Journal Archive Collections: Recent submissions

  • Isotope effect for the solution of hydrogen in metals: application to Pd/H(D) 
    Oates, W. A.; Flanagan, Ted B. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (03), 1977)
    The isotope effect for the solution of hydrogen in metals cannot be described over the whole temperature range by the usually employed model of localized oscillators. Consideration is given to the transition from localized ...
  • Decomposition of 1-phenylethyl hydroperoxide in the presence of cobalt acetylacetonates 
    Vasvári, Gábor; Gál, Dezsőa (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (03), 1977)
    The decomposition of 1-phenylethyl hydroperoxide has been investigated in the presence of Co(acac)2 and Co(acac)3 in argon and oxygen atmospheres. Co(acac)2 accelerates the decomposition of the hydroperoxide. The decomposition ...
  • On deviations from Young's equation 
    White, Lee R. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (03), 1977)
    Although Young's equation, γS=γSL+γL cos θC, is one of the oldest and most-used equations of classical physics and chemistry, it is in a rather delicate position scientifically, in that it is virtually impossible to prove ...
  • Temperature dependence of the interaction second virial coefficient using gas–liquid chromatography 
    Neogi, Parthasakha; Kudchadker, Arvind P. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (03), 1977)
    Measurement of the interaction second virial coefficient (B12) of nitrogen with methanol, ethanol, n-propanol, and n-butanol on the di-isodecyl phthalate stationary phase has been made with a high pressure gas–liquid ...
  • Thermodynamic properties of organic oxygen compounds: Part 36.—Heat capacity of isopropyl ether 
    Andon, Richard J. L.; Counsell, Jack F.; Lee, Derek A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (10), 1974)
    Heat capacities of isopropyl ether (crystals, liquid and vapour) in the range 14 to 450 K and enthalpies of melting and vaporization have been measured. Heat capacities of the ideal gas, second virial coefficients of the ...
  • Molecular complexes of substituted diphenyl sulphides with π acceptors. Charge transfer spectra and ionization potentials of the donors 
    Aloisi, G. Gaetano; Santini, Sergio; Sorriso, Salvatore (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (10), 1974)
    Charge transfer complexes of substituted diphenyl sulphides as donors with tetracyanoethylene, 2,3-dichloro-5,6-dicyano-p-benzoquinone and chloranil have been studied spectrophotometrically. From the energies of the charge ...
  • Approximation methods in the analysis of complex chemical reaction mechanisms 
    Adams, Paul A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (10), 1974)
    The application of approximation methods to the solution of systems of non-linear differential equations, of the type found in complex reaction mechanisms, has been considered. Two methods of deriving the approximations ...
  • Washburn numbers: Part 1.—The electromotive force method for alkali-metal chlorides in the methanol + water and dioxan + water systems 
    Feakins, David; Lorimer, John Phillip (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (10), 1974)
    The e.m.f. method has been used to study the transport of water in solutions of alkali-metal chlorides in methanol + water and dioxan + water systems. A detailed description of the method is given. Specimen results indicate ...
  • Nuclear magnetic resonance studies of preferential solvation: Part 4.—Thermodynamic treatment involving non-statistical distribution of solvated species 
    Covington, Arthur K.; Thain, Jennifer M. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (10), 1974)
    The solvation of an ion in a binary solvent mixture has been treated in terms of consecutive stepwise equilibria with the solvent exchange process becoming more, or less, energetically favourable as the solvation shell ...
  • Nuclear magnetic resonance studies of preferential solvation: Part 3.—Thermodynamic treatment involving change of solvation number, and application to dimethyl sulphoxide-containing solvents 
    Covington, Arthur K.; Lantzke, Ian R.; Thain, Jennifer M. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (10), 1974)
    Studies of 7Li and 133Cs ion n.m.r. chemical shifts in dimethyl sulphoxide (DMSO)+ water mixtures, have been interpreted in terms of a series of competitive equilibria in which the solvation number of the ions for DMSO is ...
  • Viscosity behaviour of some simple electrolytes in formamide solution 
    McDowall, Joseph M.; Vincent, Colin A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (10), 1974)
    Viscosity B-coefficients and activation parameters have been measured for a number of salts in formamide. The results are discussed in terms of the effects of individual ions on the structure of the solvent.
  • Photolysis of azocyclohexane alone and in an oxygen atmosphere 
    Currie, James L.; Sidebottom, Howard W.; Tedder, John M. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (10), 1974)
    The photolysis of azocyclohexane involves excited molecules which can be deactivated by collision or decompose into cyclohexyl radicals and nitrogen. Arrhenius parameters for reaction (11) have been estimated, cyclo-C6H1 ...
  • Addition of ethyl radicals to nitric oxide 
    Pratt, Graham; Veltman, Ian (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (10), 1974)
    Mixtures of methyl and ethyl radicals have been generated at 295 K in a fast flow discharge system by addition of hydrogen atoms to ethylene in helium at total pressures from 6 to 15 Torr (1 Torr = 133 N m–2). Mass ...
  • Chemisorption of nitrogen on tungsten studied by auger electron spectroscopy 
    Joyner, Richard W.; Rickman, John; Roberts, M. Wyn (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (10), 1974)
    By monitoring the surface directly by Auger electron spectroscopy (AES), adsorption isotherms for nitrogen on polycrystalline tungsten ribbons have been determined in the temperature range 1200–1400 K. These are not of the ...
  • Evidence for the nature of CO adsorbed on nickel from electron spectroscopy 
    Joyner, Richard W.; Roberts, M. Wyn (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (10), 1974)
    At 295 K there is clear evidence from the observed X-ray and u.v. induced spectra that CO is adsorbed in a molecular form. The observed spectra are in good agreement with the ionisation potentials expected of electrons in ...
  • Site-binding model of the electrical double layer at the oxide/water interface 
    Yates, David E.; Levine, Samuel; Healy, Thomas W. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (10), 1974)
    A site-binding model of the oxide/aqueous electrolyte interface is introduced, in which it is proposed that the adsorbed counter ions form interfacial ion pairs with discrete charged surface groups. This model is used to ...
  • Electric Modulated Reflectance at Mercury Electrodes: Transition between Electrostatic Adsorption and Chemisorption 
    Gottesfeld, Shimshon; Conway, Brian E. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (10), 1974)
    Reflectance changes at polished electrode surfaces can arise from changes of optical properties of the metal surface and from changes of local ionic concentrations in the double-layer. The significance of these two effects ...
  • Homogeneous Isotope Exchange Reactions: Part 3—H2S+D2 
    Pratt, Graham; Rogers, David (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (1), 1977)
    The kinetics of the early stages of the exchange reaction in H2S + D2 mixtures [H2S, 0.55–9.34 Torr (1 Torr = 133 N m–2); D2, 0.55–6.39 Torr] have been studied in a static system at 808–937 K. The effects of excess argon ...
  • Standard Free Energy of Transfer of Ionic Surfactants from Water to Water+Acetone Mixtures from Vapour Pressure Measurements 
    Treiner, Claude; Besnerais, A. Le (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (1), 1977)
    The standard free energy of transfer, ΔG°t of sodium decylsulphate (SDS) and of decyltrimethyl-ammonium bromide (DTMABr) from pure water to mixtures of water and acetone (AC) have been determined by accurate vapour pressure ...
  • Sorption of Water Vapour by some Derivatives of Bovine Serum Albumin 
    Rochester, Colin H.; Westerman, A. Valerie (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (1), 1977)
    Isotherms for the sorption of water vapour by succinyl, acetyl, amidino, methyl and carbodiimide derivatives of bovine serum albumin at 298 K have been determined gravimetrically. The effects of the specific chemical ...

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