Journal Archive Collections: Recent submissions

Now showing items 361-380 of 815

Heats of mixing of tetra-alkyltin compounds with normal and branched alkanes. Order in long alkanes

Delmas, Geneviève; Turrell, S. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

Heats of mixing at 25°C of SnR4(R = CH3, C2H5, C4H10) with seven n-alkanes from C5 to C16, three very branched alkanes 2,2,4-trimethylpentane, 2,2,4,6,6-pentamethylheptane, 2,2,4,4,6,8,8-heptamethylnonane and two lightly ...
Reaction of Oxygen Atoms with Carbonyl Compounds: Part 3.—Ketene

Mack, G. P. R.; Thrush, B. A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

The reaction between excess atomic oxygen and ketene has been studied in a discharge flow system by product analysis and kinetically using e.p.r. and chemiluminescence. This rate constant for the initial step, which yields ...
Reaction of Oxygen Atoms with Carbonyl Compounds: Part 2.—Acetaldehyde

Mack, G. P. R.; Thrush, B. A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

The reaction of excess atomic oxygen with acetaldehyde in a discharge-flow system has been studied at temperatures between 195 and 573 K. Kinetic studies and product analyses establish the mechanism to be O + CH3CHO → CH3CO ...
Upper and Lower Critical Solution Temperatures in the Cosolvent System Acetone(l) + Diethyl Ether(2) +Polystyrene(3)

Cowie, John M. G.; McEwen, Iain J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

Phase diagrams for different molecular weight fractions of polystyrene in the mixed solvent system acetone+diethyl ether have been obtained. The system shows a variation of upper and lower critical solution temperatures ...
Phase Structure and Rheological Properties of a Mixed Zwitterionic/Anionic Surfactant System

Saul, Dorothy; Tiddy, Gordon J. T.; Wheeler, Barbara A.; Wheeler, Phillip A.; Willis, Edwin (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

The phase diagram of the mixed zwitterionic/anionic surfactant system hexadecyldimethyl- ammoniopropancsulphonate/sodium dodecyl sulphate/water has been determined in the aqueous region (>90.0 % water) by optical ...
Phase Structure, Nuclear Magnetic Resonance and Rheological Properties of Viscoelastic Sodium Dodecyl Sulphate and Trimethylammonium Bromide Mixtures

Barker, Christopher A.; Saul, Dorothy; Tiddy, Gordon J. T.; Wheeler, Barbara A.; Willis, Edwin (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

The phase diagram of octyltrimethylammonium bromide and sodium dodecyl sulphate (SDS) in water (>90 %) is reported at 298 K; the phase regions observed are liquid, two liquid, and liquid plus liquid crystal. Liquids ...
Pulse Radiolysis Study of the Reactions of Hydrated Electrons with Naphthalene, Phenanthrene, Biphenyl and Fluorene in Aqueous Micellar Solutions

Fendler, Janos H.; Gillis, Hugh A.; Klassen, Norman V. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

The reaction of hydrated electrons with naphthalene, phenanthrene, biphenyl and fluorene to form the respective aromatic radical anions has been studied in aqueous solutions (1 % methanol, pH 12.1) in the presence and ...
Study of the Oxidation of Molybdenum Surfaces by Energy Loss Spectroscopy Combined with Auger Electron Spectroscopy

Kawai, Tomoji; Kunimori, Kimio; Kondow, Tamotsu; Onishi, Takaharu; Tamaru, Kenzi (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

The oxidation of molybdenum as an evaporated film and of its annealed surface was investigated by Energy Loss Spectroscopy (ELS) combined with Auger Electron Spectroscopy (AES). The 10 eV and the lower energy loss peaks ...
Series Methods in the Analysis of Kinetic Data for Chemical Systems

Adams, Paul A.; Sheppard, John G. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

Application of series methods to the evaluation of rate coefficients has been considered for reactions in which explicit integration of the system of dependent differential equations is impossible The approximation of ...
Use of a Rotating Single Probe in Studies of Ionization of Additives to Premixed Flames: Part 5.—Recombination of Metal Ions with Electrons

Anthony, Edward J.; Bulewicz, Elzbieta M.; Kelly, Roy; Padley, Peter J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

Electrostatic probe measurements are reported on the recombination rate constant, kr, or the process M++ e–X→M + X in premixed flames, for a number of metals M and (for M = Li) for the specific collision partners ×= H2, ...
Electron Spin Resonance Studies of Elementary Processes in Radiation- and Photo-chemistry: Part 12.—Fluorinated Carboxylic Acids at Cryogenic Temperatures

Ayscough, Peter B.; Mach, Karel (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

Some information concerning the mechanism of the radiolysis of perfluorinated carboxylic acids is presented from an examination of the e.s.r. spectra of radicals trapped in polycrystallinc samples of the acids between ...
Activity coefficients of single complexes and coordination equilibria in three-component systems of the type MX2+ solvent + diluent: Systems involving MnCl2, NiCl2, pyridine, benzene, chlorobenzene and o-dichlorobenzene

Libus, W.; Kluczkowski, M.; Kłonkowski, A.; Nierzwicki, W. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

Solubility isotherms for MnCl2 and NiCl2 in mixtures of pyridine with benzene and with o-dichlorobenzene have been determined at 20 and 30°C, and those of MnCl2 in mixtures of pyridine with chlorobenzene supplemented with ...
Effects of Adsorbed Ions on Simple Electrode Reactions: Part 1—Reduction of Periodate Ion in the Presence of Toluene-p-sulphonate Anions

Alias, Kamaruzzaman; Fawcett, W. R. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

The influence of adsorbed toluene-p-sulphonate ions on the rate of electroreduction of periodate ions at mercury has been studied as a function of electrode potential and bulk concentration of the adsorbing ions in solutions ...
Solvent Effects in the Kinetics of Fast Proton-transfer Reactions: Diffusion, Preliminary Complexes, and Steric Factors

Burfoot, Graham D.; Caldin, Edward F.; Goodman, Howard (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

The kinetics of the reaction of tri-n-butylamine with the substituted phenol tetrabromophenol- phthalcin ethyl ester (Bromophthalein Magenta E) in various solvents have been investigated, by a microwave temperature-jump ...
Electron paramagnetic resonance study of hydrogen atoms trapped in γ-irradiated Y type zeolites exchanged with different cations

Abou-Kais, Antoine; Vedrine, Jacques C.; Massardier, Jean; Dalmai-Imelik, Gisele (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

H atoms trapped after the γ-irradiation at 77 K of Y type zeolites exchanged with different cations have been studied using e.p.r. spectroscopy. The H atom yield is dependent on the acidic structural OH group content and ...
Experimental Determination of Heats of Formation of Negative Ions and Electron Affinities of Several Boron and Aluminium Fluorides

Srivastava, R. D.; Uy, O. M.; Farber, Milton (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

Thermodynamic properties for the negative ions of boron and aluminium fluorides were obtained by means of the effusion-mass spectrometric method over the temperature range 1100 to 1900 K. Studies were conducted involving ...
Oxidation of a Pyrophoric Iron: Part 2. Direct Measurement of Self-heating Accompanying Chemisorption of Oxygen on the Finely Divided Iron-Carbon Substrate

Galwey, Andrew K.; Gray, Peter (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

The self-heating accompanying the exposure to oxygen of a pyrophoric iron (here a finely divided iron-carbon preparation from an iron mellitate) has been studied quantitatively. In particular, temperature histories have ...
Light Scattering from the Free Surface of Water

Langevin, D. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

The spectrum of light scattered by thermally excited surface waves on water has been investigated and the value of the surface tension and, after careful analysis of instrumental broadening, the value of the viscosity ...
Kinetics of Electrode Reactions in Liquid Ammonia: Part 3.—The Silver Electrode in Acid Solution

Brown, Oliver R.; Thornton, Sean A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

The behaviour of the silver electrode in acid solutions of liquid ammonia has been studied by steady and non-steady state electrochemical measurements and electron microscopy. The apparent rate constant and standard potential ...
Molecular Complexes: Part 12- Use of Phase Distribution and Nuclear Magnetic Resonance Methods to Elucidate the Mechanism of the Acetone + Benzene Reaction

Homer, John; Cooke, Melvyn C. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

The results of studies of the acetone+benzene interaction obtained from a phase distribution technique and the conventional n.m.r. approach are compared. This reveals that the conventional n.m.r. approach to studies of ...

Now showing items 361-380 of 815

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