Journal Archive Collections: Recent submissions

  • Rate of Polymorphic Transformation Between Phases II and III of Hexachloroethane 
    Koga, Yoshikata; Miura, Robert M. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (07), 1978)
    The temperature dependent growth rate of the stable phase near the transition point between phases II and III of hexachloroethane (C2Cl6) was measured by dilatometry. Reproducible results were obtained by repetitive cycling ...
  • Chemical Energy Accommodation at Catalyst Surfaces Flow Reactor Studies of the Association of Nitrogen Atoms on Metals at High Temperatures 
    Halpern, Bret; Rosner, Daniel E. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (07), 1978)
    The fate of the energy release in highly exoergic surface-catalysed chemical reactions is of considerable fundamental interest and influences catalyst volatilization/sintering, the aerodynamic heating of hypersonic glide ...
  • Self-diffusion Coefficients of Water in Pure Water and in Aqueous Solutions of Several Electrolytes with 1SO and 2H as Tracers 
    Tanaka, Kazuko (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (07), 1978)
    The self-diffusion coefficients of water in pure water and in aqueous electrolyte solutions have been measured by using the sintered glass diaphragm cell technique with 2H and 18O as tracers. The extrapolated value from ...
  • Sorption Behaviour of Silanated H-Mordenite 
    Barrer, R. M.; Vansant, E. F.; Peeters, G. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (07), 1978)
    The changes in the sorption behaviour of H-mordenite resulting from the primary chemisorption of SiH4, secondary reactions and oxidation of chemisorbed SiHx with H2O have been investigated, using O2, N2 and CO as sorbates ...
  • Structural Analysis of Some Molten Materials by X-ray Diffraction Part 5.—LiCl, PbCL and their Mixtures 
    Ohno, Hideo; Yoroki, Mitsugu; Furukawa, Kazuo; Takagi, Yoshiki; Nakamura, Tetsuro (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (07), 1978)
    The molten structure of PbCl2, LiCl and their mixtures were examined by X-ray diffraction analysis. In molten Pbcl2, each Pb atom is surrounded by about eight Cl atoms at a distance of 2.92 Å, which is near to the sum of ...
  • Nuclear Magnetic Relaxation Studies of Preferential Solvation in Electrolyte Solutions Another Indirect Method Using only Solvent Magnetic Interactions 
    Capparelli, Alberto L.; Gill, Dip S.; Hertz, H. Gerhard; Tutsch, Rüdiger (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (07), 1978)
    In the mixture ROH/H2O (R = CnD2n+1) an intramolecular proton relaxation contribution due to magnetic dipole interaction only occurs in the water molecule. If the water molecules are preferentially bound to a hydrated ...
  • Nuclear Magnetic Relaxation Studies of Preferential Solvation in Electrolyte Solutions 
    Capparelli, Alberto L.; Gill, Dip S.; Hertz, H. Gerhard; Tutsch, Rüdiger; Weingärtner, Hermann (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (07), 1978)
    Formulae are derived which describe the increase in the total proton magnetic relaxation rate relative to the intramolecular relaxation rate in a solvent mixture when solvent molecules of one kind are enriched in the ...
  • Thermal Ummolecular Reactions of Vinvlcvelnl . Isopropenylcyclobutane 
    Frey, Henry M.; Pottinger, Ruth (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (07), 1978)
    The thermal decomposition of vinylcyclobutane proceeds by two pathways both of which are homogeneous first order processes. One reaction channel (k1) yields butadiene and ethylene, the other (k2) cyclohexene. Arrhenius ...
  • Thermal unimolecular reactions of vinylcyclobutane and isopropenylcyclobutane 
    Frey, Henry M.; Pottinger, Ruth (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (07), 1978)
    The thermal decomposition of vinylcyclobutane proceeds by two pathways both of which are homogeneous first order processes. One reaction channel (k1) yields butadiene and ethylene, the other (k2) cyclohexene. Arrhenius ...
  • Laser Flash Photolysis Study of the Photoionisation of Chlorpromazine and Promazine in Solution 
    Navaratnam, Suppiah; Parsons, Barry J.; Phillips, Glyn O.; Davies, A. Keith (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (07), 1978)
    Solutions of promazine hydrochloride and chlorpromazine hydrochloride have been flash photolysed with 25 ns pulses of 347.1 nm light from a frequency-doubled ruby laser. In addition to the excited triplet states of these ...
  • Kinetics of the Reaction Between 2,4-Dinitrophenol and Tri-n-octylamine in Chlorobenzene Solution Diffusion and other Rate-limiting Factors 
    Caldin, Edward F.; Tortschanoff, Karl (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (07), 1978)
    The kinetics of the reaction between 2,4-dinitrophenol and tri-n-octylamine in chlorobenzene solution have been investigated by a microwave temperature-jump technique. The rate constant is about 30 times smaller than the ...
  • Kinetic Isotope Effects in the Reactions of 4-Nitrophenylnitromethane with Alkylamidine Bases in Toluene 
    Caldin, Edward F.; Rogne, Otto; Wilson, Christopher J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (07), 1978)
    Kinetic isotope effects have been determined for the proton-transfer and deuteron-transfer reactions of 4-nitrophenylnitromethane (4-NPNM; NO2C6H4CH2NO2, NO2C6H4CD2NO2) with two alkylamidine bases [HN = C(NEt2)R; R = ...
  • Characterization of the Hydroxyls in Offretitc Zeolite 
    Mirodatos, Claude; Abou-Kais, Antoine; Vedrine, Jacques C.; Barthomeuf, Denise (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (07), 1978)
    It is shown that three structural hydroxyl groups are generated in offretite upon cation exchange. The 3660 cm–1 OH groups are either not acidic or only slightly so and are probably located in the inaccessible hexagonal ...
  • Far-Ultraviolet Solution Spectroscopy of Chloride Ion 
    Fox, Malcolm F.; Barker, Barry E.; Hayon, Elie (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (07), 1978)
    The far-ultraviolet absorption spectra of chloride ion have been studied in a large variety of solvents and over a large range of temperatures. Solvents used include both blue- and red-shifting solvents for charge-transf ...
  • Thermodynamic Study of Deuterium Exchange in Water-;-Methanol Systems 
    Fenby, David V. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (07), 1978)
    Molar excess enthalpies are reported for the systems H2O + CH3OH, H2O + CH3OD, H2O + CD3OD, D2O + CH3OH, D2O + CH3OD and D2O + CD3OD at 298.15 K. The results are analysed to give the enthalpies of the deuterium exchange ...
  • Ionic Activities in Sodium Dodecyl Sulphate Solutions from Electromotive Force Measurements 
    Cutler, Sidney G.; Meares, Patrick; Hall, Denver G. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (07), 1978)
    Measured surfactant ion activities (a1) and counterion activities (a2) in solutions of sodium dodecyl sulphate (SDS) in the presence and absence of NaCl are reported. The results show that premicellar association is ...
  • Correlation of the Catalytic Activities of Oxides with their Work-functions 
    Bhattacharya, Ashok K. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (07), 1978)
    The catalytic recombination of oxygen atoms has been studied on powdered samples of Li+ doped (0–1.26 atom %) nickel oxides in the temperature range 20–50°C. It is found that the energy of activation for this reaction is ...
  • Living ” Radical Polymerizations of Vinyl Monomers Initiated by Aged “ Cr2 --BPO ” in Homogeneous Solution 
    Lee, Munam; Morigami, Tadashi; Minoura, Yuji (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (07), 1978)
    Monomer is added to chromium(II) acetate (Cr2+) and benzoyl peroxide (BPO) previously treated at 10°C in dimethylformamide (DMF)(the ageing process), and polymerizations are performed. It is found that the degree of ...
  • Polymerization of Vinyl Monomers Initiated by Chromium(n) Acetate-i-Organic Peroxides 
    Lee, Munam; Minoura, Yuji (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (07), 1978)
    The redox initiator systems consisting of chromium(II) acetate (Cr2+) and organic peroxides are studied in dimethylformamide (DMF) at low temperatures. The second-order rate constants of reduction of benzoyl peroxide (BPO) ...
  • Evolution of Adsorbed Species During C2H2 Adsorption on Ni(l 11) in Relation to their Vibrational Spectra 
    Bertolini, Jean-Claude; Massardier, Jean; Dalmai-Imelik, Gisèle (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (07), 1978)
    Acetylene adsorption at room temperature on Ni (111) has been studied by low energy electron diffraction (l.e.e.d.), thermal desorption, work function changes and high resolution electron energy loss spectroscopy (h.r.e.l.s.). ...

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