Journal Articles (before-1995): Recent submissions

  • Mossbauer Studies of Ferrous-A Zeolite: Part 3.—The Adsorption of Ethanol 
    Dickson, Bruce L.; Rees, Lovat V. C. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11), 1974)
    Mossbauer spectra have been taken after successive additions of small doses of ethanol have been made in dehydrated ferrous-A. These spectra show that two molecules of adsorbate coordinate to each ferrous ion. When the ...
  • Mossbauer Studies of Ferrous-A Zeolite: Part 2.—The Mobile Adsorption of Ethylene 
    Dickson, Bruce L.; Rees, Lovat V. C. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11), 1974)
    The titration of ethlene into dehydrated ferrous-A has been followed by 57Fe Mössbauer spectroscopy. The adsorption of ethylene increases the isomer shift and the quadrupole splitting of the single doublet of the outgassed ...
  • Mossbauer Studies of Ferrous-A Zeolite: Part 1.—Adsorption/Desorption of Water 
    Dickson, Bruce L.; Rees, Lovat V. C. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11), 1974)
    Ferrous ions have been ion exchanged into A zeolite. The ferrous ions in the dehydrated form of the zeolite give an isomer shift of 1.08 mm s~l and a temperature independent quadrupole splitting of 0.46 mm s~l. The ferrous ...
  • Extraction of Uranyl Nitrate and Thorium Nitrate by Methyl Diphenyl Phosphate 
    Apelblat, Alexander (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11), 1974)
    Partition studies have been carried out for the uranyl nitrate/water/methyl diphenyl phosphate and thorium nitrate/water/methyl diphenyl phosphate systems. The activities of methyl diphenyl phosphate were calculated for ...
  • Hydrogen Bond Strengths and Acidities of Hydroxyl Groups on Silica-Alumina Surfaces and in Molecules in Solution 
    Rouxhet, Paul G.; Sempels, Raymond E. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11), 1974)
    The properties of hydroxyl groups on mixed silica–alumina gels (0–50 % Al2O3) have been studied by adsorbing weak H bond accepting molecules onto the gels and recording the OH stretching infrared band. Additional ...
  • Compensation Effect in the Kinetics of the Catalysed Oxidation of Carbon 
    Feates, Frank S.; Harris, Peter S. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11), 1974)
    A pattern of behaviour amongst catalysts in the catalysed oxidation of carbons has been identified. A link between the rates of the catalysed and uncatalysed reactions in these systems has been established. A phenomenological ...
  • Kinetics of Dissociative Recombination of Free Electrons with Hydronium Ions in Premixed Flames 
    Hayhurst, Allan N.; Telford, N. Roland (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11), 1974)
    The rate coefficient for the gas phase recombination of H3O+ ions and free electrons in H3O++ e–→ neutral products has been measured in atmospheric pressure flames of H2+ O2+ N2 over the temperature range 2025–2445 K. ...
  • Stoichiometry of Precipitation under Conditions of Double Diffusion 
    Zivkovic, Tomislav; Pokric, Biserka; Pucar, Zvonimir (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11), 1974)
    The mechanism of natural precipitation processes has been studied using as a model system the one-dimensional double diffusion of the precipitating components in a gel. It was found, theoretically and experimentally, that ...
  • Semiconductor Properties of Crystalline Anthracene: Competition of Electron and Hole Photoinjection by Redox Electrolytes 
    Rosseinsky, David R.; Hann, Richard A.; Axon, Anthony J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11), 1974)
    Electron photocurrents have been measured with a number of solution photoinjectors. A new set of electrode potentials for solid anthracene is used to account for the pH dependence of electron as compared with hole photocurrents ...
  • Hydrogenolysis of some Saturated Hydrocarbons over a Platinum Black Catalyst 
    Guczi, L.; Sarkany, A.; Tetenyi, P. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11), 1974)
    Deuterium exchange reactions of methane, ethane, propane and neopentane, and the hydrogenolysis and isomerization of ethane, propane, n-butane and isobutane on platinum black have been studied in the temperature range ...
  • Thermodynamic Study of the 1 : 1 Solid Compound, Hexafluorobenzene-Benzene 
    Brennan, J. S.; Brown, N. M. D. Brown; Swinton, Findlay L. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11), 1974)
    A study of the 1 : 1 solid compound hexafluorobenzene–benzene using a differential scanning calorimeter has enabled an estimate to be made of the enthalpy of formation of the compound when it is formed from the two pure ...
  • Salting-in of Alcohols by Symmetrical Tetra-alkylammonium Bromides 
    Aveyard, Robert; Heselden, Roy (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11), 1974)
    The changes in free energy, enthalpy and entropy associated with the transfer of several alkanols at high dilution from water to aqueous solutions of some symmetrical tetra-alkylammonium bromides (R4NBr) have been determined ...
  • P,V,T Behaviour of Liquid n-Dodecane at Negative Pressures 
    Huang, Hann-Sheng; Winnick, Jack (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11), 1974)
    The extension of a column of liquid n-dodecane in a centrifugal field has been measured optically. Schlieren photographs of the meniscus position were made at rotational speeds up to 24 000 r.p.m. and at temperatures from ...
  • Ionic Conduction in Ammonium Perchlorate Doped with Divalent Ions 
    Owen, Gari P.; Thomas, John M.; Williams, John O. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11), 1974)
    D.c. electrical measurements are reported for sulphate-ion-doped and barium-ion-doped ammonium perchlorate. The extension of an impurity-dominated regime in sulphate-ion-doped ammonium perchlorate, and the fact that ...
  • Derivation of Partial Molal Volumes in Binary Systems 
    Sinclair, Crawiord D.; Vincent, Colin A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11), 1974)
    A number of methods of evaluating partial molal volumes from experimental density/composition data for binary systems are considered. Systematic analysis of density data for four binary systems involving water and a second ...
  • Appearance and Ionization Potentials of Ions produced by Electron-impact on some Phosphorus-Fluorine Compounds: the Phosphorus-Phosphorus Bond Dissociation Energy in Diphosphorus Tetralluoride 
    Dean, Christopher R. S.; Finch, Arthur; Gardner, Peter J.; Payling, David W. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (11), 1974)
    The ionization potentials of P2F4, PF3 PF2H and PF2I and the appearance potentials of the PF+2 ion from these species are reported. The ionization potential of the PF2˙ radical is estimated using approximations for the ...
  • Experimental Enthalpies for Nitrous Oxide Vapour in the range 1 to 49 bar and 273.15 to 373.15 K 
    Dawe, Richard A.; Snowdon, Peter N. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    The enthalpy-pressure behaviour for nitrous oxide along eleven isotherms in the vapour phase has been determined from measurements of the Joule-Thomson effect. These measurements and the derived enthalpy values are reported ...
  • Kinetics and Mechanism of the Reduction of Manganese(III) in Perchloric Acid at a Platinum Electrode 
    Rosseinsky, David R.; Hill, R. John (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    The electrode kinetics at 25°C of the reduction of manganese(III) on an oxidised platinum surface confirms an unusually low transfer coefficient of 0.26. Interpretation involving a comparison with a correlation of hydrolytic ...
  • Aqueous Hydroxide Ion: Part 1.—Hydrogen Isotope Fractionation Studies by Proton Magnetic Resonance 
    Taylor, C. E.; Tomlinson, C. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    The hydrogen isotope fractionation of the aqueous hydroxide ion has been studied through p.m.r. measurements on lithium, sodium, and potassium hydroxide solutions in light and heavy water. The experimental results are ...
  • Electron Spin Resonance Detection of Radical Intermediates During Photo-oxidation by Metal Ions in Solution 
    Greatorex, David; Hill, Richard J.; Kemp, Terence J.; Stone, Thomas J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    Irradiation of fluid solutions of ceric and uranyl ions in various organic media in the temperature range 140–290 K gives rise in many cases to well-resolved e.s.r. spectra of solvent-derived radicals, enabling characterisation ...

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