• y-Radiolysis of Methane Adsorbed on '/-Alumina Part 2.1—Kinetics ot Reactions Occurring During Irradiation 

  Norfolk, David J.; Swan, Timothy (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (07), 1978)

  An earlier study showed that γ-alumina surfaces outgassed above 570 K contain sites involving exposed lattice ions at which methane is chemisorbed during γ-irradiation. When the species so formed are heated they decompose ...
• Patterns of activity in the benzene–deuterium exchange reaction and the hydrogenation of benzene catalysed by evaporated metal films 

  James, Robert G.; Moyes, Richard B. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (07), 1978)

  The hydrogenation and exchange reactions of benzene with molecular deuterium catalysed by evaporated films of twelve transition elements (Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Ta, W, Re and Ir) have been examined in the region ...
• Gas-Liquid Chromatographic Studies of Thermodynamic Interactions in Ternary Systems Comprising Dinonylphthalate+Trinitrotoluene+Volatile Hydrocarbon 

  Perry, Robert W.; Tiley, Peter F. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (07), 1978)

  Gas–liquid chromatographic partition coefficients have been determined at 82°C for eleven hydrocarbons, aliphatic and aromatic, in the stationary phases di(3,5,5-trimethylhexyl)phthalate (DNP), and 2,4,6-trinitrotoluene ...
• Thermal reactions of perfluoromethyl and perfluoroacetyl manganese pentacarbonyls. Part 2.—Initiation of free-radical polymerization and formation of methyl(2-methyl 4-oxo-5,5,5-trifluoropentanoate) 

  Bamford, Clement H.; Mullik, Sanam U. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (07), 1978)

  This paper continues the study of the thermal reactions of low-molecular-weight analogues of macroinitiators carrying terminal Mn(CO)5 groups e.g. [graphic omitted]CF2 CF2 Mn(CO)5. The reactions of CF3Mn(CO)5 and CF3COMn(CO)5 ...
• Thermal reactions of methyl and acetyl manganese pentacarbonyls. Part 1.—Initiation of free-radical polymerization and formation of methyl(2-methyl 4-oxopentanoate) 

  Bamford, Clement H.; Mullik, Sanam U. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (07), 1978)

  The manganese pentacarbonyl derivatives CH3Mn(CO)5 and CH3COMn(CO)5 are low-molecular-weight analogues of macroinitiators which carry terminal Mn(CO)5 groups and their thermal reactions in methyl methacrylate at 100°C have ...
• Semiconducting oxides: infrared and rate studies of the effects of surface blocking by surfactants in dissolution kinetics 

  Jones, Colin F.; Segall, Robert L.; Smart, Roger St. C.; Turner, Peter S. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (07), 1978)

  For nickel oxide annealed at different temperatures (after preparation from the hydroxide), surface blocking by adsorbed anionic surfactant reduces dissolution rates per unit surface area in acid solution. Cationic and ...
• Semiconducting Oxides: Effects of Electronic and Surface Structure on Dissolution Kinetics of Nickel Oxide 

  Jones, Colin F.; Segall, Robert L.; Smart, Roger St. C.; Turner, Peter S. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (07), 1978)

  The effect of decreasing dissolution rate of nickel oxide per unit surface area in acid solution with increasing prior annealing temperature (700–1450°C) has been shown to occur over a wide range of pH. The linear dependence ...
• Calculations on Ionic Solvation Part 1.—Free Energies of Solvation of Gaseous Univalent Ions Using a One-layer Continuum Model 

  Abraham, Michael H.; Liszi, János (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (07), 1978)

  The electrostatic free energy of solvation of an ion has been calculated using a model in which an ion of radius a and dielectric constant εi= 1 is surrounded by a solvent layer of thickness (b–a) and dielectric constant ...
• Structure and catalytic activity of CoxMg1–xAl2O4 spinel solid solutions. Part 2.—Decomposition of N2O 

  Angeletti, Carlo; Pepe, Franco; Porta, Piero (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (07), 1978)

  The catalytic decomposition of N2O was studied on spinel catalysts of general formula CoxMg1–xAl2O4(x= 0 → 1). The bulk distribution of Co2+ ions is predominantly tetrahedral with a small fraction of Co2+ in octahedral ...
• Dehydrogenation and isomerization of n-butenes on mixed tin + antimony oxide catalysts 

  Irvine, Elizabeth A.; Taylor, Duncan (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (06), 1978)

  The dehydrogenation and concurrent isomerization of the three n-butenes have been investigated at 474 K on a range of mixed tin + antimony oxide catalysts outgassed at 698 K. The initial approximately zero order reaction ...
• Origin of Charge on Colloidal Particles in Butanol 

  Cooper, W. David; Marsden, Robert S. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (06), 1978)

  The electrophoretic mobilities of colloidal polystyrene, polytetrafluoroethylene and the carbon blacks Graphon and Black Pearls A dispersed in butanol have been determined. From changes in electrophoretic mobility caused ...
• Ionic Solvation in Water-FCo-solvent Mixtures Part 6.—Free Energies of Transfer of Single Ions from Water into Water + Dioxan Mixtures 

  Wells, Cecil F. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (06), 1978)

  The method used earlier to calculate the free energy of transfer of the proton from water into aqueous mixtures, ΔG0t(H+), and thereby to separate ΔG0t(HX) to produce ΔG0t(X–), has now been applied to water + dioxan mixtures. ...
• Resonance Raman spectra of carbonium ions adsorbed on porous Vycor glass 

  Yamamoto, Yoichiro; Yamada, Haruka (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (06), 1978)

  Measurements of Raman spectra for unstable intermediates adsorbed on porous Vycor glass (PVG) have been made. When 1,1-diphenylethylene (DPE) was adsorbed on PVG, some unstable intermediates, blue, green and yellow species, ...
• D2O-H2O Isotope Effect on Nuclear Magnetic Relaxation of Alkali Halide Nuclei and Preferential Solvation in Mixed Solvents 

  Holz, Manfred (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 74 (3), 1977)

  The effect of substitution of H2O by D2O on the nuclear magnetic relaxation of the ionic nuclei 23Na, 87Rb and 81Br, which all relax by quadrupole interaction, has been investigated in several NaBr and RbBr solutions. The ...
• Ionic Solvation in Water4-Co-solvent Mixtures Part 5: Free Energies of Transfer of Large Single Ions from Water into Water + Methanol with the “ Neutral ” Component Removed 

  Wells, Cecil F. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 74 (3), 1977)

  Values for the change in proton affinity, ΔPa, of large molecules on transferring them from water into mixtures of water with methanol have been calculated. –ΔPa for anions and ΔPa for cations represent an elimination of ...
• Gamma Radiolysis of Copper (ll) Nitrilotriacetate in Aqueous Solution 

  Bhattacharyya, Sudhindra N.; Srisankar, Elappulli V. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 74 (3), 1977)

  Aqueous solutions of copper (II) nitrilotriacetate (CuIINTA) were irradiated with 60Co-gamma rays in deaerated conditions as well as in the presence of various scavengers such as O2, N2O, NO–3, HCOO– and aliphatic alcohols. ...
• Percolation of Gases into (K, Ca)-A Zeolites and their Cation Distribution 

  Ohgushi, Tatsuo; Yusa, Atsushi; Takaishi, Tetsuo (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 74 (3), 1977)

  The sorption capacity of (K12–2xCax)–A zeolite was measured as a function of its composition, for O2, N2 and Ar at 77 and 90 K, and for n-butane at 298 and 323 K. The molecular sieving character of the zeolite changed ...
• Solid State Reversible Reactions: Thermal Behaviour of the Photoisomer of Bi[anthracene-9,10-dimethylene] 

  Mau, Albert W. H. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 74 (3), 1977)

  The reversible thermal reaction of the photoisomer of 6,7,14,15-tetrahydro-15,16[1′,2′]8,13[1″,2″]-dibenzenodibenzo [a,g]cyclododencene(bi[anthracene-9,10-dimethylene]) in the solid state has been investigated. The reaction ...
• Radicals Derived from 1,4-Disubstituted Anthraquinones: Further Evidence for Association of Quinones in Solution 

  McAlpine, Eoghan; Sinclair, Roy S.; Truscott, T. George (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 74 (3), 1977)

  The radicals derived from three 1,4-disubstituted anthraquinones containing NH;, NHMc and OH substituent groups have been studied in methanol solution using the technique of pulse radiolysis. Absorption spectra and rates ...
• Structure of Aqueous Solutions: Infrared Librational Band Study of Structure Making and Structure Breaking by Dissolved Electrolytes 

  James, David W.; Frost, Ray L. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 74 (3), 1977)

  The concentration dependence of the infrared libration band of water has been studied for forty- six electrolytes and normalised first and second band moments have been calculated. Changes in the band parameters give ...

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