Journal Archive Collections: Recent submissions

  • Stoichiometry of Precipitation under Conditions of Double Diffusion 
    Zivkovic, Tomislav; Pokric, Biserka; Pucar, Zvonimir (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11), 1974)
    The mechanism of natural precipitation processes has been studied using as a model system the one-dimensional double diffusion of the precipitating components in a gel. It was found, theoretically and experimentally, that ...
  • Semiconductor Properties of Crystalline Anthracene: Competition of Electron and Hole Photoinjection by Redox Electrolytes 
    Rosseinsky, David R.; Hann, Richard A.; Axon, Anthony J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11), 1974)
    Electron photocurrents have been measured with a number of solution photoinjectors. A new set of electrode potentials for solid anthracene is used to account for the pH dependence of electron as compared with hole photocurrents ...
  • Hydrogenolysis of some Saturated Hydrocarbons over a Platinum Black Catalyst 
    Guczi, L.; Sarkany, A.; Tetenyi, P. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11), 1974)
    Deuterium exchange reactions of methane, ethane, propane and neopentane, and the hydrogenolysis and isomerization of ethane, propane, n-butane and isobutane on platinum black have been studied in the temperature range ...
  • Thermodynamic Study of the 1 : 1 Solid Compound, Hexafluorobenzene-Benzene 
    Brennan, J. S.; Brown, N. M. D. Brown; Swinton, Findlay L. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11), 1974)
    A study of the 1 : 1 solid compound hexafluorobenzene–benzene using a differential scanning calorimeter has enabled an estimate to be made of the enthalpy of formation of the compound when it is formed from the two pure ...
  • Salting-in of Alcohols by Symmetrical Tetra-alkylammonium Bromides 
    Aveyard, Robert; Heselden, Roy (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11), 1974)
    The changes in free energy, enthalpy and entropy associated with the transfer of several alkanols at high dilution from water to aqueous solutions of some symmetrical tetra-alkylammonium bromides (R4NBr) have been determined ...
  • P,V,T Behaviour of Liquid n-Dodecane at Negative Pressures 
    Huang, Hann-Sheng; Winnick, Jack (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11), 1974)
    The extension of a column of liquid n-dodecane in a centrifugal field has been measured optically. Schlieren photographs of the meniscus position were made at rotational speeds up to 24 000 r.p.m. and at temperatures from ...
  • Ionic Conduction in Ammonium Perchlorate Doped with Divalent Ions 
    Owen, Gari P.; Thomas, John M.; Williams, John O. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11), 1974)
    D.c. electrical measurements are reported for sulphate-ion-doped and barium-ion-doped ammonium perchlorate. The extension of an impurity-dominated regime in sulphate-ion-doped ammonium perchlorate, and the fact that ...
  • Derivation of Partial Molal Volumes in Binary Systems 
    Sinclair, Crawiord D.; Vincent, Colin A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11), 1974)
    A number of methods of evaluating partial molal volumes from experimental density/composition data for binary systems are considered. Systematic analysis of density data for four binary systems involving water and a second ...
  • Appearance and Ionization Potentials of Ions produced by Electron-impact on some Phosphorus-Fluorine Compounds: the Phosphorus-Phosphorus Bond Dissociation Energy in Diphosphorus Tetralluoride 
    Dean, Christopher R. S.; Finch, Arthur; Gardner, Peter J.; Payling, David W. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11), 1974)
    The ionization potentials of P2F4, PF3 PF2H and PF2I and the appearance potentials of the PF+2 ion from these species are reported. The ionization potential of the PF2˙ radical is estimated using approximations for the ...
  • Experimental Enthalpies for Nitrous Oxide Vapour in the range 1 to 49 bar and 273.15 to 373.15 K 
    Dawe, Richard A.; Snowdon, Peter N. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    The enthalpy-pressure behaviour for nitrous oxide along eleven isotherms in the vapour phase has been determined from measurements of the Joule-Thomson effect. These measurements and the derived enthalpy values are reported ...
  • Kinetics and Mechanism of the Reduction of Manganese(III) in Perchloric Acid at a Platinum Electrode 
    Rosseinsky, David R.; Hill, R. John (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    The electrode kinetics at 25°C of the reduction of manganese(III) on an oxidised platinum surface confirms an unusually low transfer coefficient of 0.26. Interpretation involving a comparison with a correlation of hydrolytic ...
  • Aqueous Hydroxide Ion: Part 1.—Hydrogen Isotope Fractionation Studies by Proton Magnetic Resonance 
    Taylor, C. E.; Tomlinson, C. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    The hydrogen isotope fractionation of the aqueous hydroxide ion has been studied through p.m.r. measurements on lithium, sodium, and potassium hydroxide solutions in light and heavy water. The experimental results are ...
  • Electron Spin Resonance Detection of Radical Intermediates During Photo-oxidation by Metal Ions in Solution 
    Greatorex, David; Hill, Richard J.; Kemp, Terence J.; Stone, Thomas J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    Irradiation of fluid solutions of ceric and uranyl ions in various organic media in the temperature range 140–290 K gives rise in many cases to well-resolved e.s.r. spectra of solvent-derived radicals, enabling characterisation ...
  • Transport and Kinetics in Two Phase Systems 
    Albery, W. John; Couper, A. Mottram; Hadgraft, Jonathan; Ryan, Charles (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    A new technique for investigating kinetics in and transport between two liquid phases is described. The interface of known area is established on the sinter in a Stokes diffusion cell. Transport to the interface is controlled ...
  • Kinetic Studies of Diatomic Free Radicals using Mass Spectrometry: Part 1.—System Description and Applications to F Atoms and FO Radicals 
    Clyne, Michael A. A.; Watson, Robert T. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    A system for sampling of free radicals from a discharge-flow system to a mass spectrometer is described. The molecular radicals FO, ClO, BrO, IO, OH, SF, NF2, and SF2, and the atoms N, O, Br, Cl and F have been detected ...
  • pH Effects on the Pulse Radiolysis of Deoxygenated Aqueous Solutions of Sulphur Dioxide 
    Eriksen, Trygve E. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    Dilute deoxygenated aqueous solutions of sulphur dioxide and its related anions HSO–3 and SO2–3 in the pH-range 2–11 were pulse irradiated and the time dependence of the transient optical absorptions and electrical conductance ...
  • Infra-red Study of the Reactions between Ethyl Isocyanate and the Surface of Magnesium Oxide 
    Eley, Daniel D.; Kiwanuka, Gerald M.; Rochester, Colin H. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    Ethyl isocyanate reacts at 306 K with isolated hydroxyl groups on the surface of magnesium oxide to form a urethane. The adsorption reaction is reversed by evacuation at high temperatures. Adjacent interacting hydroxyl ...
  • Low Temperature Gas-phase Oxidation of Aldehydes: Part 2.—Retardation by Formaldehyde above 120°C 
    Dixon, David J.; Skirrow, Geoffrey; Tipper, Charles F. H. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    The effect of added formaldehyde on the oxidation of acetaldehyde and propionaldehyde between 119 and 188°C has been studied using a static system. Formaldehyde retards the oxidation, and at 188°C the rate after 25 % ...
  • Low Temperature Gas-phase Oxidation of Aldehydes: Part 1.—The Reaction Below 120°C 
    Dixon, David J.; Skirrow, Geoffrey; Tipper, Charles F. H. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    The gas-phase oxidation of acetaldehyde, propionaldehyde and the butyraldehydes, in an unpacked and a packed vessel between 45 and 120°C, has been studied using a static system with a very small dead volume. Contrary to ...
  • Self-heating and Spontaneous Ignition in the Combustion of Gaseous Methylhydrazine 
    Gray, Peter; Sherrington, Malcolm E. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    The exothermic oxidation of gaseous monomethylhydrazine (CH3NHNH2) has been investigated in the gas phase over a temperature range 370–510°C in a 1-litre vessel. Critical conditions of pressure, temperature and reactant ...

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