Journal Articles (before-1995): Recent submissions

  • Polarographic Determination of Hydrogen Ion Activities in Strongly Acidic Media: A New Acidity Function 
    Janata, Jiří; Jansen, Geertje (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (9), 1972)
    An electrochemical method of determination of the activity of hydrogen ions in strongly acidic media has been developed. The novelty of the method rests in the way in which the potential of a glass electrode is measured. ...
  • Heterogeneous Decomposition of Hydrazine: Part 1.—On a Supported Rhodium Catalyst 
    Davis, K. M. C.; Sayer, C. F. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (10), 1972)
    A study has been made of the kinetics of the decomposition of aqueous hydrazine solutions on a supported rhodium catalyst. The decomposition may be represented by the reaction : 2N2H4->N2 + H2 + 2NH3 and it has been ...
  • Thermal Isomerization of Cyclobutenes: Part 19.—3,3,4,4-Tetrafluorocyclobutcne 
    Frey, H. M.; Hopkins, R. G.; Vinall, I. C. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (10), 1972)
    The thermal isomerization of 3,3,4,4-tetrafluorocyclobutene has been shown to yield 1,1,4,4- tetrafluorobuta-l,3-diene quantitatively. In the temperature range 306 to 36O'C the reaction is a homogeneous first order essentially ...
  • Free Radical Addition to Olefins: Part 9. Addition of Methyl Radicals to Fluoro-ethylenes 
    Tedder, J. M.; Walton, J. C.; Winton, K. D. R. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (10), 1972)
  • Molecular Sieve Properties of the Carbonaceous Products prepared by Chemical Dehydrohalogenation of Polyvinylidene Chloride 
    Barton, Stuart S.; Beswick, Paul G.; Harrison, Brian H. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (9), 1972)
    The molecular sieve properties of the carbonaceous products prepared by chemical dehydrohalogenation of polyvinylidene chloride (hereafter referred to as “carbons”) have been investigated by a heat of immersion study, using ...
  • Nanosecond Pulse Radiolysis of Acetone: Kinetic and Thermodynamic Properties of Some Aromatic Radical Cations 
    Rodgers, M. A. J (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (7), 1972)
    Spectra of the molecular ions of acetone, formed during liquid phase pulse radiolysis arc reported. The kinetic features of the monomer-dimer cation equilibria of some aromatic hydrocarbon solutes have been obtained at a ...
  • Electron Spin Resonance Studies of Elementary Processes in Radiation- and Photo-chemistry: Part 11.—Radical Reactions of α-Aminobutyric Acid between 26 and 440 K 
    Ayscougfi, P. B.; Olsen, K. J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (9), 1972)
    Irradiation of α-aminobutyric acid single crystals with 60Co γ-rays at 26 to 77 K results in the trapping of the protonated molecular-anion CH3CH2CH(NH3+)CO2H–(R1). During thermal annealing to 440 K, six further radicals ...
  • Kinetics of the Reactions of Hydrogen Atoms with Ethylene and Vinyl Fluoride 
    Teng, L; Jones, W. E. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (7), 1972)
    Hydrogen atoms generated in a Wood-Bonhoeffer discharge were reacted with vinyl fluoride and ethylene. The products of the vinyl fluoride reaction were: HF, C2H4, C2H6, C2H2, CH4, C3H6, n-C4H10 and C3H8. With the exception ...
  • γ-Radiolysis of Diethyl Succinate 
    Mills, K. J.; Nosworthy Peto, J. M. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (9), 1972)
    Diethyl succinate has been irradiated under vacuum with 60Co γ-radiation. An attempt was made to identify and measure the complete product spectrum. Twenty different products were found after a maximum total dose of 9 × ...
  • Energy Partition in the y-Radiolysis of Gaseous H2S+N2, H2S+Ar and H2S+Xe Mixtures 
    Ahmad, M.; Huyton, D. W.; Woodward, T. W. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (10), 1972)
    Ionization measurements in H24-N2, H2S4-Ar, and H2S4-Xc mixtures arc used to determine apparent stopping power ratios for the mixtures, or “ energy partition parameters ”. The values found for H2S4- N2, H2S4-Ar, and H2S4-Xc ...
  • Catalytic Activities of Polynaphthoquinone, Containing various Metal Halides: Dehydrogenation of Formic Acid, Cyclohexene, Ammonia and Alcohols, and Isomerization of Butene 
    Iwasawa, Yasuhiro; Soma, Mitsuyuki; Onishi, Takaharu; Tamaru, Kenzi (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (9), 1972)
    The catalytic activities of polynaphthoquinone, containing various metal halides, such as FeCl3, VCl3, MoCl5 and TiCl4, were studied. The polynaphthoquinone was obtained by the oxidation of naphthalene-1,7-diol and successive ...
  • Radiation Chemistry of Butan-l-ol 
    Ackerman, L. G. J; Basson, R. A; Linde, H. J. van der (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (7), 1972)
    The radiolysis products of butan-l-ol have been determined at low doses. The effects of total energy input, oxygen and ferric chloride on the yields of the products have been studied. The results are interpreted in terms ...
  • Photo-initiation of Polymerization by Manganese(III) Chelates 
    Bamford, C. H; Ferrar, A. N (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (7), 1972)
    Manganese(lII) acetylacctonatc (Mn(acac)3) and manganese(III) tris(l,l,l-trifluoroacetyl- acetonate) (Mn(facac)3) photosensitize (A = 365 nm) the free-radical polymerization of methyl methacrylate and styrene. Photolysis ...
  • Kinetic Equations for Consecutive Reversible Reactions with Special Reference to Protein Denaturations 
    Hijazi, Nasrat H.; Laidler, Keith J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (7), 1972)
    The interconversion of the native (N) and denatured (D) form of a protein sometimes exhibits simple exponential kinetic behaviour consistent with the mechanism N⇌D. Sometimes, however, logarithmic plots of the variation ...
  • Light Scattering Studies on n-Dodecyltrimethylammonium Bromide and n-Dodecylpyridinium Iodide 
    Jones, M. N.; Piercy, J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (10), 1972)
    The aggregation numbers and effective charges of the micelles of n-dodecyltrimethylammonium bromide and n-dodecylpyridinium iodide have been measured over a range of temperature and ionic strength in aqueous solutions by ...
  • Apparent Molar Volumes of Multiply Charged Electrolytes 
    Indelli, A.; Zamboni, R. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (10), 1972)
    The apparent molar volumes of K4Mo(CN)8, K3Cr(C2O4)3, Ca2Fe(CN)6, LaFe(CN)6 and K4Zr(C2O4)4 were measured using a pycnometric and dilatometric methods at 25 and 3.39°C. At 25°C K4Mo(CN)8 follows accurately, K3Cr(C2O4)3 and ...
  • Kinetics of the Reaction between Methyl Iodide and Silver Nitrate in Aqueous Solution 
    Huq, Rokeya (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (10), 1972)
    The kinetics of the interactions between silver nitrate and methyl iodide in aqueous solution have been followed using a conductivity technique. The observed second-order rate constant increases with initial concentration ...
  • Enthalpy of Solvation of Carbonium Ions 
    Gold, V. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (9), 1972)
    Literature data on the rate of hydrolysis of t-butyl chloride and of the acid-catalyzed hydration of isobutene, both in dilute aqueous solution, have been combined with thermochemical data to yield standard heats of formation ...
  • Kinetics of Reaction of Metal Alkyls with Alkenes: Part 8.—Oligomerization of Ethylene by n-Butyl-lithium- NNN'N'-Tetramethylethylenediamine 
    Hay, J N; McCabe, J F; Robb, J C (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (7), 1972)
    n-Butyl-lithium (BuLi) in the presence of NNN′N′-tetramethylethylenediamine (TMEDA) progressively adds on ethylene molecules to produce a linear alkyl-lithium compound. This oligomerization has been studied at low pressure, ...
  • Rate of Combination of Trimethylsilyl Radicals in the Gas Phase 
    Cadman, P.; Tilsley, G. M.; Trotman-Dickenson, A. F. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (10), 1972)
    Trimcthylsilyl radicals have been generated by the mercury photosensitized decomposition of trimcthylsilane. The absolute rate of combination of these radicals has been measured by the classical rotating sector technique ...

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