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Now showing items 1-20 of 552

Studies of Free Radical Reactions in Molten Salts by Glow-Discharge Electrolysis: Part 1.—Molten Nitrates

Hamilton, L. W.; Ingram, M. D. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (4), 1972)

The chemical effects of glow-discharge electrolysis (GDE) have been investigated for molten nitrate electrolytes. The yields are characteristically different from those of conventional electrolysis; for example nitrite and ...
Excited Products in the Photodissociation of Methyl Thiocyanate and Isothiocyanate in the Vacuum Ultra-violet

D’Amario, P.; Stefano, G. Di; Lenzi, M.; Mele, A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (5), 1972)

Photolysis of CH3NCS and CH3SCN in the vacuum u.-v. produces fluorescence attributed to SCN excited radicals. In the case of CH3SCN production of CNB2∑+ system is also found. The threshold wavelength of incident photons ...
Radiation Chemistry and Photochemistry of Oxychlorine Ions: Part 1.—Radiolysis of Aqueous Solutions of Hypochlorite and Chlorite Ions

Buxton, G. V.; Subhani, M. S. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (5), 1972)

The radiolysis of aqueous solutions of ClO– and ClO–2 has been investigated using pulse and steady state methods. The absorption spectrum of ClO has been identified (λmax= 280 nm) and the complete reaction mechanism has ...
Radiation Chemistry and Photochemistry of Oxychlorine Ions: Part 2.—Photodecomposition of Aqueous Solutions of Hypochlorite Ions

Buxton, G. V.; Subhani, M. S. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (5), 1972)

The photodecomposition of alkaline aqueous solutions of hypochlorite ion has been investigated using steady state and flash photolysis techniques. At 365 nm the primary products are O(3P), O–, Cl and Cl– formed by the ...
Radiation Chemistry and Photochemistry of Oxychlorine Ions: Part 3.—Photodecomposition of Aqueous Solutions of Chlorite Ions

Buxton, G. V.; Subhani, M. S. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (5), 1972)

The steady state and flash photolysis of aqueous solutions of chlorite ion has been investigated. The primary photodecomposition reactions are ClO–2[graphic omitted]ClO–+ O (a), ClO–2[graphic omitted]ClO–+ O–(b), ClO–2[graphic ...
Homogeneous Catalysis by Pt(Il)-Sn(II) Chloride Complex: Part 2.—Mechanism of the Isomerization of n-Butenes

Hirabayashi, Kazuo; Saito, Shuji; Yasumori, Iwao (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (5), 1972)

The mechanism of the isomerization of n-butencs catalyzed by a methanolic solution of Pt(II)- Sn(II) chloride complex has been studied by kinetic, mass-spcctromctric and microwave-spectro scopic measurements. This ...
Kinetics of Reaction of Metal Alkyls with Alkenes: Part 8.—Oligomerization of Ethylene by n-Butyl-lithium- NNN'N'-Tetramethylethylenediamine

Hay, J N; McCabe, J F; Robb, J C (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (7), 1972)

n-Butyl-lithium (BuLi) in the presence of NNN′N′-tetramethylethylenediamine (TMEDA) progressively adds on ethylene molecules to produce a linear alkyl-lithium compound. This oligomerization has been studied at low pressure, ...
Enthalpy of Solvation of Carbonium Ions

Gold, V. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (9), 1972)

Literature data on the rate of hydrolysis of t-butyl chloride and of the acid-catalyzed hydration of isobutene, both in dilute aqueous solution, have been combined with thermochemical data to yield standard heats of formation ...
Kinetic Equations for Consecutive Reversible Reactions with Special Reference to Protein Denaturations

Hijazi, Nasrat H.; Laidler, Keith J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (7), 1972)

The interconversion of the native (N) and denatured (D) form of a protein sometimes exhibits simple exponential kinetic behaviour consistent with the mechanism N⇌D. Sometimes, however, logarithmic plots of the variation ...
Dynamic Contact Angles: Part 7.1 Impact Spreading of Water Drops in Air and Aqueous Solutions of Surface Active Agents in Vapour on Smooth Paraffin Wax Surfaces

Elliott, T. A.; Ford, D. M. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (10), 1972)

A drop of pure water impacting on a horizontal solid surface passes through a series of characteristic shapes which are, within specific limits, independent of the height of fall, size of the drop, ambient temperature, and ...
Rate of Combination of Trimethylsilyl Radicals in the Gas Phase

Cadman, P.; Tilsley, G. M.; Trotman-Dickenson, A. F. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (10), 1972)

Trimcthylsilyl radicals have been generated by the mercury photosensitized decomposition of trimcthylsilane. The absolute rate of combination of these radicals has been measured by the classical rotating sector technique ...
Apparent Molar Volumes of Multiply Charged Electrolytes

Indelli, A.; Zamboni, R. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (10), 1972)

The apparent molar volumes of K4Mo(CN)8, K3Cr(C2O4)3, Ca2Fe(CN)6, LaFe(CN)6 and K4Zr(C2O4)4 were measured using a pycnometric and dilatometric methods at 25 and 3.39°C. At 25°C K4Mo(CN)8 follows accurately, K3Cr(C2O4)3 and ...
Light Scattering Studies on n-Dodecyltrimethylammonium Bromide and n-Dodecylpyridinium Iodide

Jones, M. N.; Piercy, J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (10), 1972)

The aggregation numbers and effective charges of the micelles of n-dodecyltrimethylammonium bromide and n-dodecylpyridinium iodide have been measured over a range of temperature and ionic strength in aqueous solutions by ...
Kinetics of the Reaction between Methyl Iodide and Silver Nitrate in Aqueous Solution

Huq, Rokeya (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (10), 1972)

The kinetics of the interactions between silver nitrate and methyl iodide in aqueous solution have been followed using a conductivity technique. The observed second-order rate constant increases with initial concentration ...
Specificity in the Interaction between some Chiral Co(III) Complex Ions and DNA in Aqueous Solution

Ascoli, F; Branca, M; Mancini, C; Pispisa, B (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (7), 1972)

The binding of some chiral Co(IIl) complex ions by native DNA in aqueous solution at pH 7.2 has been studied. Equilibrium dialysis and “ phase-separation ” data show that the affinity for the complex counter-ions used by ...
Energy Partition in the y-Radiolysis of Gaseous H2S+N2, H2S+Ar and H2S+Xe Mixtures

Ahmad, M.; Huyton, D. W.; Woodward, T. W. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (10), 1972)

Ionization measurements in H24-N2, H2S4-Ar, and H2S4-Xc mixtures arc used to determine apparent stopping power ratios for the mixtures, or “ energy partition parameters ”. The values found for H2S4- N2, H2S4-Ar, and H2S4-Xc ...
Catalytic Activities of Polynaphthoquinone, Containing various Metal Halides: Dehydrogenation of Formic Acid, Cyclohexene, Ammonia and Alcohols, and Isomerization of Butene

Iwasawa, Yasuhiro; Soma, Mitsuyuki; Onishi, Takaharu; Tamaru, Kenzi (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (9), 1972)

The catalytic activities of polynaphthoquinone, containing various metal halides, such as FeCl3, VCl3, MoCl5 and TiCl4, were studied. The polynaphthoquinone was obtained by the oxidation of naphthalene-1,7-diol and successive ...
E.M.F. Measurements with Solid Electrolyte Galvanic Cells on the Calcium Oxide+Zirconia System: Determination of the Phase Relationships

Pizzini, S.; Morlotti, R. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (9), 1972)

E.m.f. measurements on the cell Pt | O2| CaO(+ CaF2)‖ CaF2(tF–= I)‖ ZrO2–CaO | O2| Pt have been carried out in the temperature range 900–1100°C to measure thermodynamic parameters of the lime + zirconia solid solutions ...
Photo-initiation of Polymerization by Manganese(III) Chelates

Bamford, C. H; Ferrar, A. N (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (7), 1972)

Manganese(lII) acetylacctonatc (Mn(acac)3) and manganese(III) tris(l,l,l-trifluoroacetyl- acetonate) (Mn(facac)3) photosensitize (A = 365 nm) the free-radical polymerization of methyl methacrylate and styrene. Photolysis ...
γ-Radiolysis of Diethyl Succinate

Mills, K. J.; Nosworthy Peto, J. M. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (9), 1972)

Diethyl succinate has been irradiated under vacuum with 60Co γ-radiation. An attempt was made to identify and measure the complete product spectrum. Twenty different products were found after a maximum total dose of 9 × ...

Now showing items 1-20 of 552

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