Journal Articles (before-1995): Recent submissions

Now showing items 1-20 of 660

Heterogeneous Recombination of Atoms: Theory of the Smith-Linnett Method

Jablonski, Aleksander (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (1), 1977)

A general differential equation has been derived which describes the concentration of atoms diffusing and recombining in a cylindrical tube. It is shown that the previously published equations are particular cases of that ...
Effects of Ionisation on Adsorption from Solution

Rendall, Henry M; Smith, Alec L (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (1), 1977)

The adsorption of γ-picoline (4-methyl pyridine) at the silica–water interface, as a function of pH, is reported. A general model for the adsorption is developed, which allows for the possibility that the ionised (HPic+) ...
Molecular complexes of substituted aryl diphenylmethyl sulphides with π-acceptors: Charge transfer spectra and ionization potentials of the donors

Unknown author (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (1), 1977)

Charge transfer complexes of substituted aryl diphenylmethyl sulphides, X1C6H4(X2C6H4) CH—S—C6H4Y, with tetracyanoethylene, 2,3-dichloro-5,6-dicyano-p-benzoquinone and chloranil have been studied spectrophotometrically. ...
Desorption of Electrolytes at Liquid-Vapour and Liquid-Liquid Interfaces

Aveyard, Robert; Saleem, Syed M.; Heselden, Roy (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (1), 1977)

The desorption of various simple inorganic salts at the decanol-water interface has been studied, and analysed together with previously obtained results for the air-electrolyte and dodecane-electrolyte interfaces. The ...
Nuclear Magnetic Relaxation of Alkali Halide Nuclei and Preferential Solvation in Methanol-J-Water Mixtures

Holz, Manfred; Weingartner, Hermann; Hertz, Hermann-Gerhard (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (1), 1977)

Nuclear magnetic relaxation rates of the ionic nuclei 35Cl, 81Br, 127I, 23Na and 87Rb in methanol + water mixtures have been measured over the complete mixtures range and extrapolated to zero salt concentration. The ...
Structure and Catalytic Activity of Iron Oxide and Magnesium Oxide Solid Solutions: Part 3- E.S.R. Characterization

Cordischi, Dante; Pepe, Franco; Schiavello, Mario (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (1), 1977)

Magnesium oxide + iron oxide, fired both in air and in a reducing atmosphere, and magnesium oxide + iron oxide + lithium oxide (up to 1 % atomic Fe) were investigated by e.s.r. spectroscopy. The effects of outgassing ...
Dielectric properties of water adsorbed by kaolinite clays

Hall, Peter G.; Rose, Mark A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (05), 1978)

The dielectric loss observed for adsorbed water on kaolinite clays is interpreted in terms of a Debye dipolar mechanism in preference to a Maxwell–Wagner mechanism. The variation of relaxation times, τ, with coverage shows ...
Intercrystalline molecular transport in zeolites studied by uptake experiments and by nuclear magnetic resonance pulsed field gradient techniques

Kärger, Jörg; Bülow, Martin; Struve, Peter; Kočiřik, Milan; Zikánová, Arlette (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (05), 1978)

A comparison of n.m.r. self-diffusion and uptake measurements was performed with the systems cyclohexane (n-hexane)+NaX-zeolite. For intracrystalline adsorption kinetics a significant difference in the values of the ...
Effect of polyelectrolytes on the kinetics of ionic reactions. Part 5.—Decomposition of 2,4-dinitrophenylphosphate in polycation solutions

Fernández-Prini, Roberto; Baumgartner, Erwin; Turyn, Daniel (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (05), 1978)

The rate of reaction of 2,4-dinitrophenylphosphate (DNPP) in solutions of added polycations has been determined in order to evaluate the influence of the polyelectrolyte effect on the rate constant. The observed enhancement ...
Electronic Absorption Spectra of Benzoyl Radicals Produced from Benzoyl Halides by Irradiation with y-Rays in Organic Glass

Ito, Osamu; Sakaguchi, Tokuhisa; Matsuda, Minoru (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (05), 1978)

Benzoyl radicals, formed by dissociative electron attachment to substituted benzoyl bromides and iodide in γ-irradiated organic glasses at 77 K, were identified by optical absorption bands centred in the region 600–700 nm, ...
Surface and electrokinetic potentials of interfaces containing two types of ionising group

Rendall, Henry M.; Smith, Alec L. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (05), 1978)

A general treatment is presented of the variation of the “wall” potential ψ0 with pH for an interface which derives its surface charge from the ionisation of two separate types (e.g., amino and carboxyl) of ionisable surface ...
Electromotive force studies of electrolytic dissociation. Part 12.—Dissociation constants of some strongly ionising acids at zero ionic strength and 25°C

Monk, Cecil B.; Amira, Mohamed F. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (05), 1978)

A glass electrode–AgCl cell, measured to ±0.01 mV, has been used in evaluations of pK values at 25°C of four acids in the range pK 1–2.2. The practical work consisted of calibrating the cell with dilute HCl followed by ...
Some properties of binary aqueous liquid mixtures. Apparent molar volumes and heat capacities at 298.15 K over the whole mole fraction range

Visser, Cees De; Heuvelsland, Wim J. M.; Dunn, Lawrence A.; Somsen, Gus (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (05), 1978)

Densities and molar heat capacities have been measured for the following binary systems at 298.15 K: water + formamide, water +N,N-dimethylacetamide, water + dimethylsulphoxide and water + acetonitrile over the whole mole ...
Gas phase pyrolysis of cyclopropene. Part 1.—Kinetics and mechanism

Bailey, Ivy M.; Walsh, Robin (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (05), 1978)

The vapour phase kinetics of pyrolysis of cyclopropene have been studied both by product formation and reactant loss relative to an internal standard in the temperature range 466–516 K. The major product is methylacetylene ...
Infrared study of the adsorption of anisoles on silica immersed in heptane

Rochester, Colin H.; Trebilco, Deborah-Anne (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (05), 1978)

Infrared spectra have been reported of silica immersed in solutions of anisole, six substituted anisoles (4-nitro, 4-chloro, 4-bromo, 4-methyl, 2-fluoro and 2,6-dimethyl), nitrobenzene and 4-nitrotoluene in heptane. Surface ...
Fourier inversion of light scattering intensity data from coagulating dispersions

House, William A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (05), 1978)

The short range structure of aggregates, which are formed during the coagulation of monodisperse sols, is investigated by developing a rigorous approach to the analysis of light scattering data. The particle distribution ...
Effects of water on proton migration in alcoholic solvents. Part 5.—Conductance of hydrogen chloride in methanol at 15, 25 and 35°C and in ethanol and pentan-1-ol at 15 and 35°C

Lisi, Rosario De; Goffredi, Mario; Liveri, Vincenzo Turco (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (05), 1978)

Conductance data are reported for hydrogen chloride in water + methanol mixtures at 15, 25 and 35°C and in water + ethanol and in water + pentan-1-ol mixtures at 15 and 35°C. Measurements were carried out in alcohol-rich ...
Mass spectrometric determination of the heats of formation of the silicon fluorides SiF(g), SiF2(g) and SiF3(g)

Farber, Milton; Srivastava, R. D. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (05), 1978)

An effusion-mass spectrometric study of the reaction of SiF4(g) with Si(c, 1) in the temperature range 1590–1782 K has been completed. Second and third law reaction enthalpies were obtained for SiF4(g)+ Si(g)= 2SiF2(g), ...
Spectrophotometric Investigations of Aqueous Solutions at Elevated Temperatures

Alexander, Roger D.; Buisson, David H.; Dudeney, A. William L.; Irving, Roger J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (05), 1978)

The overall stability constants (β3) of the tris complexes of 1,10-phenanthroline, 5-nitro-1,10 phenanthroline and 2,2′-bipyridyl with iron (II) have been determined at various temperatures between 298 and 433 K by a new ...
Effect of temperature on the acid dissociation constants of 1,10-phenanthroline and some related bases in water

Alexander, Roger D.; Dudeney, A. William L.; Irving, Roger J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (05), 1978)

The acid dissociation constants (Ka) of the 1,10-phenanthrolium ion, 5-nitro-1,10-phenanthrolium ion, 2,9-dimethyl-1,10-phenanthrolium ion and 5,6-dimethyl-1,10-phenanthrolium ion in aqueous solution have been determined ...

Now showing items 1-20 of 660

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