Journal Archive Collections: Recent submissions

  • Kinetics of Quaternization of 4-Methyl and 4-Ethyl Pyridine with n-Propyl and n-Butyl Bromide in Sulpholane 
    Boucher, Ernest A.; Khosravi-Babadi, Ezatollah; Mollett, Christopher C. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (02), 1978)
    Kinetic measurements have been carried out in sulpholane to provide a basis for comparison with quaternization reactions of poly(4-vinyl pyridine), and to clarify the roles of steric and inductive effects. Activation ...
  • Pulse Radiolysis Study of Protoferrihaem IX Intercalated in Sodium Dodecyl Sulphate Micelles 
    Evers, Edward L.; Jayson, Gerald G.; Swallow, A. John (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (02), 1978)
    Haemin intercalated in sodium dodecyl sulphate (SDS) micelles exists as monomer in an organic sphere of dimensions similar to that of cytochrome-c and thus provides a model which is closer to the biological molecule than ...
  • Infrared Study of the Adsorption of Acetone on Rutile 
    Griffiths, David M.; Rochester, Colin H. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (02), 1978)
    The associative adsorption of acetone onto Lewis acidic Ti4+ ion sites on rutile is followed by the formation of a surface enolate complex which reacts with a further acetone molecule to give mesityl oxide. The enolate is ...
  • Analysis of Activity Data in Three Component Systems by Means of an Augmented Redlich-Kister Formalism 
    Eliezer, Isaac; Howald, Reed A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (02), 1978)
    In a three component system, the activity coefficient (and other thermodynamic properties) of each species can be expressed as a Redlich-Kister expansion in the sum of the other two mole fractions, T=Xj + Xk-. logyi = 7'2M( ...
  • Washburn Numbers: Part 3.—Alkali-metal Chlorides in the DMSO4-Water System; Comparison with Hydrochloric Acid ; “ Structural ” Effects 
    Feakins, David; O’Shaughnessy, Denis A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (02), 1978)
    Washburn numbers for alkali-metal chlorides have been measured in the range 0-40 % (w/w) DMSO (x2 = 0-0.094) and are compared with literature values for H+CI-. There is evidence for significant incorporation of DMSO into ...
  • Decomposition of 2,2,3,3-Tetramethylbutane in the Presence of Oxygen 
    Atri, Gulshan M.; Baldwin, Roy R.; Evans, Geoffrey A.; Walker, Raymond W. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (02), 1978)
    The oxidation of 2,2,3,3-tetramethylbutane in KCl-coated vessels has been studied between 440 and 54O°C, and over the pressure range 60-500 Torr. The results are consistent with a simple mechanism comprising reactions ...
  • Heats of Solution of Electrolytes in Ethanol and Derived Enthalpies of Transfer from Water 
    Abraham, Michael H.; Ah-Sing, Eric; Namor, Angela F. Danil De; Hill, Tony; Nasehzadeh, Asadollah; Schulz, Ronald A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (02), 1978)
    Heats of solution of 12 1:1 electrolytes in ethanol have been determined calorimetrically, and have been extrapolated to zero electrolyte concentration to give iXH° values for these electrolytes. Together with literature ...
  • Test of the Nonane Method for Micropore Evaluation: Use of Nitrogen, n-Hexane and Carbon Tetrachloride as Adsorptives with Ammonium Phosphomolybdate, Phosphotungstate and Silicomolybdate as Absorbents 
    Gregg, S. John; Tayyab, Mohammad (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (02), 1978)
    The adsorption isotherms of nitrogen, n-hexane and carbon tetrachloride on each of three micro- porous solids have been determined gravimetrically both before and after pre-adsorption of n-nonane. The solids were ammonium ...
  • Thermodynamics and constitution of silicate melts. The system PbO + PbF2+ SiO2 
    Caley, William F.; Masson, Charles R. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12), 1978)
    Activities of PbF2 in PbO + PbF2 and PbO + PbF2+ SiO2 melts with up to 40 mol% PbF2 were determined at 1073–1173 K by means of an electrochemical cell with CaF2 as solid electrolyte. The results, together with previous ...
  • Application of Polymer Theory to Silicate Melts The System MO + MF2 + SiO2 
    Masson, Charles R.; Caley, William F. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12), 1978)
    Expressions are derived for activities of MO and MF2 as functions of composition in MO + MF2+ SiO2 melts. The treatment is based on the assumption that the melts consist of M2+ cations and O2–, F– and an array of silicate ...
  • Infrared Spectra of NO, N2O, NO2 and Oi Adsorbed on SiO Films 
    Lubezky, Aviva; Folman, Mordechai (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12), 1978)
    Infrared spectra of nitrogen and oxygen adsorbed on high surface area SiO films were investigated at different temperatures and surface coverages. On adsorption of NO at 77 K and at low coverage, decomposition of the ...
  • CF? Emission During Vacuum Ultraviolet Photodissociation of CF2Br2 
    Johnson, Christopher A. F.; Ross, Mrs.Hilary J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12), 1978)
    Photolysis of CF2Br2 at wavelengths shorter than 135 nm leads to the production of electronically excited CF2. At low pressure fluorescence is observed over the range 230–340 nm. Considerable vibrational excitation of the ...
  • Enthalpy of interaction between some cationic polypeptides and n-alkyl sulphates in aqueous solution 
    Paz-Andrade, Maria I.; Jones, Malcolm N.; Skinner, Henry A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12), 1978)
    The enthalpies of interaction of a homologous series of n-alkyl sulphates with poly(L-lysine)-hydrobromide, poly(L-arginine)hydrochloride and poly(L-histidine)hydrochloride have been measured at 25°C. A linear relationship ...
  • Photoluminescent Spectra of Surface States in Alkaline Earth Oxides 
    Coluccia, Salvatore; Deane, A. Michael; Tench, Anthony J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12), 1978)
    Photoluminescence has been observed from high surface area alkaline earth oxides with exciting light of a much lower frequency than that expected from the band gaps of the bulk oxides. This luminescence can be quenched by ...
  • Ionic oxides: distinction between mechanisms and surface roughening effects in the dissolution of magnesium oxide 
    Segall, Robert L.; Smart, Roger St. C.; Turner, Peter S. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12), 1978)
    The mechanism of the rate determining step (r.d.s.) for dissolution of well characterised, very perfect MgO “smoke” crystals, has been re-evaluated by studies of the dependence of log (rate) on pH. Surface potential barrier ...
  • Polarography and Solvatochromism: Part 1.—Polarographic Reduction of 5'-Methoxy-2'-hydroxy-N-methyl-4-stilbazolium Iodide and Related Compounds 
    Zuman, Petr; Szyper, Mira (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (07), 1977)
    2’-Hydroxy-N-methy]-4-stilbazolium iodide (IIa), its 5'-chloro-(lIc) and 5'-nitro-(IIb) derivatives arc strongly adsorbed at the surface of the dropping mercury electrode (d.m.e.). 5'-Methoxy-2- hydroxy-lV-methyl'4-stilbazoliuin ...
  • Far Ultraviolet Solution Spectroscopy of the Iodide Ion 
    Fox, Malcolm F; Hayon, Elie (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (07), 1977)
  • Thermodynamic Properties of Hydrogen in Palladium and its Alloys under Conditions of Constant Volume 
    Oates, W. Alan; Flanagan, Ted B (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (07), 1977)
  • Reversible Flocculation of Sterically-stabilised Dispersions 
    Cowell, Christopher; Li-In-On, Regis; Vincent, Brian (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (02), 1978)
    Because of the existence of a shallow minimum in the interaction energy against particle separation diagram for neutral, sterically-stabilised particles, dispersions of such particles exhibit reversible flocculation above ...
  • Sorption of Hydrogen by Palladium and Palladium/Silver Alloy Wires 
    Couper, Aitken; John, Christopher S. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (02), 1978)
    Heats of adsorption q{8), sticking probabilities and temperature programmed desorption spectra are reported for the adsorption of H2 onto clean wire surfaces of Pd, all as functions of coverage 0. Data, principally from ...

Search DSpace


Advanced Search

Browse

My Account