposition result from the following elementary reactions. ...
  • Infrared spectra from binuclear bridging complexes of sulphate adsorbed on goethite (α-FeOOH) 
    Parfitt, R. L.; Smart, R. St. C. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (05), 1977)
    Spectra of sulphate adsorbed on synthetic goethite (α-FeOOH) show replacement of A-type (one coordinated to Fe3+) surface hydroxyls and the formation of adsorbed sulphate groups with C2v symmetry. High affinity adsorption ...
  • Hydration and dimerization of some aliphatic carboxylic acids in benzene as studied by partition 
    Fujii, Yukio; Tanaka, Motoharu (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (05), 1977)
    The hydration and dimerization of some aliphatic carboxylic acids have been studied by partition. Monomer monohydrate, dimer mono- and tri-hydrates have been formed in benzene contacted with water. The formation constant ...
  • Photolysis of alkyloxy vanadium(V) chelates. A possible general route to alkyloxy radicals 
    Aliwi, Salah M.; Bamford, Clement H. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (05), 1977)
    We have studied the photochemical reactions (λ= 365 nm) of nineteen vanadium(V) chelates of structure VOQ2OR where Q is the 8-quinolyloxo ligand and R is an alkyl group. In all cases photolysis proceeds in a first-order ...
  • Conductance of some alkali metal halides in dilute aqueous solution at 25°C 
    Pethybridge, Alan D.; Spiers, David J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (05), 1977)
    Precise conductivity results are reported for dilute aqueous solutions of lithium, rubidium and caesium fluorides and for lithium bromide and iodide and sodium iodide at 25°C. The results are analysed in terms of both the ...
  • Spectral distributions of photo-electrochemical reactions over metal phthalocyanine electrodes 
    Meshitsuka, Shunsuke; Tamaru, Kenzi (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (05), 1977)
    The spectral distributions of photo-electrochemical currents over cobalt, nickel and copper phthalocynanines were measured in the region 340 to 800 nm. Two distinctive spectra were obtained for each metal phthalocyanine, ...
  • Study of the effect of compaction on the surface area and porosity of six powders by measurement of nitrogen sorption isotherms 
    Gregg, Sidney J.; Langford, John F. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (05), 1977)
    The effect, on the surface area and porosity of six powders, of compacting at pressures up to 1480 GN m–2 has been studied by measurements of the sorption isotherms of nitrogen at 77 K. The powders covered a variety of ...
  • X-ray photoelectron spectroscopy and heterogeneous catalysis, with elimination reactions as an example 
    Vinek, Hannelore; Noller, H.; Ebel, Maria; Schwarz, K. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (05), 1977)
    Assuming that the EPA and EPD strength of catalytically active surface sites is the major factor responsbile for catalytic properties, XPS is shown to be a powerful tool for estimating this factor and for predicting (or ...
  • Photochemistry and radiation chemistry of 9,10-anthraquinone-2-sodium sulphonate in aqueous solution. Part 3.—Pulse and gamma radiolysis 
    Clark, K. P.; Stonehill, H. I. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (05), 1977)
    Electron-pulse and gamma radiolysis of “aqueous” solutions of the title compound (D) in the range pH 14 to > 100 % H2SO4 give the same products as photolysis (mainly α- and β-monohydroxyderivatives ROH with some polyhydroxylated ...
  • Partial molar volumes of organic compounds in water. Part 2.—Amines and Amides 
    Shahidi, Fereidoon; Farrell, Patrick G.; Edward, John T. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (05), 1977)
    The partial molar volumes of a variety of aliphatic amines and amides in water at 25°C have been determined, and related to their van der Waals volumes. In accordance with earlier studies the relationship between partial ...
  • Partial molar volumes of organic compounds in water. Part 1.—Ethers, ketones, esters and alcohols 
    Edward, John T.; Farrell, Patrick G.; Shahidi, Fereidoon (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (05), 1977)
    The partial molar volumes of a number of ethers, ketones, esters and alcohols in water at 25.0°C have been determined and related to their van der Waals volumes by one of two equations, depending on whether the molecules ...
  • Photo-effects on benzoylferrocene in hydroxylic solvents 
    Heaney, Elizabeth K.; Logan, S. R.; Powell, John A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (04), 1977)
    It is shown that, contrary to earlier claims, the illumination of benzoylferrocene in a primary alcohol with light of around 300 nm does not cause photoionization to the benzoylferricenium ion and the solvated electron.
  • General solution to the Smith–Ewart equation for emulsion polymerization kinetics 
    Hawkett, Brian S.; Napper, Donald H.; Gilbert, Robert G. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (04), 1977)
    Using matrix methods, complete time-dependent solutions are derived for the Smith–Ewart equations describing polymerization in emulsion systems with a constant number of polymerizing loci, where the mechanisms of free ...
  • Melting of ice in porous solids 
    Rennie, George K.; Clifford, John (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (04), 1977)
    Differential scanning calorimetry (d.s.c.) and nuclear magnetic resonance (n.m.r.) techniques were used to study the melting of ice in porous solids. At low water contents (less than about three monolayers) no freezing ...

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