The rate constant changes of ionic reactions due to the electrostatic polyelectrolyte effect can be described in some detail. For second-order reactions between ions of equal charge sign, it is shown that the inhomogeneous ...

The pHS of three standard buffer solutions has been measured using a hydrogen electrode against a silver–silver chloride electrode in a cell nominally without a liquid–liquid junction. The measurements have been carried ...

A new derivation of the number of ions in various fractions of the Debye–Hückel ionic cloud is presented. The results provide an estimate of how many ions are involved in many-body long-range (ion–atmosphere) interactions ...

An infrared cell of novel design is described and has been used for the measurement of spectra of discs of powdered silica immersed in liquid mixtures of 2,2,4-trimethylpentane + cyclohexanone, 1,4-dimethylbenzene + ...

Reduction of molybdenum supported on silica leads to X-band e.p.r. spectra with g⊥= 1.940 and g‖= 1.882. When molybdenum enriched in 95Mo is used, the hyperfine tensor can be measured as A⊥= 44 G and A‖= 98 G. The simulation ...