• Kinetics of the thermal unimolecular reactions of cyclopropane and cyclobutane behind reflected shock waves 

  Barnard, John A.; Cocks, Alan T.; Lee, Richard K-Y. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (09), 1974)

  The kinetics of the thermal reactions of cyclopropane and cyclobutane behind reflected shock waves have been studied in a single-pulse chemical shock tube. Comparisons of methods for obtaining reflected-shock temperatures ...
• Adsorption of Gases on Polycrystalline Nickel Films Studied by X-Ray and Ultra-violet Photoelectron Spectroscopy 

  Page, Peter J.; Trimm, David L.; Williams, Peter M. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (09), 1974)

  The adsorption of a series of gases onto clean evaporated films of polycrystalline nickel has been studied using ultraviolet and X-ray photoelcctron (u.p.e. and X.p.e. respectively) spectroscopy. Observation of the intensity ...
• Relative and absolute electrochemical quantities. Components of the potential difference across the electrode/solution interface 

  Trasatti, Sergio (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (09), 1974)

  The absolute value of the standard potential of the hydrogen electrode is calculated on the basis of a value of –263.1 kcal mol–1 for [graphic ommitted], the standard chemical free energy of hydration of the proton. This ...
• Interactions of Dienes and Alkynes with Rutile (Titanium Dioxide) 

  Halliday, Marlene M.; Kemball, Charles; Leach, H. Frank (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (09), 1974)

  The catalytic properties of titanium dioxide (rutile) have been examined for a number of reactions involving dienes (propadiene and buta-1,3-diene) or alkynes (ethyne, propyne and but-2-yne) with hydrogen, deuterium or ...
• Virial Analysis of Low-coverage Physical Adsorption Data on Heterogeneous Surfaces 

  Pierotti, Robert A.; Thomas, Howard E. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (09), 1974)

  The general treatment of the McMillan–Mayer theory of solutions is applied to low-coverage adsorption on heterogeneous surfaces. Expressions are derived for the second and third gas/solid virial coefficients for adsorption ...
• Calculation of the Interaction of Adsorption of Inert Gases on to the (100) Face of Sodium Chloride and Argon on to the (100) Face of Potassium Chloride 

  House, William A.; Jaycock, Michael J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (09), 1974)

  Calculations are presented for the adsorptive potential energy for inert gases on the (100) faces of NaCl and KCl. These are performed using the “exponential-six” equation to calculate dispersion and repulsion terms, and ...
• Quenching of the uranyl (UO 2+2) emission by inorganic ions in solution 

  Matsushima, Ryoka; Fujimori, Hidenobu; Sakuraba, Shukichi (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (09), 1974)

  Quenching constants (K) of various inorganic ions have been measured for the quenching of the uranyl emission in aqueous acid solution at room temperature. Quenching constants of halogen or halogen-like anions (X–) increase ...
• One-electron Reactions in Some Cobalamins 

  Blackburn, R.; Erkol, A. Y.; Phillips, G. O. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (09), 1974)

  Pulse radiolysis has been used to study the reaction of hydrated electrons and other agents with various cobalamins, viz. cyanocobalamin (vitamin B12), hydroxocobalamin (vitamin B12a), and cob(II)alamin (vitamin B12r). It ...
• Dehydration of Propan-2-ol on X Zeolites 

  Gentry, Stephen J.; Rudham, Robert (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (09), 1974)

  The dehydration of propan-2-ol on moderately protonated X zeolites leads to the formation of both propene and di-isopropyl ether at temperatures in the range 383-430 K. Unexchanged zeolite was considerably less active, and ...
• Dimerization and Cracking of [4-13C]But-l-ene with Deamminated Ammonium Exchanged Type Y Zeolite 

  Weeks, Thomas J.; Bolton, A. P. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (09), 1974)

  The use of highly enriched [4-13C]but-1-ene with an integrated gas chromatograph–mass spectrometer has enabled a better understanding of the mechanism of reaction between but-1-ene and deamminated ammonium exchanged type ...
• Kinetics and Kinetic Oscillation in Carbon Monoxide Oxidation 

  Yang, Ching H.; Berlad, Abraham L. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (09), 1974)

  A kinetic mechanism is proposed for the low temperature oxidation of carbon monoxide. A general mathematical model which conserves all reactants, catalytic impurities and intermediate species is formulated to contain all ...
• Measurement and prediction of equilibrium ratios for the C2H6+ CO2 system 

  Fredenslund, Aage; Mollerup, Jorgen (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (09), 1974)

  Isothermal vapour/liquid equilibrium compositions and pressures are determined for the C2H6+ CO2 system, which is known to form a minimum boiling azeotrope. A vapour recirculation apparatus was used in obtaining experimental ...
• Microcalorimetric studies: Enthalpies of formation of Cr(PF3)6 and Ni(PF3)4 

  S. Brown, D. Lalage; Connor, Joseph A.; Skinner, Henry A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (09), 1974)

  Measurements of the heats of iodination of hexakis(trifluorophosphine)chromium(0) and of tetrakis(trifluorophosphine)nickel(0) were carried out by high temperature microcalorimetry. Standard enthalpies of formation were ...
• The Medium Effect for Single Ionic Species 

  Parsons, Roger; Rubin, Barry T. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (09), 1974)

  The relation of the “ medium effect ” or “ solvent activity coefficient ” to the directly measurable real free energy of transfer is discussed. Measurements of the latter quantity for solutions in aqueous solvents containing ...
• Electrical Resistivity of Solutions of Germanium, Tin and Lead in Liquid Sodium 

  Hubberstey, Peter; Pulham, Richard J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (09), 1974)

  The electrical resistivity of solutions of germanium (up to 1.0 atom %), tin (up to 6.9 atom %) and lead (up to 7.8 atom %) in liquid sodium have been measured over the temperature ranges 200-450, 200-400 and 100-300 C ...
• Absorption of Hydrogen by Iridium/Palladiuni Substitutional Alloys 

  LaPrade, Marie; Allard, Kenneth D.; Lynch, James F.; Flanagan, Ted B (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (09), 1974)

  Thermodynamic parameters for absorption of hydrogen by Ir/Pd alloys have been determined by p, c, T techniques in an u.h.v. system and by electrochemical measurements. The equilibrium solubility of hydrogen in these alloys ...
• Ellipsometric Study of Organic Monolayers: Part 1.—Condensed Monolayers 

  Engelsen, Daan den; Koning, Bob de (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (09), 1974)

  The applicability of an ellipsometric method for the study of monolayers spread on water is described. Our ellipsometric measurements of condensed lipid monolayers are explained by use of a model based on the variation of ...
• Thermodynamic Study of Disorder in Hexa-amminenickel(II) Iodide and Diamminenickel(II) Iodide 

  Worswick, Richard D.; Cowell, Janice C.; Staveley, Lionel A. K. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (09), 1974)

  The heat capacity of crystalline nickel(II) iodide, diamminenickel(II) iodide and hexa-ammine-nickel(II) iodide has been determined from 10 to 300 K by conventional adiabatic low-temperature calorimetry, and from 300 to ...
• Dissociation Energies of BeF and BeCl and the Heat of Formation of BeCIF 

  Farber, Milton; Srivastava, Rameshwar D. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (09), 1974)

  An effusion-mass spectrometric investigation of the Be–Cl–F system to obtain bond energies of BeF and BeCl and the heat of formation of the mixed halide BeClF has been completed. A study of the ion intensities of the species ...
• Absorption and Emission Studies of Solubilization in Micelles: Part 2.—Determination of Aggregation Numbers and Solubilisate Diffusion in Cationic Micelles 

  Dorrance, Richard C.; Hunter, Thomas F. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (09), 1974)

  Excimer formation of pyrene is studied as a function of temperature in decyl-, dodecyl-, tetradecyl- and hexadecyl-trimethylammonium bromide (C10–C16TAB) micelles. The distribution of the solubilisate in the micelles is ...

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