Journal Articles (before-1995): Recent submissions

  • Chemisorption of nitrogen on tungsten studied by auger electron spectroscopy 
    Joyner, Richard W.; Rickman, John; Roberts, M. Wyn (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (10), 1974)
    By monitoring the surface directly by Auger electron spectroscopy (AES), adsorption isotherms for nitrogen on polycrystalline tungsten ribbons have been determined in the temperature range 1200–1400 K. These are not of the ...
  • Evidence for the nature of CO adsorbed on nickel from electron spectroscopy 
    Joyner, Richard W.; Roberts, M. Wyn (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (10), 1974)
    At 295 K there is clear evidence from the observed X-ray and u.v. induced spectra that CO is adsorbed in a molecular form. The observed spectra are in good agreement with the ionisation potentials expected of electrons in ...
  • Site-binding model of the electrical double layer at the oxide/water interface 
    Yates, David E.; Levine, Samuel; Healy, Thomas W. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (10), 1974)
    A site-binding model of the oxide/aqueous electrolyte interface is introduced, in which it is proposed that the adsorbed counter ions form interfacial ion pairs with discrete charged surface groups. This model is used to ...
  • Electric Modulated Reflectance at Mercury Electrodes: Transition between Electrostatic Adsorption and Chemisorption 
    Gottesfeld, Shimshon; Conway, Brian E. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (10), 1974)
    Reflectance changes at polished electrode surfaces can arise from changes of optical properties of the metal surface and from changes of local ionic concentrations in the double-layer. The significance of these two effects ...
  • Homogeneous Isotope Exchange Reactions: Part 3—H2S+D2 
    Pratt, Graham; Rogers, David (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (1), 1977)
    The kinetics of the early stages of the exchange reaction in H2S + D2 mixtures [H2S, 0.55–9.34 Torr (1 Torr = 133 N m–2); D2, 0.55–6.39 Torr] have been studied in a static system at 808–937 K. The effects of excess argon ...
  • Standard Free Energy of Transfer of Ionic Surfactants from Water to Water+Acetone Mixtures from Vapour Pressure Measurements 
    Treiner, Claude; Besnerais, A. Le (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (1), 1977)
    The standard free energy of transfer, ΔG°t of sodium decylsulphate (SDS) and of decyltrimethyl-ammonium bromide (DTMABr) from pure water to mixtures of water and acetone (AC) have been determined by accurate vapour pressure ...
  • Sorption of Water Vapour by some Derivatives of Bovine Serum Albumin 
    Rochester, Colin H.; Westerman, A. Valerie (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (1), 1977)
    Isotherms for the sorption of water vapour by succinyl, acetyl, amidino, methyl and carbodiimide derivatives of bovine serum albumin at 298 K have been determined gravimetrically. The effects of the specific chemical ...
  • Excess Enthalpies of some Binary Mixtures of 1,2-Dichloroethane and Hydrocarbons 
    Mahl, B. S.; Khurma, J. R. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (1), 1977)
    The excess enthalpies of mixtures of 1,2-dichloroethane with cyclohexane, benzene, toluene, o-, in- and p-xylenes have been measured at 298.15 K. 7/E values for the first two systems are found to be positive over the entire ...
  • Generalised Forster Cycle: Thermodynamic and Extrathermodynamic Relationships Between Proton Transfer, Electron Transfer and Electronic Excitation 
    Grabowski, Zbigniew R.; Rubaszewska, Wieseawa (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (1), 1977)
    The thermodynamic quantities characterizing one electron reduction, protonation and electronic excitation, are mutually related in the ground and excited states by 6 thermodynamic (or approximate thermodynamic) cycles. The ...
  • Different Species of Hydrogen Chemisorbed on Raney Nickel Studied by Neutron Inelastic Spectroscopy 
    Renouprez, A. J.; Fouilloux, P.; Coudurier, G. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (1), 1977)
    The chemisorption of hydrogen on Raney nickel has been studied by neutron inelastic spectroscopy at high energy transfer. The main vibration levels at 120 and 140 meV are interpreted as being produced by multi-bonded surface ...
  • Kinetics of the thermal unimolecular reactions of cyclopropane and cyclobutane behind reflected shock waves 
    Barnard, John A.; Cocks, Alan T.; Lee, Richard K-Y. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (09), 1974)
    The kinetics of the thermal reactions of cyclopropane and cyclobutane behind reflected shock waves have been studied in a single-pulse chemical shock tube. Comparisons of methods for obtaining reflected-shock temperatures ...
  • Adsorption of Gases on Polycrystalline Nickel Films Studied by X-Ray and Ultra-violet Photoelectron Spectroscopy 
    Page, Peter J.; Trimm, David L.; Williams, Peter M. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (09), 1974)
    The adsorption of a series of gases onto clean evaporated films of polycrystalline nickel has been studied using ultraviolet and X-ray photoelcctron (u.p.e. and X.p.e. respectively) spectroscopy. Observation of the intensity ...
  • Relative and absolute electrochemical quantities. Components of the potential difference across the electrode/solution interface 
    Trasatti, Sergio (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (09), 1974)
    The absolute value of the standard potential of the hydrogen electrode is calculated on the basis of a value of –263.1 kcal mol–1 for [graphic ommitted], the standard chemical free energy of hydration of the proton. This ...
  • Interactions of Dienes and Alkynes with Rutile (Titanium Dioxide) 
    Halliday, Marlene M.; Kemball, Charles; Leach, H. Frank (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (09), 1974)
    The catalytic properties of titanium dioxide (rutile) have been examined for a number of reactions involving dienes (propadiene and buta-1,3-diene) or alkynes (ethyne, propyne and but-2-yne) with hydrogen, deuterium or ...
  • Virial Analysis of Low-coverage Physical Adsorption Data on Heterogeneous Surfaces 
    Pierotti, Robert A.; Thomas, Howard E. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (09), 1974)
    The general treatment of the McMillan–Mayer theory of solutions is applied to low-coverage adsorption on heterogeneous surfaces. Expressions are derived for the second and third gas/solid virial coefficients for adsorption ...
  • Calculation of the Interaction of Adsorption of Inert Gases on to the (100) Face of Sodium Chloride and Argon on to the (100) Face of Potassium Chloride 
    House, William A.; Jaycock, Michael J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (09), 1974)
    Calculations are presented for the adsorptive potential energy for inert gases on the (100) faces of NaCl and KCl. These are performed using the “exponential-six” equation to calculate dispersion and repulsion terms, and ...
  • Quenching of the uranyl (UO 2+2) emission by inorganic ions in solution 
    Matsushima, Ryoka; Fujimori, Hidenobu; Sakuraba, Shukichi (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (09), 1974)
    Quenching constants (K) of various inorganic ions have been measured for the quenching of the uranyl emission in aqueous acid solution at room temperature. Quenching constants of halogen or halogen-like anions (X–) increase ...
  • One-electron Reactions in Some Cobalamins 
    Blackburn, R.; Erkol, A. Y.; Phillips, G. O. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (09), 1974)
    Pulse radiolysis has been used to study the reaction of hydrated electrons and other agents with various cobalamins, viz. cyanocobalamin (vitamin B12), hydroxocobalamin (vitamin B12a), and cob(II)alamin (vitamin B12r). It ...
  • Dehydration of Propan-2-ol on X Zeolites 
    Gentry, Stephen J.; Rudham, Robert (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (09), 1974)
    The dehydration of propan-2-ol on moderately protonated X zeolites leads to the formation of both propene and di-isopropyl ether at temperatures in the range 383-430 K. Unexchanged zeolite was considerably less active, and ...
  • Dimerization and Cracking of [4-13C]But-l-ene with Deamminated Ammonium Exchanged Type Y Zeolite 
    Weeks, Thomas J.; Bolton, A. P. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (09), 1974)
    The use of highly enriched [4-13C]but-1-ene with an integrated gas chromatograph–mass spectrometer has enabled a better understanding of the mechanism of reaction between but-1-ene and deamminated ammonium exchanged type ...

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