Journal Archive Collections: Recent submissions

  • Solid/Liquid Phase Equilibria and Solid Compound Formation in Mixtures of Hexafluorobenzene with Nitrogen Containing Compounds 
    Ott, J. Bevan; Goates, J. Rex; Reeder, Joan; Shirts, Randall B. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974)
    Thermal methods have been used to determine with high precision the solid/liqnid phase equilibria diagrams tor mixtures of hcxafluorobcnzene with Y-methylmorpholine, TV-methyipipcridinc and AW'-dimcthylpiperazine. Solid ...
  • Thermal Decomposition of Manganese(II) Oxalate in Vacuum and in Oxygen 
    Brown, Michael E.; Dollimore, David; Galwey, Andrew K. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974)
    Comparative studies of the kinetics of thermal decomposition of anhydrous manganese(ll) oxalate in vacuum and in oxygen are reported. Reaction rates were appreciably influenced by the conditions of salt dehydration : ...
  • Enthalpy of Interaction between some Globular Proteins and Sodium n-Dodecyl Sulphate in Aqueous Solution 
    Tipping, Edward; Jones, Malcolm N.; Skinner, Henry A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974)
    The enthalpy of binding of sodium n-dodecyl sulphate (SDS) to scrum albumin, ovalbumin and ribonuclease A has been measured by microcalorimetry over the temperature range 18.5 to 32.0 C. The amount of SDS bound to the ...
  • Photolysis of Cycloheptanon 
    Frey, Henry M.; Mautner, Gillian N. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974)
    The photochemical decomposition of cyclohcptanonc lias been studied in the gas phase as a function of pressure, temperature and wavelength. The major products arc carbon monoxide, hcx-l-cnc, cyclohexane and hcpt-6-enal. ...
  • Adiabatic Compressibility of Binary Liquid Mixtures 
    Jain, D. V. S.; North, Alastair M.; Pethrick, Richard A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974)
    Adiabatic compressibility, density and some viscosity measurements arc reported on a scries of mixtures of aromatic compounds with cyclic saturated rings and carbon tetrachloride. The magni tudes and signs of the excess ...
  • Pre-melting Transitions in Caged Hydrocarbons, a General Theory of Disorder in Plastic Crystals 
    Clark, Timothy; McKervey, M. Anthony; Mackle, Henry; Rooney, John J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974)
    rhe results of differential scanning calorimetry studies on caged hydrocarbons have been used, with existing data, to propose a new interpretation of orientational disorder in plastic crystals. New empirical relationships ...
  • Kinetics of Electrode Reactions in Liquid Ammonia: Part 4.—The Cun/Cu'/Cu° System in Acid Solution 
    Brown, Oliver R.; Thornton, Sean A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974)
    The Cu^/Cu1 redox system is fully reversible on gold or platinum electrodes and quasi-reversible on vitreous carbon. When the metal electrodes are anodically oxidised prior to the measurements, the redox process is ...
  • Oxidation of Formaldehyde in KCl-coated Vessels 
    Baldwin, Roy R.; Fuller, Alan R.; Longthorn, David; Walker, Raymond W. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974)
    In the temperature range 440-540’C, the oxidation of HCHO in KCl-coated vessels is reproducible and of short chain length for HCHO concentrations in the range 0.05-4 Torr. Interpretation of the [CO] against time profile ...
  • Photo-oxidation of Alkylbenzenes Initiated by 1-Naphthol 
    Klein, Allan E.; Pilpel, Neiton (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974)
    The addition of 1-naphthol accelerates the photo-oxidation of alkylbenzcncs when their alkyl group contains a reactive hydrogen atom. From the effects of u.v. light on dilute solutions of 1-naphthol in cumene, ...
  • Probability of Reaction of H with N2O as a Function of Energy 
    Oldershaw, G. A.; Porter, D. A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974)
    The net probabilities of reactions (1) and (2) have been determined as a function of the initial kinetic energy of H* by analysis of the products of photolysis, at various wavelengths, of Hl mixed with N2O. H* + ...
  • Effect of Surface Dynamics on the Process of Droplet Formation from Supported and Free Liquid Cylinders 
    Carroll, Brendan J.; Lucassen, Jacob (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974)
    The formation of droplets from cylindrical oil films supported by oleophilic filaments has been studied experimentally. In the absence of surfactant, the initial rate of growth of a disturbance on the cylindrical fluid ...
  • Electrification Associated with Droplet Production from Liquid Jets 
    Iribarne, J. V.; Keemes, M. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974)
    In the first part, a theoretical model is proposed for the charging of droplets separating from the tip of liquid jets or filaments, based on a previous hypothesis by Iribarnc and Mason. The charging is attributed to ...
  • Negative Ion Mass Spectrometry: Part 2?—Ionization Processes in 2- and 3-Nitrotoluene 
    Alexander, Roger G.; Bigley, David B.; Turner, Robert B.; Todd, John F. J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974)
    Ionization efficiency curves (profiles) have been recorded for parent and major daughter negative ions from 2- and 3-nitrotoluene. From the effects of adding sulphur hexafluoride as a thermal electron scavenger it is ...
  • Viscosities of Binary Gas Mixtures at High Temperatures 
    Maitland, Geoffrey C.; Smith, E. Brian (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974)
    The viscosities of He + Ar, Ar + Kr and CH4 + CF4 binary gas mixtures have been measured over the temperature range 293-1600 K using a capillary flow technique. The results are in good agree ment with existing data ...
  • Electron Paramagnetic Resonance Study of the Conformation of Macromolecules Adsorbed at the Solid/Liquid Interface 
    Fox, Katharine K.; Robb, Ian D.; Smith, Royston (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974)
    A method using e.p.r. spectroscopy has been developed for determining the ratio of the number of segments in loops to the number in trains for polymers adsorbed at the solid/liquid interface. The method can be used on ...
  • Pressure Dependence of the Volumes of Ionization of Carboxylic Acids at 25, 35 and 45°C and 1-1200 bar 
    Hoiland, Harald (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974)
    The equivalent conductances of formic acid, acetic acid, propionic acid, valeric acid, hexanoic acid, isobutyric acid, and isovaleric acid have been measured as functions of pressure up to 1200 bar. Equilibrium constants ...
  • Radiolysis of Pyrimidines in Aqueous Solutions: Part 3.’—Micellar Effects on Product Yields Formed in the Interaction of ea~, •H, -OH and Cl? with Thymine and Uracil 
    Fendler, Janos H.; Infante, A.; Jirathana, Poonsri; Fendler, Eleanor J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974)
    Micellar surfactants decrease the yield of products formed in the interaction of ea"q, -H, -OH and Cl2 with uracil and thymine far in excess of the decrease expected on the basis of simple competition of these species ...
  • Radiolysis of Pyrimidines in Aqueous Solutions: Part 2.—Product Formation in the Interaction of ea~, -H, -OH and C17- with 
    Infante, Gabriel A.; Jirathana, Poonsri; Fendler, Eleanor J.; Fendler, Janos H. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974)
    Product yields in the reaction of e~, -H, -OH and Cl/ with uracil and uracil- have been determined quantitatively in 60Co y-irradiated aqueous uracil solutions in the presence of suitable scavengers. Good material ...
  • Poisoning of a Supported Molybdenum Olefin Disproportionation Catalyst 
    Howe, Russell F.; Kemball, Charles (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974)
    Nitric oxide and carbon monoxide have been used to poison a propene disproportionation catalyst prepared from molybdenum hexacarbonyl on silica. Nitric oxide is strongly adsorbed, and an effective poison, but infra-red ...
  • Primary Acidity Constant of Maleic Acid in Ordinary Water and in Deuterium Oxide 
    Lowe, Barrie M.; Smith, David G. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    The primary acidity constant of maleic acid has been determined at 298.2 K in ordinary water by conductance measurements and in both ordinary water and deuterium oxide by precise e.m.f. measure ments with glass and ...

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