Journal Archive Collections: Recent submissions

  • Semiconducting Oxides The Effect of Prior Annealing Temperature on Dissolution Kinetics of Nickel Oxide 
    Jones, Colin F; Segall, Robert L; Smart, Roger St. C; Turner, Peter S (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (11), 1977)
    The paper describes studies of the dissolution rate of NiO (a p-type semiconductor) in nitric acid solution at 60°C as a function of prior annealing temperature in air. The dissolution rate per unit surface area decreased ...
  • Transformation of some Saturated Hydrocarbons on Iridium, Rhodium and Ruthenium Blacks 
    Sarkany, Antal; Matusek, Karoly; Tetenyi, Pal (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (11), 1977)
    The adsorption and deuterium exchange of methane and ethane and the hydrogenolysis and isomerization of ethane, butanes and some C5 hydrocarbons have been investigated on Ru, Rh and Ir blacks. Product distribution patterns, ...
  • Thiocyanate Adsorption and Corrosion at Silver Electrodes A Raman Spectroscopic Study 
    Cooney, Ralph P; Reid, Euan S; Fleischmann, Martin; Hendra, Patrick J (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (11), 1977)
    Laser Raman spectra have been obtained from silver electrode surfaces in contact with acidic and basic solutions containing thiocyanate ions. At pH 2.8, spectra obtained in the potential interval –0.8 (s.c.e.) to –0.4 V ...
  • Prediction of Infinite Dilution Activity Coefficients in Binary n-Alkane Mixtures 
    Laub, Richard J; Martire, Daniel E; Purnell, J. Howard (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (11), 1977)
    The Janini–Martire modification of Prigogine's theory of chain molecule mixtures is further tested via a comparison of predicted infinite dilution activity coefficients (γ∞1) and currently available experimental values. ...
  • Hydroisomerization and Hydrocracking of n-Pentane(3-C13) with Type Y Zeolite 
    Weeks, Thomas J; Bolton, Anthony P (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (11), 1977)
    Highly enriched n-pentane(3-13C) in the presence of hydrogen has been used to investigate the mechanisms of hydroisomerization and hydrocracking over a calcined and reduced palladium on ammonium exchanged type Y zeolite. ...
  • Mass Spectrometric Determination of the Heats of Formation of the Silicon Subchlorides SiCl(g), SiCl2(g) and SiCl3(g) 
    Farber, Milton; Srivastava, Rameshwar D (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (11), 1977)
    An effusion-mass spectrometric determination of the reaction of SiCl4(g) with Si(c, l) in the temperature range 1593–1792 K has been completed. Second and third law reaction enthalpies were obtained for SiCl4(g)+ Si(g)= ...
  • The Oxygen Electrode Part 8.—Oxygen Evolution at Ruthenium Dioxide Anodes 
    Burke, Laurence D; Murphy, Oliver J; O’Neill, John F; Venkatesan, Srinivasan (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (11), 1977)
    The electrocatalytic behaviour of Ti-supported RuO2, prepared by thermal decomposition of RuCl3, as substrate for oxygen evolution was investigated by a variety of techniques. B.E.T. adsorption experiments showed that the ...
  • Selectivity of a Heterogeneous Rhodium Catalyst for the Carbonylation of Monohydric Alcohols 
    Christensen, Bjarne; Scurrell, Michael S (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (12), 1977)
    The carbonylation activity of a heterogeneous rhodium-zeolite catalyst has been examined for the reactions of methanol, ethanol and propan-2-ol. A marked contrast in the behaviour of these three alcohols is seen. Selectivity ...
  • Pulse Radiolysis Study of the Reaction of Solvated Electrons with Sulphur Hexafluoride in Methanolic Solution 
    Johnson, David W; Salmon, G. Arthur (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (12), 1977)
    The rate constant for the reaction of e–s with SF6 in deaerated methanolic solution has been determined to be k3=(1.88 ± 0.06)× 1010 dm3 mol–1 s–1. The product of this reaction, ·SF5, has an absorption spectrum with a ...
  • Reaction of Oxygen Atoms with Nitromethane and with Nitroethane 
    Salter, Leo F; Thrush, Brian A (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (12), 1977)
    The reaction of oxygen atoms with nitromethane and nitroethane has been studied in a discharge flow system at temperatures between 294 and 473 K. The initial attack involves abstraction of a hydrogen atom, for which the ...
  • Photolysis of 3-Methyl-3-chlorodiazirine 
    Frey, Henry M; Penny, David E (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (12), 1977)
    The photolysis of 3-methyl-3-chlorodiazirine has been investigated in the gas phase at pressures (with added bath gases) up to 6000 Torr (800 kPa). The principal products were vinyl chloride, nitrogen, acetylene, hydrogen ...
  • Theory of Compartmentalised Free-Radical Polymerisation Reactions 
    Birtwistle, David T; Blackley, David C (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (12), 1977)
    Explicit analytic solutions are given for nr, the number of reaction loci per unit volume containing r radicals, as a function of time, t, for the case of a seeded emulsion polymerisation which fulfils the following ...
  • Infrared Study of the Adsorption of [2H4]Acetic Acid on to Rutile 
    Griffiths, David M; Rochester, Colin H (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (12), 1977)
    Infrared spectroscopic studies are reported of the adsorption of [2H4]acetic acid onto three samples of rutile which differed in their extents either of hydration or of reduction. Acetic acid was associatively adsorbed on ...
  • van der Waals Interaction between Mica Surfaces: Comparison of Theory and Experiment 
    Gregory, John (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (12), 1977)
    Published experimental results for the interaction of crossed mica cylinders are compared with theoretical predictions based on a simple London–Hamaker approach, using only one dispersion frequency in the ultraviolet. ...
  • Structure and Catalytic Activity of CoxMg1_YA12O4 Spinel Solid Solutions Part 1.—Cation Distribution of Co2+ Ions 
    Angeletti, Carlo; Pepe, Franco; Porta, Piero (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (12), 1977)
    The cation distribution in CoAl2O4 and in several CoχMg1–χAl2O4 solid solutions with χ ranging from 0.05 to 0.5 has been studied by magnetic susceptibility, reflectance spectroscopy, lattice parameter variation and analysis ...
  • Luminescence Following Laser Excitation of Trapped Electrons in Mixed-Solute Aqueous Glasses 
    Nguyen, Tuan Q; Walker, David C (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (12), 1977)
    Based on measurements of the luminescence produced when infrared-absorbing electron states (e–ir) at 77 K decay, it is contended that this electron state is normally to be expected in irradiated aqueous media and is not ...
  • Conductometric Investigation of Complexes of Trifluoroacetic Acid with Hexaoxa-“ Crown ” Ethers 
    Nae, Nehemia; Grodzinski, Joseph Jagur (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (12), 1977)
    The complexation of trifluoroacetic acid with two hexaoxa-“crown” ethers (18/CR/6 and DCC/A) in 1,2-dichloroethane was investigated conductometrically. The equilibrium constants of complex formation are of the same order ...
  • Kinetics of Activated Chemisorption Pari 3.—Amount and Distribution of Adsorbate at Varying Temperatures and Pressures 
    Aharoni, Chaim; Ungarish, Moshe (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (12), 1977)
    The heterogeneous-surface model applied in Part 2 to the kinetics, is now applied to the effects of temperature and pressure on the amount adsorbed. It predicts isobars with a maximum that is displaced towards higher ...
  • Electrolyte Viscosities in Hexamethylphosphotriamide at 25 C 
    Sacco, Antonio; Petrella, Giuseppe; Monica, Mario Della; Castagnolo, Maurizio (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (12), 1977)
    Viscosities of several uni-univalent electrolytes in hexamethylphosphotriamide (HMPT) at 25°C have been measured. Data were analysed by the Jones–Dole equation, and the B-coefficients discussed on the basis of Einstein's ...
  • Kinetics of the Thermal Gas-Phase Decomposition of 1,2-Epoxypropanet 
    Flowers, Michael C (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (12), 1977)
    The kinetics of the gas-phase decomposition of 1,2-epoxypropane have been studied over the temperature range 654–717 K at pressures between 5 and 326 Torr. Unimolecular isomerizations to propanal, propanone, methyl vinyl ...

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