Journal Articles (before-1995): Recent submissions

  • Polarography and Solvatochromism: Part 2.—Comparison of Electrochemical and Spectral Properties of 5'-Methoxy-2'-hydroxy-Ar-methyl-4-stilbazolium Iodide 
    Szyper, Mira; Zuman, Petr (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (07), 1977)
    When polarographic half-wave potentials of 5′-methoxy-2′-hydroxy-N-methyl-4-stilbazolium iodide were measured at pH > 13 in mixtures of water with DMF and DMSO, practically no solvent effect was observed. In this pH-range ...
  • Thermodynamics of Binary Liquid Mixtures Involving Hydrogen Bromide, Hydrogen Chloride and Xenon 
    Calado, Jorge C. G.; Gray, Christopher G.; Gubbins, Keith E.; Palavra, Antonio M. F.; Soares, Virgilio A. M.; Staveley, Lionel A. K.; Twu, Chorng-Horng (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (04), 1978)
    The total vapour pressure of the systems hydrogen bromide+xenon and hydrogen bromide + hydrogcn chloride have been measured as a function of composition at 195.42 K. The results have been used to estimate the excess ...
  • Electron Spin Resonance Studies of the Formation and Thermal Stability of Oxygen Radicals on CaO and some other Oxides 
    Cordischi, Dante; Indovina, Valerio; Occhiuzzi, Manlio (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (04), 1978)
    The formation of surface radicals by adsorption of oxygen on CaO, MgO, y-Al2O3 and ZnO has been studied by e.s.r. spectroscopy. The oxides, after activation by heating under vacuum, were exposed to oxygen at 298 K. In ...
  • Interaction of Oxygen with Zinc Surfaces 
    Bickley, Roger I.; Metcalfe, Leonard P. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (04), 1978)
    The interaction of oxygen with clean zinc surfaces has been investigated in the temperature range 78-493 K. Oxygen incorporation occurs extensively at 78 K, the limiting uptake being equivalent to ~ 6 monolayers of oxygen. ...
  • Partial Molar Volumes of Organic Compounds in Water: Part 4.—Aminocarboxylic Acids 
    Shahidi, Fereidoon; Farrell, Patrick G. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (04), 1978)
    The partial molar volumes of the a,a>-aminocarboxylic acids up to 11-aminoundecanoic acid, together with those of a number of cyciopentane and cyclohexane analogues, have been measured in water at 25'C, and related to their ...
  • Capillary Phenomena: Part 6—Behaviour Associated with the Flotation and Mechanical Manipulation of Solid Spheres at Fluid Interfaces 
    Boucher, Ernest A.; Kent, Henry J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (04), 1978)
    Solid sphere behaviour at the interface between two immiscible fluids will depend on whether or not it can float unaided, or, on the type of device used to manipulate it by an applied force. A thermodynamic treatment is ...
  • Activity Coefficients for the System HCl+BaCl2+H2O at 298.15 K: Comparison of Scatchard’s and Pitzer’s Interpretations 
    Khoo, Kean H.; Chan, Chee-Yan; Lim, Tiong-Koon (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (04), 1978)
    Activity coefficients of hydrochloric acid in aqueous solutions of barium chloride have been measured at 298.15 K at constant total ionic strengths of 0.1, 0.5, 1.0, 2.0 and 3.0 mol kg-1 using hydrogen-silver-silver chloride ...
  • Electron Transfer from Aromatic Molecules to Dimethylmercury via a Triplet Exciplex 
    Donckt, E. Vander; Vooren, C. Van (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (04), 1978)
    Whereas low concentrations of added dimcthylmcrcury [0 < (DMM) < 0.1-1 mol dm-3] increase the intersystem crossing rates of electronically excited aromatic molecules, higher concentrations of the fluorescence quencher ...
  • Recoil Tritium Reactions with CH3SiD3: Pressure Dependent Yields 
    Volpe, Paolo; Casuglion, Mario (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (04), 1978)
    The T + CH3S1D3 system has been studied to evaluate the effect of reactant pressure on parent-T yield. The substitution yields for C—H and Si—D bonds have been found to be in the ratio 1 : 1.7. The decomposition rate of ...
  • Energy Distribution and Mechanism in 3-Chloro-3-methyldiazirine Photolysis 
    Figuera, Juan M.; Perez, Juan M.; Tobar, Aurora (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (04), 1978)
    Gas-phase photolysis of pure 3-chloro-3-methyldiazirine over a wide range of pressure (133- 1.015 x 105 N m~2) was performed at 334 and 313 nm. The reaction produces “ hot ” vinyl chloride with enough energy to subsequently ...
  • Structural Analysis of Some Molten Materials by X-ray Diffraction: Part 3.—MnCl2 
    Ohno, Hideo; Furukawa, Kazuo; Tanemoto, Kei; Tagaki, Yoshiki; Nakamura, Tetsuro (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (04), 1978)
    The structure of molten MnCl2 has been examined by consideration of the radial distribution function. The nearest Mn-Cl distance is 2.51 A and the coordination number of manganese is 4.0. An f.c.c. structural model with ...
  • Structural Analysis of Some Molten Materials by X-ray Diffraction: Part 2.—Li2SO4, Na2SO4 and the Mixed System 
    Ohno, Hideo; Furukawa, Kazuo (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (04), 1978)
    The structures of molten Li2SO4, Na2SO4 and their mixtures have been examined by co nsideration of the radial distribution function and the molar volume. The existence of tetrahedral su phate ions in these molten salts has ...
  • Flow Equation for Coagulated Suspensions 
    Cooper, Peter G.; Rayner, John G.; Nicol, Stuart K. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (04), 1978)
    From analysis of the coagulation-redispcrsion kinetics of a sheared suspension an equation for the viscosity at any shear rate is developed. The use of an analogy with chemical reaction kinetics attributes some physical ...
  • Cyclisation in the Gas Phase Photolysis of Neopentyl Bromide 
    Bayliss, Stuart G.; Failes, Robert L.; Shapiro, Jacob S. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (04), 1978)
    Gas phase photolysis of neopentyl bromide was studied over the temperature range 478-564 K. The major products were hydrogen bromide, 1,1-dimethylcyclopropane, with smaller amounts of methylbutenes and neopentane. Above ...
  • Rate Constants for the Removal of Radicals at the Wall in Linearly Branched or Terminated Chain Reactions 
    Blackmore, David R. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (04), 1978)
    The effect of the removal of radicals by the wall is described for reacting systems linear in radical concentration. Exact expressions are derived for the surface rate constant ksurf, defined in terms of the mean radical ...
  • Study of Surface Atom Behaviour on Pt/SiO2 and Pt/Al2O3 Catalysts by Isotopic Exchange of Oxygen from CO2 
    Ducarme, Valentin; Vedrine, Jacques C. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (02), 1978)
    Isotopic exchange of oxygen from CO2 was used to study and characterize the lability of oxygen species at the surface of a catalyst. The catalysts were Pt supported on silica or alumina with several Pt loadings. Pt dispersion ...
  • Role of Breasted Acid Centres for Alkene Double Bond Migration over Alumina at Temperatures above 450 K 
    John, Christopher S.; Tada, Akio; Kennedy, Lois V. F. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (02), 1978)
    Water was added to alumina samples following their activation in vacuo at both 723 and 1023 K. Reactions of [2Ho]propene and of CD2=CH—CH2 were then studied on these catalysts. Adsorption of water (2.7 x 1018 molecule m-2) ...
  • Diffusion in Binary Liquid Mixtures of non Electrolytes 
    Barrie, James A.; Dawson, Ray B.; Sheppard, Richard N. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (02), 1978)
    Self diffusion coefficients at 25 'C for octamethylcyclotetrasiloxanc in binary mixtures with benzene and carbon tetrachloride have been measured by pulsed field gradient pulsed n.m.r. A comparison is made of the diffusion ...
  • Stability Constants for Cadmium Iodide Complexes in Aqueous Cadmium Iodide (298.15 K) 
    Lutfullah; Paterson, Russell (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (02), 1978)
    In order to interpret the transport properties of aqueous cadmium iodide, the concentrations of free ions and complexes (CdU'n; n = 1,2, 3,4) were required. For this method the method of Reilly and Stokes was used. ...
  • Location of Cations in Synthetic Zeolites-X and -Y: Part 6.—Influence of X-ray Irradiation on the Location of Exchangeable Cations 
    Costenoble, Martin L.; Mortier, Wilfried J.; Uytterhoeven, Jan B. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (02), 1978)
    The X-ray irradiation of a scries of Ca- and La-Y zeolites, pretreated at different temperatures results in the formation of oxides (CaO and La2O3) in the sodalite cage, and in a depopulation of the hexagonal prisms. The ...

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