Journal Archive Collections: Recent submissions

  • Apparent molal heat capacities of organic compounds in aqueous solution. Part 3.—ω-Amino acids and related compounds 
    Cabani, Sergio; Conti, Giovanni; Matteoli, Enrico; Tani, Alessandro (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (03), 1977)
    Values of apparent molal heat capacities ΦCp in the range 23°–55°C, were determined by adiabatic calorimetry for the following amino acids: glycine, α-alanine, α-aminoisobutanoic acid, valine, serine, threonine, sarcosine, ...
  • Molar conductivity of (n-butyl)4N+(n-butyl)4B– as a function of temperature and pressure 
    Speedy, R. J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (03), 1977)
    The electrical conductivity of the ionic liquid (n-butyl)4N+(n-butyl)4B– was measured from 110 to 180°C and from 200 to 1800 bar. The viscosity and volume of the salt have been measured previously. For practical purposes ...
  • Electron spin resonance study of the 1 : 1 hydrogen-bonded complex of di-t-butylnitroxide with methanol. An analysis of an acceptor : self-associated donor equilibrium 
    Bullock, Anthony T.; Howard, Christopher B. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (03), 1977)
    The formation constant Kf for the 1:1 complex of di-t-butylnitroxide with methanol has been determined over the temperature range –23°C to + 65°C by measuring the variation of aN with methanol concentration. The solvent ...
  • Kinetics of activated chemisorption. Part 2.—Theoretical models 
    Aharoni, Chaim; Ungarish, Moshe (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (03), 1977)
    In activated chemisorption the plot of the reciprocal of the rate Z=(dq/dt)–1 against the time t is convex towards the Z axis at low t and concave at high t. This condition is satisfied if both the energy of activation, ...
  • Photoinduced oxidation of propan-2-ol by acid chromate 
    Kläning, Ulrik K. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (03), 1977)
    The photoinduced oxidation of propan-2-ol by acid chromate has been studied (i) by flash photolysis, (ii) by quantum yield measurements at low light intensity, (iii) by e.s.r. measurements during photolysis of solutions ...
  • Interaction of di-t-butyl nitroxide with alkanols: e.s.r. measurements 
    Atherton, Neil M.; Manterfield, Michael R.; Oral, Burhan; Zorlu, Feride (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (03), 1977)
    The 14N hyperfine coupling constant in di-t-butyl nitroxide dissolved in ethanol + carbon tetrachloride mixtures depends on the solvent composition. The analysis of the effect in terms of hydrogen-bonding between the radical ...
  • Absorption Spectra of Radical Ions of Polyenes of Biological Interest 
    Land, Edward J.; Lafferty, Joseph; Sinclair, Roy S.; Truscott, T. George (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (03), 1977)
    The radical cations and anions of a number of carbonyl containing polyenes of biological importance have been generated, and their absorptions characterised using pulse radiolysis techniques. The wavelength maxima of the ...
  • Isotope effect for the solution of hydrogen in metals: application to Pd/H(D) 
    Oates, W. A.; Flanagan, Ted B. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (03), 1977)
    The isotope effect for the solution of hydrogen in metals cannot be described over the whole temperature range by the usually employed model of localized oscillators. Consideration is given to the transition from localized ...
  • Decomposition of 1-phenylethyl hydroperoxide in the presence of cobalt acetylacetonates 
    Vasvári, Gábor; Gál, Dezsőa (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (03), 1977)
    The decomposition of 1-phenylethyl hydroperoxide has been investigated in the presence of Co(acac)2 and Co(acac)3 in argon and oxygen atmospheres. Co(acac)2 accelerates the decomposition of the hydroperoxide. The decomposition ...
  • On deviations from Young's equation 
    White, Lee R. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (03), 1977)
    Although Young's equation, γS=γSL+γL cos θC, is one of the oldest and most-used equations of classical physics and chemistry, it is in a rather delicate position scientifically, in that it is virtually impossible to prove ...
  • Temperature dependence of the interaction second virial coefficient using gas–liquid chromatography 
    Neogi, Parthasakha; Kudchadker, Arvind P. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (03), 1977)
    Measurement of the interaction second virial coefficient (B12) of nitrogen with methanol, ethanol, n-propanol, and n-butanol on the di-isodecyl phthalate stationary phase has been made with a high pressure gas–liquid ...
  • Thermodynamic properties of organic oxygen compounds: Part 36.—Heat capacity of isopropyl ether 
    Andon, Richard J. L.; Counsell, Jack F.; Lee, Derek A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (10), 1974)
    Heat capacities of isopropyl ether (crystals, liquid and vapour) in the range 14 to 450 K and enthalpies of melting and vaporization have been measured. Heat capacities of the ideal gas, second virial coefficients of the ...
  • Molecular complexes of substituted diphenyl sulphides with π acceptors. Charge transfer spectra and ionization potentials of the donors 
    Aloisi, G. Gaetano; Santini, Sergio; Sorriso, Salvatore (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (10), 1974)
    Charge transfer complexes of substituted diphenyl sulphides as donors with tetracyanoethylene, 2,3-dichloro-5,6-dicyano-p-benzoquinone and chloranil have been studied spectrophotometrically. From the energies of the charge ...
  • Approximation methods in the analysis of complex chemical reaction mechanisms 
    Adams, Paul A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (10), 1974)
    The application of approximation methods to the solution of systems of non-linear differential equations, of the type found in complex reaction mechanisms, has been considered. Two methods of deriving the approximations ...
  • Washburn numbers: Part 1.—The electromotive force method for alkali-metal chlorides in the methanol + water and dioxan + water systems 
    Feakins, David; Lorimer, John Phillip (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (10), 1974)
    The e.m.f. method has been used to study the transport of water in solutions of alkali-metal chlorides in methanol + water and dioxan + water systems. A detailed description of the method is given. Specimen results indicate ...
  • Nuclear magnetic resonance studies of preferential solvation: Part 4.—Thermodynamic treatment involving non-statistical distribution of solvated species 
    Covington, Arthur K.; Thain, Jennifer M. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (10), 1974)
    The solvation of an ion in a binary solvent mixture has been treated in terms of consecutive stepwise equilibria with the solvent exchange process becoming more, or less, energetically favourable as the solvation shell ...
  • Nuclear magnetic resonance studies of preferential solvation: Part 3.—Thermodynamic treatment involving change of solvation number, and application to dimethyl sulphoxide-containing solvents 
    Covington, Arthur K.; Lantzke, Ian R.; Thain, Jennifer M. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (10), 1974)
    Studies of 7Li and 133Cs ion n.m.r. chemical shifts in dimethyl sulphoxide (DMSO)+ water mixtures, have been interpreted in terms of a series of competitive equilibria in which the solvation number of the ions for DMSO is ...
  • Viscosity behaviour of some simple electrolytes in formamide solution 
    McDowall, Joseph M.; Vincent, Colin A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (10), 1974)
    Viscosity B-coefficients and activation parameters have been measured for a number of salts in formamide. The results are discussed in terms of the effects of individual ions on the structure of the solvent.
  • Photolysis of azocyclohexane alone and in an oxygen atmosphere 
    Currie, James L.; Sidebottom, Howard W.; Tedder, John M. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (10), 1974)
    The photolysis of azocyclohexane involves excited molecules which can be deactivated by collision or decompose into cyclohexyl radicals and nitrogen. Arrhenius parameters for reaction (11) have been estimated, cyclo-C6H1 ...
  • Addition of ethyl radicals to nitric oxide 
    Pratt, Graham; Veltman, Ian (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (10), 1974)
    Mixtures of methyl and ethyl radicals have been generated at 295 K in a fast flow discharge system by addition of hydrogen atoms to ethylene in helium at total pressures from 6 to 15 Torr (1 Torr = 133 N m–2). Mass ...

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