• Diffusion in Crystalline Hexamethyldisilane 

  Saltmouse, Peter W; Sherwood, John N (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (11), 1977)

  An examination has been made of plastic deformation and of diffusion of hexamethylethane-14C in the highly plastic phase of hexamethyldisilane. The results are consistent with most previous studies of this type of material.
• Belousov-Zhabotinskii Oscillating Reaction in Solutions containing Gallic Acid 

  Babu, J. Sreekantha; Srinivasulu, K (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (11), 1977)

  Chemical oscillations are observed in a Belousov–Zhabotinskii type reaction using gallic acid rather than malonic acid.
• Activation Enthalpy of Diffusion for Iodine in Mixed Solvents 

  Nakanishi, Koichiro; Nishimoto, Yasunobu (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (11), 1977)

  The diffusion coefficients of iodine diluted in two different binary mixed solvents have been measured as a function of temperature. The enthalpy of activation of diffusion was evaluated from the Arrhenius plot of the data ...
• Closed Capillary Method for Tracer Diffusion Measurements in Liquids 

  Passiniemi, Pentti; Liukkonen, Simo; Noszticzius, Zoltan (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (11), 1977)

  A continuous closed capillary method is described in which the lower half of the capillary is filled at the beginning of the experiment with radioactive solution and the upper half with inactive solution. Measurement of ...
• Heterogeneous Catalysis in Solution Part 15.1—Theoretical Treatment of Parallel First-Order Catalysed and Uncatalysed Reactions 

  Spiro, Michael (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (11), 1977)

  A general treatment is presented of first-order or pseudo-first-order reactions proceeding both homogeneously in solution or the gas phase and heterogeneously on a catalytic surface. Rapid adsorption and desorption are ...
• Adsorption and Oxidation of Dimethylaniline by Laponite 

  Vansant, Etienne F; Yariv, Shmuel (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (11), 1977)

  Coloration of synthetic Laponite by dimethylaniline was studied in relation to the adsorption data, and to different reaction conditions including the nature of the exchangeable cations, the pH and the concentration. Using ...
• Charge Density Effects in Ion Exchange Pari 1.—Heterovalcnt Exchange Equilibria 

  Maes, Andre; Cremers, Adrien (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (11), 1977)

  A thermodynamic study is made of the Na–Ca heterovalent exchange reaction in 4 montmorillonite clay minerals with complete octahedral isomorphic layer charge but varying in charge density (Otay, three Camp Berteau samples ...
• Solvation Spectra Part 54.1—A Low Temperature Infrared Spectroscopic Study of the Solvation of Ions in Methanol 

  Strauss, Imants M; Symons, Martyn C. R (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (11), 1977)

  Broad featureless bands in the O—H stretching region for CH3OH in CH3OD containing a range of 1:1 electrolytes become narrower on cooling below the glass point and usually display several features. Lithium and sodium salts ...
• Mass Spectrometric Study of the Thermal Decomposition of 1,3,5-Trinitrohexahydro-l ,3,5-triazine (RDX) 

  Bradley, John N; Butler, Alan K; Capey, William D; Gilbert, James R (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (11), 1977)

  The thermal decomposition of RDX has been studied over the temperature range 130–230°C under free molecular flow conditions which allow reactions in the gas phase and reactions in the condensed phase to be clearly ...
• Transport in Aqueous Solutions of Group IIB Metal Salts at 298.15 K Part 2.—Interpretation and Prediction of Transport in Dilute Solutions of Cadmium Iodide : An Irreversible Thermodynamic Analysis 

  Paterson, Russell; Anderson, John; Anderson, Stephen S; Lutfullah (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (11), 1977)

  The transport data of Part 1 have been used to obtain the binary mobility coefficients (Lik) and corresponding resistance coefficients (Rik) of the salt in the range 0.05–0.60 mol dm–3. It is shown that these binary mobility ...
• Transport in Aqueous Solutions of Group IIB Metal Salts at 298.15 K Part 1.—Isothermal Transport Properties of Cadmium Iodide 

  Paterson, Russell; Anderson, John; Anderson, Stephen S (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (11), 1977)

  The isothermal transport properties of aqueous cadmium iodide solutions have been measured in the range 0.05–0.60 mol dm–3. Transport numbers (t+) and solvent-fixed diffusion coefficients of the salt (Dv) were obtained, ...
• Redox Behaviour of Transition Metal Ions in Zeolites Part 6.—Reversibility of the Reduction Reaction in Silver Zeolites 

  Jacobs, Peter A; Uytterhoeven, Jan B; Beyer, Hermann K (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (11), 1977)

  In this paper is shown that hydrogen is formed by oxidative thermal desorption from Y-zeolite or mordenite containing highly dispersed silver metal in the cages. Upon thermal degassing above 573 K, hydrogen is desorbed ...
• Redox Behaviour of Transition Metal Ions in Zeolites Part 5.—Method of Quantitative Determination of Bidisperse Distributions of Metal Particle Sizes in Zeolites 

  Jacobs, Peter A; Linart, Jean Philippe; Nus, Hubert; UYTTERHOEVEN, JAN B (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (11), 1977)

  Temperature programmed reduction and oxidation techniques were used as a fast and quantitative method to determine the amount transition metal inside or outside the zeolite after a reductive treatment. The method has been ...
• Kinetic Studies of Olefin Polymerization on a Supported Ziegler Catalyst 

  Eley, Daniel D; Keir, Douglas A; Rudham, Robert (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (11), 1977)

  Microgravimetric measurements have been used to follow the polymerization of ethylene and propylene on a supported Ziegler catalyst prepared by treatment of MgO with TlCl4 followed by AlEt3. Polymerization between 273 and ...
• Nuclear Magnetic Resonance Studies of Liquid Crystal Phase Structure and Self-diffusion Coefficients in the System Lithium Perfluoro-octanoate+water 

  Tiddy, Gordon J. T (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (11), 1977)

  In the lithium perfluoro-octanoate + water system, the reversed hexagonal structure assigned previously to the highest surfactant concentration liquid crystalline phase is inconsistent with 19F n.m.r. observations, and an ...
• Ionic Product and Enthalpy of Ionization of Water from Electromotive Force Measurements 

  Covington, Arthur K; Ferra, M. Isabel A; Robinson, Robert A (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (11), 1977)

  New e.m.f. data have been obtained for the cell: Pt, H2|MOH,NX|AgX|Ag at 25°C where M, N = Li, Na, K, Cs and X = Cl, Br, from which the ionic product (Kw) of water can be obtained (pKw= 14.004). Application of a theory of ...
• Semiconducting Oxides The Effect of Prior Annealing Temperature on Dissolution Kinetics of Nickel Oxide 

  Jones, Colin F; Segall, Robert L; Smart, Roger St. C; Turner, Peter S (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (11), 1977)

  The paper describes studies of the dissolution rate of NiO (a p-type semiconductor) in nitric acid solution at 60°C as a function of prior annealing temperature in air. The dissolution rate per unit surface area decreased ...
• Transformation of some Saturated Hydrocarbons on Iridium, Rhodium and Ruthenium Blacks 

  Sarkany, Antal; Matusek, Karoly; Tetenyi, Pal (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (11), 1977)

  The adsorption and deuterium exchange of methane and ethane and the hydrogenolysis and isomerization of ethane, butanes and some C5 hydrocarbons have been investigated on Ru, Rh and Ir blacks. Product distribution patterns, ...
• Thiocyanate Adsorption and Corrosion at Silver Electrodes A Raman Spectroscopic Study 

  Cooney, Ralph P; Reid, Euan S; Fleischmann, Martin; Hendra, Patrick J (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (11), 1977)

  Laser Raman spectra have been obtained from silver electrode surfaces in contact with acidic and basic solutions containing thiocyanate ions. At pH 2.8, spectra obtained in the potential interval –0.8 (s.c.e.) to –0.4 V ...
• Prediction of Infinite Dilution Activity Coefficients in Binary n-Alkane Mixtures 

  Laub, Richard J; Martire, Daniel E; Purnell, J. Howard (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (11), 1977)

  The Janini–Martire modification of Prigogine's theory of chain molecule mixtures is further tested via a comparison of predicted infinite dilution activity coefficients (γ∞1) and currently available experimental values. ...

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