Journal Archive Collections: Recent submissions

  • Kinetics of the hydrogen reduction of nickel ions in silica–magnesia 
    Briend-Faure, Marguerite; Delafosse, Denise (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (06), 1977)
    The H2 reduction of Ni2+-substituted silica–magnesia gel was studied in the ranges 613–753 K and 1.3–13 kN m–2. The reaction is slow and requires an activation energy of 174 ± 20 kJ mol–1. The rate varies with the hydrogen ...
  • Work and entropy of adhesion at liquid–liquid interfaces and the relationship to salt desorption 
    Aveyard, Robert; Saleem, Syed M. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (06), 1977)
    Works of adhesion of cyclohexane, toluene, chloro-octane and nonan-2-one, with water, have been determined as a function of temperature. From these results, and others in the literature, it is shown that a rectilinear ...
  • Thermolysis of 2-ethyloxetan 
    Clarke, Michael J.; Holbrook, Kenneth A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (06), 1977)
    The gas-phase thermolysis of 2-ethyloxetan has been studied at temperatures between 699 and 752 K and at initial pressures from 0.45 to 32.5 Torr.† The stoichiometries of the reactions involved correspond closely with the ...
  • Infrared study of the surface of silica immersed in liquid mixtures of hydrocarbons 
    Rochester, Colin H.; Trebilco, Deborah-Anne (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (06), 1977)
    A simple infrared cell is described which enables studies to be made of the perturbation of surface hydroxyl groups caused by the immersion of powdered oxides in hydrocarbon solvents. Results are presented for silica in ...
  • Far-ultraviolet solution spectroscopy of the bromide ion 
    Fox, Malcolm F.; Hayon, Elie (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (06), 1977)
    The far ultraviolet absorption spectra of the bromide ion have been studied in a large variety of solvents and over a wide range of temperatures. The solvents used include those which are strongly red-shifting or blue-shifting, ...
  • Effect of cyano-group substitution of rates of metathetical reactions. Part 2.—Abstraction of chlorine atoms by cyclohexyl radicals from CHCl2CN and CH2ClCN 
    Gonen, Yued; Horowitz, Abraham; Rajbenbach, Leon A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (06), 1977)
    Temperature dependence of the liquid phase radiation induced abstraction of chlorine atoms by cyclohexyl radicals from CHCl2CN and CH2ClCN was studied competitively. Reactions involved are c-C6H11+ CHCl2CN→c-C6H11Cl + ...
  • Excited states of protoporphyrin IX dimethyl ester: reaction on the triplet with carotenoids 
    Chantrell, Susan J.; McAuliffe, Charles A.; Munn, Robert W.; Pratt, Albert C. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (06), 1977)
    The triplet and singlet excited states of protoporphyrin IX dimethyl ester (PPIXDME) have been identified by means of pulse radiolysis experiments in benzene solution. The absorption spectrum, extinction coefficients, ...
  • Electrochemical luminescence of rubrene dissolved in benzonitrile in thin cells 
    Dunnett, James S.; Voïnov, Michel (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (06), 1977)
    The electrochemical luminescence of rubene in benzonitrile was generated in cells with path length 20–40 µm by passing a direct current. The luminescence yield, corrected for refractive index losses, increases from 0.008 ...
  • Interpretation of the “Intermediate Frequency” Dielectric Spectra of Synthetic Zeolites X 
    Ravalitera, Guy; Carru, Jean-Claude; Chapoton, Alain (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (06), 1977)
    The dielectric spectra of synthetic zeolites X (13X and 10X) were studied in the frequency range 1 Hz-4 GHz at T=+ 25°C on samples hydrated at various rates. They all showed a distributed “intermediate frequency” relaxation ...
  • Determination of Electronic Transference Numbers of Polymers 
    Petit, Michel A.; Jozefowicz, Marcel (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (06), 1977)
    Liang's method has been employed under new conditions to determine electronic transference numbers of polymers using the sandwich cell (Ag–AgI–polymer–graphite). In this cell, when the graphite electrode is polarized by a ...
  • Physico-Chemical Studies in Nonaqueous Solvents Part 13.—Thermochemical Studies of some 1; 1 electrolytes in Tetramethylurea 
    Paul, Jauhar, Surinder P. Ram C.; Banait, Narula, Suraj P. Jagtar S. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (06), 1977)
    Heats of solution of alkali metal, ammonium and substituted ammonium perchlorates, lithium and sodium bromides and sodium and potassium thiocyanates have been measured in the concentration range 1.75-67.7×10−3 mol dm−3 in ...
  • Solute interactions in dilute aqueous solutions. Part 3.—Volume changes associated with the hydrophobic interaction 
    Franks, Felix (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (05), 1977)
    Second virial coefficients in the excess volume equation have been evaluated for BuOH, BuiOH, BusOH and ButOH in dilute aqueous solution at several temperatures. The coefficients are negative and decrease in magnitude with ...
  • Ring-disc electrodes. Part 17.—Ring response to periodic disc electrode forcing functions 
    Bruckenstein, Stanley; Tokuda, Koichi; Albery, W. John (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (05), 1977)
    The theory of ring electrode response to any periodic forcing function at the disc electrode of a ring-disc electrode has been derived and varified for a square wave current function using the ferri–ferrocyanide system.
  • Dissociation of 2-methylbut-1-ene and the resonance energy of the 2-methyl allyl radical 
    Trenwith, Antony B.; Wrigley, Stephen P. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (05), 1977)
    The pyrolysis of 2-methylbut-1-ene has been investigated over the temperature range 671–722 K and pressures between 50 and 500 Torr. Values for the limiting high pressure rate constant of the dissociation reaction ...
  • Comparison of the mechanisms of the thermal decompositions of 2,2′-azisobutane and azoisopropane 
    McKay, Gordon; Turner, James M. C.; Zaré, Farhad (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (05), 1977)
    The gas phase pyrolyses of 2,2′-azoisobutane and azoisopropane have been investigated in the temperature range 471–573 K. The products of 2,2′-azoisobutane (AIB) decomposition result from the following elementary reactions. ...
  • Infrared spectra from binuclear bridging complexes of sulphate adsorbed on goethite (α-FeOOH) 
    Parfitt, R. L.; Smart, R. St. C. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (05), 1977)
    Spectra of sulphate adsorbed on synthetic goethite (α-FeOOH) show replacement of A-type (one coordinated to Fe3+) surface hydroxyls and the formation of adsorbed sulphate groups with C2v symmetry. High affinity adsorption ...
  • Hydration and dimerization of some aliphatic carboxylic acids in benzene as studied by partition 
    Fujii, Yukio; Tanaka, Motoharu (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (05), 1977)
    The hydration and dimerization of some aliphatic carboxylic acids have been studied by partition. Monomer monohydrate, dimer mono- and tri-hydrates have been formed in benzene contacted with water. The formation constant ...
  • Photolysis of alkyloxy vanadium(V) chelates. A possible general route to alkyloxy radicals 
    Aliwi, Salah M.; Bamford, Clement H. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (05), 1977)
    We have studied the photochemical reactions (λ= 365 nm) of nineteen vanadium(V) chelates of structure VOQ2OR where Q is the 8-quinolyloxo ligand and R is an alkyl group. In all cases photolysis proceeds in a first-order ...
  • Conductance of some alkali metal halides in dilute aqueous solution at 25°C 
    Pethybridge, Alan D.; Spiers, David J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (05), 1977)
    Precise conductivity results are reported for dilute aqueous solutions of lithium, rubidium and caesium fluorides and for lithium bromide and iodide and sodium iodide at 25°C. The results are analysed in terms of both the ...
  • Spectral distributions of photo-electrochemical reactions over metal phthalocyanine electrodes 
    Meshitsuka, Shunsuke; Tamaru, Kenzi (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (05), 1977)
    The spectral distributions of photo-electrochemical currents over cobalt, nickel and copper phthalocynanines were measured in the region 340 to 800 nm. Two distinctive spectra were obtained for each metal phthalocyanine, ...

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