Journal Archive Collections: Recent submissions

  • Selective Free Radical Reactions with Proteins and Enzymes: The Inactivation of Subtilisin Carlsberg and Subtilisin Novo 
    Bisby, Roger H.; Cundall, Robert B. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (12), 1974)
    Reactions of the selective inorganic radical anions (SCN)–2 and Br–2, with subtilisins Novo and Carlsberg lead to selective oxidation of the tryptophan, tyrosine, and histidine amino-acid residues. Inactivation studies ...
  • Protein-Surfactant Interactions: Nuclear Magnetic Resonance and Binding Isotherm Studies of Interactions between Bovine Serum Albumin and Sodium Dodecyl Sulphate 
    Oakes, John (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (12), 1974)
    The interactions between the protein, bovine serum albumin (BSA), and sodium dodecyl sulphate (SDS) at pH 5.6 have been studied by n.m.r. spectroscopy. The main findings are (i) above binding numbers of about 10-20, SDS ...
  • Electron Donor Sites on the Surface of Magnesium Oxide Powder studied by Electron Spin Resonance Spectroscopy 
    Cordischi, D.; Indovina, V.; Cimino, A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (12), 1974)
    The electron donor properties of MgO powders, activated in vacuo in the temperature range 300–1200 K have been investigated by adsorption of nitrobenzene and some of its para substituted derivatives. The results confirm ...
  • Surface Properties of Silica-Magnesia Gels 
    Kermarec, M.; Briend-Faure, M.; Delafosse, D. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (12), 1974)
    The acid-base properties of silica–magnesia gels have been examined by an i.r. spectroscopic study of the adsorption of ammonia and pyridine and by a study of the cationic exchange capacity of the gels. The basic properties ...
  • Mechanism of the Kryptonation of Nickel by Film Evaporation 
    Bodys, J. W. S.; Campbell, Kenneth C. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (12), 1974)
    Nickel films have been evaporated in the presence of krypton on to a Pyrex substrate maintained at 77 K, and the variation of the krypton incorporation with metal deposition rate and krypton pressure has been studied. ...
  • Thermodynamics of the High Temperature Adsorption of some Permanent Gases by Porous Carbons 
    Cole, John H.; Everett, Douglas H.; Marshall, Charles T. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (12), 1974)
    This paper presents precise experimental data for the adsorption (na) of nitrogen and the noble gases by two unactivated and two activated (10.8% and 22.0% burn-off) Saran type porous carbons over the temperature range ...
  • Use of the Langmuir Method for Kinetic Studies of Decomposition Reactions: Calcite (CaCO3) 
    Beruto, Dario; Searcy, Alan W. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (12), 1974)
    The Langmuir method for measurement of vapour pressures has been tested for use in studies of decomposition reactions. The isothermal weight loss in vacuum from cleavage (1011) planes of calcite (CaCO3) single crystals was ...
  • Cation motion in dehydrated, partially ca2+-exchanged zeolites 
    Schoonheydt, Robert A.; Wilde, Willy De (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (12), 1974)
    Ionic conduction in dehydrated partially Ca2+-exchanged synthetic faujasites is due to Na+ ions on sites II. The mechanism is a vacancy diffusion. Activation energies lie in the range 38–59 kJ mol–1 and are mainly determined ...
  • Investigation of the Transport Properties of a Quaternary Ammonium Anion Exchange Membrane: Part 1.- —Application of Irreversible Thermodynamics to the Chloride Form 
    McCallum, Colin; Paterson, Russell (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (12), 1974)
    A detailed study of the transport properties of the chloride form of a strong base quaternary ammonium anion exchange membrane has been completed. Experimental determination of isotope diffusion coefficients and electrical, ...
  • Ellipsometry of Spread Monolayers: Part 2.—Coloured Systems : Chlorophyll a, Carotenoic Acid, Rhodamine 6G and a Cynanine Dye 
    Engelsen, Daan Den; Koning, Bob De (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11), 1974)
    Ellipsometric measurements of light-absorbing monomolecular layers are described in this paper. Combination of the ellipsometric results with data from surface pressure studies and absorption spectra leads to a better ...
  • Photoinitiation of Polymerization by Chloro-o.xobis(2,4- pentanedionato)vanadium(v) 
    Aliwi, S. M.; Bamford, Clement H. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11), 1974)
    Chloro-oxobis(2,4-pentanedionato)vanadium(V)[VO(acac)2Cl] sensitizes the polymerization of methyl methacrylate when irradiated by wavelengths in the near ultra-violet. Under the experimental conditions employed ([VO(acac)2Cl]<10–4 ...
  • Ion-exchange Selectivity and Electrolyte Concentration 
    Barrer, Richard M.; Klinowski, Jacek (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11), 1974)
    It is shown how, from a given exchange isotherm at a given total solution normality, one may calculate isotherms and exchange selectivity coefficients at other total normalities. When the exchange ions have different ...
  • Solute Ion and Radical Formation in the Pulse Radiolysis of Acetonitrile Solutions 
    Baptista, Joao L.; Burrows, Hugh D. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11), 1974)
    Following microsecond pulse radiolysis of solutions of a variety of solutes in acetonitrile, absorptions assigned to solute cation radicals, anion radicals, excited states and neutral radicals are observed. Pulse radiolysis ...
  • Mossbauer Studies of Ferrous-A Zeolite: Part 3.—The Adsorption of Ethanol 
    Dickson, Bruce L.; Rees, Lovat V. C. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11), 1974)
    Mossbauer spectra have been taken after successive additions of small doses of ethanol have been made in dehydrated ferrous-A. These spectra show that two molecules of adsorbate coordinate to each ferrous ion. When the ...
  • Mossbauer Studies of Ferrous-A Zeolite: Part 2.—The Mobile Adsorption of Ethylene 
    Dickson, Bruce L.; Rees, Lovat V. C. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11), 1974)
    The titration of ethlene into dehydrated ferrous-A has been followed by 57Fe Mössbauer spectroscopy. The adsorption of ethylene increases the isomer shift and the quadrupole splitting of the single doublet of the outgassed ...
  • Mossbauer Studies of Ferrous-A Zeolite: Part 1.—Adsorption/Desorption of Water 
    Dickson, Bruce L.; Rees, Lovat V. C. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11), 1974)
    Ferrous ions have been ion exchanged into A zeolite. The ferrous ions in the dehydrated form of the zeolite give an isomer shift of 1.08 mm s~l and a temperature independent quadrupole splitting of 0.46 mm s~l. The ferrous ...
  • Extraction of Uranyl Nitrate and Thorium Nitrate by Methyl Diphenyl Phosphate 
    Apelblat, Alexander (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11), 1974)
    Partition studies have been carried out for the uranyl nitrate/water/methyl diphenyl phosphate and thorium nitrate/water/methyl diphenyl phosphate systems. The activities of methyl diphenyl phosphate were calculated for ...
  • Hydrogen Bond Strengths and Acidities of Hydroxyl Groups on Silica-Alumina Surfaces and in Molecules in Solution 
    Rouxhet, Paul G.; Sempels, Raymond E. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11), 1974)
    The properties of hydroxyl groups on mixed silica–alumina gels (0–50 % Al2O3) have been studied by adsorbing weak H bond accepting molecules onto the gels and recording the OH stretching infrared band. Additional ...
  • Compensation Effect in the Kinetics of the Catalysed Oxidation of Carbon 
    Feates, Frank S.; Harris, Peter S. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11), 1974)
    A pattern of behaviour amongst catalysts in the catalysed oxidation of carbons has been identified. A link between the rates of the catalysed and uncatalysed reactions in these systems has been established. A phenomenological ...
  • Kinetics of Dissociative Recombination of Free Electrons with Hydronium Ions in Premixed Flames 
    Hayhurst, Allan N.; Telford, N. Roland (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11), 1974)
    The rate coefficient for the gas phase recombination of H3O+ ions and free electrons in H3O++ e–→ neutral products has been measured in atmospheric pressure flames of H2+ O2+ N2 over the temperature range 2025–2445 K. ...

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