Journal Articles (before-1995): Recent submissions

  • Pulse Radiolysis of 9,10-Anthraquinones: Part 1.—Radicals 
    Hulme, B. E.; Land, E. J.; Phillips, G. O. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (10), 1972)
    Radicals derived from 1- and 2-substituted 9,10-anthraquinones have been studied using pulse radiolysis. In aqueous solution, both sodium anthraquinone-1- and -2-sulphonatcs react rapidly with hydrated electrons, and more ...
  • Dislocations in Orthorhombic Minerals: Part 1.—Naturally-occurring Barytes 
    Williams, J. O.; Tennakoon, D. T. B.; Thomas, J. M. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (10), 1972)
    The emergence points of dislocations at cleavage faces of natural barytes crystals have been identified using the etchpit technique. The alignments of these etchpits and the observation of slip traces both in as-grown and ...
  • Effect of the Solution Vapour Pressure on the Temperature Dependence of the Dissociation Constant of Acetic Acid in Water 
    Lown, D. A.; Thirsk, H. R. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (10), 1972)
    The dissociation constant of acetic acid in water is between 4 and 26% greater at the solution vapour pressure than at one atmosphere in the range 250 to 374°C. K = /(T)s.v.P. corresponds to neither the isobaric nor isochoric ...
  • Pressure and Temperature Dependence of the Self-diffusion of Carbon Tetrachloride 
    McCool, M. A.; Woolf, L. A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (10), 1972)
    A modified diaphragm cell method 1 has been used to measure the self-diffusion coefficient of carbon tetrachloride at 283, 298, 313 and 328 K over the pressure ranges 1-769, 1-1216, 1-1469 and 1-1475 bar, respectively. ...
  • Activity Coefficients for the System HC1—MnCl2—H2O at 25°C 
    Downes, C. J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (10), 1972)
    Activity coefficients of hydrochloric acid in mixed solutions with manganous chloride have been measured at total ionic strengths of 0.1,0.5, 1.0, 2.0 and 3.0 mol kg-1 using cells containing hydrogen and silver-silver ...
  • Influence of Framework Charge Density on lon-exchange Properties of Zeolites 
    Barrer, R. M.; Klinowski, J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (10), 1972)
    Ion-exchange isotherms have been measured at 25 ’C for the high framework charge chabazite- typezeolite, K-Gl, and involving the cation pairs: K* F^Na*,Na* Li*, Na* f^ Cs*, Na* f^ Ca2*, Na* f^ Sr2*, and Na* f^ Ba2*. The ...
  • Sorption of Ethylene, Propylene and Cyclopropane in 5A Zeolite: Analysis of Equilibrium Isotherms 
    Derrah, R. I.; Loughlin, K. F.; Ruthven, D. M. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (10), 1972)
    Experimental equilibrium isotherms are presented for the sorption of light unsaturated hydrocarbons in type A zeolite. The data are analyzed according to the extended potential theory of Dubinin and also by the use of a ...
  • Oxidation of a Pyrophoric Iron Part 1.—Kinetics of Chemisorption of Oxygen on the finely divided Iron-Carbon Substrate 
    Galwey, A. K. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (10), 1972)
    A kinetic study of the reaction of oxygen with a finely divided, pyrophoric, iron-carbon mixture is reported. At low pressures (<0.2 Torr) of oxygen, chemisorption proceeded to about two mono- layers. Above 0.8 Torr oxygen ...
  • Effect of Pressure Changes on the Oxidation Rate of Aluminium in the Temperature Range 323-673 K. 
    Hunt, G L; Ritchie, I M (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (8), 1972)
    This paper describes sonic experiments on the oxidation of evaporated aluminium films in the temperature range 323-673 K. The kinetics were followed by measuring the rate of increase in resistance as the film was consumed ...
  • Role of the Catalyst Support in the Oxidation of Methane over Palladium 
    Cljllis, C. F.; Nevell, T. G.; Trimm, D. L. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (8), 1972)
    The influence of the catalyst support on the oxidation of methane over palladium has been studied using a microcalorimctric bead reactor. The nature of the support had no detectable influence on the catalytic activity ...
  • Studies in Ion Solvation in Non-aqueous Solvents and their Aqueous Mixtures: Part 14.1—Free Energies of Transfer of the Alkali-metal Chlorides from Water to 10-99 % (w/w) Methanol-Water Mixtures at 25°C 
    Feakins, D; Voice, P J (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (8), 1972)
    The cell Ag-AgCl | MCl(ms), S | M(Hg)| MCl(mw), W | AgCl-Ag has been used to determine the standard molar free energies of transfer, ΔG°t, of the alkali-metal chlorides, MCl, from water, W, to 10–99 %(w/w) methanol-water ...
  • Thermodynamic Study of Disorder in Zinc Fluoride Tetrahydrate 
    Cook, R O; Davies, A; Staveley, L A K (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (8), 1972)
    The heat capacity of zinc fluoride tetrahydrate has been measured from 10 K to 300 K, giving a value for Scab the calorimetric entropy, at 25°C. The entropy Scq of this salt has been determined by studying the solution ...
  • Radiolysis of Carboxylic Compounds: Part 1.—Comparison of Potassium Acetate and Acetic Acid Radiolysis 
    Lukac, S; Teply, J; Vacek, K (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (8), 1972)
    Measurement of the yields of CO2, CO, H2, CH4, C2H6 and of trapped paramagnetic species reveals substantial differences in the radiolysis of CH3COOH and CH3COOK both at room temperature and 77 K. Microwave power saturation ...
  • Complex Formation in Molten Salts: Part 2.-—Association Constants of Silver Chloro-complexes in Molten Eutectic NaNO3 + Ba(NO3)2 
    Gaur, H C; Bansal, N P (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (7), 1972)
    E.m.f. measurements in dilute solutions of Ag+ and Cl" in molten eutectic NaNO3 + Ba(NO3)2 (94.2:5.8 mol %) at 350, 375 and 400cC have been used to evaluate thermodynamic association constants Kti and Ki2 for the formation ...
  • Addition of Formaldehyde to Slowly Reacting Hydrogen + Oxygen Mixtures 
    Baldwin, R R; Fuller, A R; Walker, R W (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (7), 1972)
    The effect of HCHO in reducing the induction periods of H2+ O2+ N2 mixtures at 500°C has been examined for a range of mixture composition, using HCHO concentrations in the range 0.05–1.0 %. Computer treatment shows that ...
  • Standard Enthalpy of Formation of Crystalline Gold(III) Oxide 
    Ashcroft, S J; Schwarzmann, E (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (7), 1972)
    The heat capacity and the enthalpy of the quantitative thermal decomposition of crystalline Au2O3 have been measured by differential scanning calorimetry. A value of –13.0±2.4 kJ mol–1 is calculated for ΔfH⊖(Au2O3,s).
  • Interaction of Oxygen with Poly crystalline Tungsten: Part 3.—Electron Stimulated Desorption 
    King, David A.; Madey, Theodore E.; Yates, John T. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (7), 1972)
    This paper is a sequel to a detailed study of the kinetics of adsorption and desorption in the interaction of O2 with polycrystalline tungsten, in which a number of oxide and O atom states were identified by thermal ...
  • Effect of Salts on the Diffusion of Dissolved Non-electrolytes 
    Tham, M K; Gubbins, K E (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (7), 1972)
    Experimental measurements of the diffusion coefficient Dlm of non-electrolytes in electrolyte solutions arc reported at 25°C. The systems studied are methane in aqueous NaCl, NaBr, Nai, CaCl2 and LaCl3, neopentane in NaCl ...
  • Analysis of the Reversible Aggregation of Macromolecules in a Centrifugal Field 
    Skerrett, R J (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (7), 1972)
    Solutions of macromolecules which associate in a non-specific manner to give indefinitely large aggregates can be expected to give characteristic patterns when examined by analytical ultracentrifuge. When the rate of ...
  • Use of a Perchlorate-responsive Membrane Cell for the Determination of Activity Coefficients of Aqueous Perchloric Acid 
    Mussini, T; Galli, R; Dubini-Paglia, E (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (7), 1972)
    The e.m.f. of the membrane cell H2(l atm), HC104(/?h, fixed), ClO;-responsive membrane, HC1O4(/h2, variable), H2(l atm) has been measured in order to determine the mean molal activity coefficients for aqueous perchloric ...

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