Journal Articles (before-1995): Recent submissions

  • Calculation of Adsorption Potentials for Water on Rutile 
    Jaycock, Michael J.; Waldsax, John C. R. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (08), 1974)
    Adsorption potential calculations have been made for the adsorption of water onto ideal (100) and (110) faces of rutile. The results for the (110) face may be interpreted so as to be consistent with the published results ...
  • Solvated Electrons in Hexamethylphosphoramide: Part 2.—Density Measurements, Electrical Properties of Frozen Solutions, Electron Emission from Surfaces of Solutions 
    Gremmo, Norberto; Randles, John E. B. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (08), 1974)
    The dissolution of alkali metals in hexamethylphosphoramide (HMPA) causes a decrease in density and a value of approximately 80 cm3 for the apparent molal volume of the solvated electron has been deduced. The change ...
  • Solvated Electrons in Hexamethylphosphoramide: Part 1.—Conductivity of Solutions of Alkali Metals 
    Gremmo, Norberto; Randles, John E. B. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (08), 1974)
    Apparatus for the preparation, and measurement of the conductance, of solutions of lithium, sodium and potassium in hexamethylphosphoramide is described. The time- and concentration- dependence of the conductance of ...
  • Infra-red Study of Phosphate Adsorption on Goethite 
    Atkinson, Roger J.; Parfitt, Roger L.; Smart, Roger St. C. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (08), 1974)
    Infra-red spectra of phosphate adsorbed on synthetic goethite (a-FcOOH) show only PO^- ions to be present. Phosphate bands observed at about 1125, 1050 and 1000 cm-1 are shifted to 1J90, 1100 and 1000 cm'1 following ...
  • Solid/Solution Interface Equilibria for Aromatic Molecules Adsorbed from Non-aromatic Media: Part 2.—Aromatic Carboxylic Acids 
    Wright, Ernest H. M.; Pratt, Nana C. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (08), 1974)
    Data have been obtained for benzoic acid, 1-naphthoic acid and 2-naphthoic acid adsorption on the carbon blacks Graphon and Spheron 6, and on the oxides Alcoa C73O, Alon C, titanium dioxide and Cab-O-Sil using some or ...
  • Standard Potentials of M/M+ (M=Li, Na, K, Rb or Cs) Electrodes in Dimethyl Sulphoxide+Water Mixtures at 25°C and Related Ion-Solvent Interactions in the Solvents 
    Das, Asim K.; Kundu, Kiron K. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (08), 1974)
    The standard electrode potentials GE’) of M/M+ (M = Li, Na, K, Rb and Cs) electrodes in aqueous solutions of dimethyl sulphoxide (DMSO) (containing 10, 20, 40 and 60 wt. % DMSO) have been determined at 25°C from e.m.f. ...
  • Thermodynamics of the Liquid System Methane+Propane 
    Calado, Jorge C. G.; Garcia, Gerald A.; Staveley, Lionel A. K. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (08), 1974)
    The total vapour pressure of liquid mixtures of methane and propane has been measured as a function of composition at temperatures of 115.77 and 134.83 K. The activity coefficient of methane f\ and the excess Gibbs ...
  • Reaction of Hydrogen Atoms with Ethane 
    Camilleri, Patrick; Marshall, Roger M.; Purnell, J. Howard (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (08), 1974)
    The reaction between hydrogen atoms and ethane has been studied in a flow-discharge system over the wide temperature range 503–753 K at pressures between 8 and 16 Torr. The major products are methane and ethane, reformed ...
  • Activated Choroalkyl Radicals in the Chlorination of Olefins 
    Beadle, Peter C.; Knox, John H. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (08), 1974)
    Propane has been photochlorinated in competition with cis- and trans-dichloroethylene (c-DCE and t-DCE), 1,1-dichloroethylene (1,1-DCE), trichloroethylene (TrCE) and tetrachloroethylene (TCE) at temperatures between 300 ...
  • Effect of Hydrostatic Pressure on the Electrical Conductivity of Ag2HgI4 and Cu2HgI4 
    Shibata, Shuichi; Hoshino, Hideoki; Shimoji, Mitsuo (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974)
    The electrical conductivity of the a and ft phases of Ag2HgI4 and Cu2HgI4 has been measured as a function of hydrostatic pressure up to 3xlO8Nm~2 in the temperature range between 283 and 363 K. The activation volumes ...
  • Infra-red Structural Study of Aluminium-deficient Y Zeolites 
    Pichat, Pierre; Beaumont, Rejane; Bartiiomeuf, Denise (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974)
    The linear variations in frequency of the stretching O—(Al, Si)—O vibrations (around 1050 and 800 cm-1) with Al content of aluminium-deficient zeolites can also be extended to ultrastable zeolites. This result confirms ...
  • Oxidation of Ferrous Ions by an Aliphatic Dioxyl Radical 
    Butler, John; Jayson, Gerald G.; Swallow, A. John (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974)
    1-Hydroxy-1-methylethyl radicals react with oxygen with a rate constant of 4.5 ± 0.5 × 109 dm3 mol–1 s–1. The resulting dioxyl radicals react with ferrous ions with a rate constant at 25°C of 1.7 ± 0.2 × 106 dm3 mol–1 s–1, ...
  • Kinetic Evidence for Excited Water in the Cobalt-60 y-Radiolysis of Ferrous Sulphate in 0.4 mol dm-3 Sulphuric Acid Solutions 
    Matthews, Ralph W. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974)
    The effect of oxygen and ferrous ion concentrations on G(Fe3+) from ferrous sulphate in 0.4 mol dm–3 sulphuric acid solution irradiated with 60Co γ-rays has been studied. The results cannot be fully explained in terms of ...
  • Lithium + Methylamine Solutions: Part 3.—Vapour Pressures 
    Nakamura, Yoshio; Horie, Yutaka; Shimoji, Mitsuo (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974)
    The vapour pressures of the lithium+methylamine system have been determined as a function of metal concentration between —55 and + 5°C. The activity of methylamine deviates positively from Raoult’s law at low metal ...
  • Bond dissociation energies from equilibrium studies: Part 5.—The equilibria Br2+ CH2F2⇌ HBr + CHF2Br and Br2+ CH3F ⇌ HBr + CH2FBr. Determination of D(CHF2—Br) and ΔH °f(CHF2Br, g) 
    Okafo, Ernest N.; Whittle, Eric (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974)
    The equilibrium, Br2+ CH2F2⇌ HBr + CHF2Br (4), has been studied in the temperature range 371–479°C, with equilibrium being approached from both sides. Third-law calculations lead to ΔH°4=–39.9 ± 0.3 kJ mol–1 at 298 K from ...
  • Infra-red Spectra of Nitrogen Adsorbed on Silica-supported Platinum 
    Egerton, Terence A.; Sheppard, Norman (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974)
    Infra-red absorption bands of considerable intensity near 2230 enr1 have been obtained from nitrogen adsorbed on silica-supported platinum and are assigned to N=N bond-stretching vibra tions. Samples have been studied ...
  • Dissociation of the Bisulphate Ion at Moderate Concentrations 
    Turner, David J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974)
    A Raman study has been made of the dissociation of the HSO–4 ion at 25°C in H2SO4, NH4HSO4 and LiHSO4 over a wide concentration range. Evidence for the presence of an ion pair H3O+·SO2–4 was obtained and its formation ...
  • Anionic Polymerization of Styrene in Binary Mixtures of 1,2-Dimethoxyethane and Benzene 
    Takaya, K.; Ise, Norio (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974)
    The kinetics of living anionic polymerizations of styrene has been studied with lithium as gegenion in solution in binary mixtures of 1,2-dimethoxyethane and benzene at 0, 25 and 35°C. The contri bution of intermolecular ...
  • Kinetics of Anionic Polymerization of Styrene in Binary Mixtures of Dimethoxyethane and Benzene 
    Takaya, K.; Yamauchi, S.; Ise, Norio (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974)
    The kinetics of anionic polymerization of polystyryl salts with various gegen ions have been investigated spcctrophotomctrically in 1,2-dimethoxyethanc (DME) + benzenc mixtures at 25QC. The behaviour of two types of ...
  • Solid/Liquid Phase Equilibria and Solid Compound Formation in Mixtures of Hexafluorobenzene with Nitrogen Containing Compounds 
    Ott, J. Bevan; Goates, J. Rex; Reeder, Joan; Shirts, Randall B. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974)
    Thermal methods have been used to determine with high precision the solid/liqnid phase equilibria diagrams tor mixtures of hcxafluorobcnzene with Y-methylmorpholine, TV-methyipipcridinc and AW'-dimcthylpiperazine. Solid ...

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