Journal Articles (before-1995): Recent submissions

Now showing items 41-60 of 882

Effect of Surface Dynamics on the Process of Droplet Formation from Supported and Free Liquid Cylinders

Carroll, Brendan J.; Lucassen, Jacob (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974)

The formation of droplets from cylindrical oil films supported by oleophilic filaments has been studied experimentally. In the absence of surfactant, the initial rate of growth of a disturbance on the cylindrical fluid ...
Electrification Associated with Droplet Production from Liquid Jets

Iribarne, J. V.; Keemes, M. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974)

In the first part, a theoretical model is proposed for the charging of droplets separating from the tip of liquid jets or filaments, based on a previous hypothesis by Iribarnc and Mason. The charging is attributed to ...
Negative Ion Mass Spectrometry: Part 2?—Ionization Processes in 2- and 3-Nitrotoluene

Alexander, Roger G.; Bigley, David B.; Turner, Robert B.; Todd, John F. J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974)

Ionization efficiency curves (profiles) have been recorded for parent and major daughter negative ions from 2- and 3-nitrotoluene. From the effects of adding sulphur hexafluoride as a thermal electron scavenger it is ...
Viscosities of Binary Gas Mixtures at High Temperatures

Maitland, Geoffrey C.; Smith, E. Brian (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974)

The viscosities of He + Ar, Ar + Kr and CH4 + CF4 binary gas mixtures have been measured over the temperature range 293-1600 K using a capillary flow technique. The results are in good agree ment with existing data ...
Electron Paramagnetic Resonance Study of the Conformation of Macromolecules Adsorbed at the Solid/Liquid Interface

Fox, Katharine K.; Robb, Ian D.; Smith, Royston (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974)

A method using e.p.r. spectroscopy has been developed for determining the ratio of the number of segments in loops to the number in trains for polymers adsorbed at the solid/liquid interface. The method can be used on ...
Pressure Dependence of the Volumes of Ionization of Carboxylic Acids at 25, 35 and 45°C and 1-1200 bar

Hoiland, Harald (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974)

The equivalent conductances of formic acid, acetic acid, propionic acid, valeric acid, hexanoic acid, isobutyric acid, and isovaleric acid have been measured as functions of pressure up to 1200 bar. Equilibrium constants ...
Radiolysis of Pyrimidines in Aqueous Solutions: Part 3.’—Micellar Effects on Product Yields Formed in the Interaction of ea~, •H, -OH and Cl? with Thymine and Uracil

Fendler, Janos H.; Infante, A.; Jirathana, Poonsri; Fendler, Eleanor J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974)

Micellar surfactants decrease the yield of products formed in the interaction of ea"q, -H, -OH and Cl2 with uracil and thymine far in excess of the decrease expected on the basis of simple competition of these species ...
Radiolysis of Pyrimidines in Aqueous Solutions: Part 2.—Product Formation in the Interaction of ea~, -H, -OH and C17- with

Infante, Gabriel A.; Jirathana, Poonsri; Fendler, Eleanor J.; Fendler, Janos H. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974)

Product yields in the reaction of e~, -H, -OH and Cl/ with uracil and uracil- have been determined quantitatively in 60Co y-irradiated aqueous uracil solutions in the presence of suitable scavengers. Good material ...
Poisoning of a Supported Molybdenum Olefin Disproportionation Catalyst

Howe, Russell F.; Kemball, Charles (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (07), 1974)

Nitric oxide and carbon monoxide have been used to poison a propene disproportionation catalyst prepared from molybdenum hexacarbonyl on silica. Nitric oxide is strongly adsorbed, and an effective poison, but infra-red ...
Primary Acidity Constant of Maleic Acid in Ordinary Water and in Deuterium Oxide

Lowe, Barrie M.; Smith, David G. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

The primary acidity constant of maleic acid has been determined at 298.2 K in ordinary water by conductance measurements and in both ordinary water and deuterium oxide by precise e.m.f. measure ments with glass and ...
Kinetics of the Thermal Gas-phase Decomposition of 6-Oxabicyclo[3,1,0]hexane

Flowers, Michael C.; Penny, David E. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

The kinetics of the gas-phase decomposition of 6-oxabicyclo[3,l,0jhcxanc have been studied over the temperature range 670-742 K. at pressures between 1 and 28 Torr. Isomerization to cyclopcnta- nonc and cyclopcnt-2-en-l-ol ...
Redox Reactions between Halides and Reducing Metal Complexes in Non-aqueous Solution: Part 2.—Derivatives of Molybdenum Carbonyl

Bamford, Clement H.; Sakamoto, Izumi (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

Molybdenum carbonyl undergoes ligand exchange with vinyl monomers such as methyl metha crylate (mma) to produce complexes of the type Mo(CO)5fmma) (I) which readily enter into redox processes with organic halides to ...
Redox Reactions between Halides and Reducing Metal Complexes in Non-aqueous Solution: Part 1.—Derivatives of Tetrakis(triphenyl phosphite)nickel(O)

Bamford, Clement H.; Sakamoto, Izumi (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

Tetrakisftriphcnyl phosphite)nickel(O) (Ni(tp)4) undergoes ligand exchange with electron donors such as methyl methacrylate (mma) to form complexes of the type Ni(tp)3(mma) which enter into redox reactions with organic ...
Triple Point of the First Monomolecular Layer of Krypton Adsorbed on the Cleavage Face of Graphite: Influence of the Structure of this Surface on the Structure of the First Adsorbed Layer of Rare Gases

Larher, Y. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

From adsorption isotherms of krypton on graphite measured between 79.24 and 88.46 K. in the monolayer domain a two-dimensional triple point of 84.8 ± 0.5 K is determined for this system. Thermodynamic analysis of these ...
Free Radical Addition to Olefins: Part 12.—Addition of Bromodifluoromethyl Radicals to Fluoroethylenes

Tedder, John M.; Walton, John C. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

The kinetics of the photochemical addition of dibromodifluororncthanc to vinyl fluoride, 1,1- difluoroethylene and tetrafluoroethylene has been examined in gas phase experiments. The mech anism involves the addition ...
Free Radical Addition to Olefins: Part 11.—Telomerization of Tetrafluoroethylene with Dibromodifluoromethane and Trifluoroiodomethane

Ashton, David S.; Tedder, John M.; Walton, John C. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

The telomerization of tetrafluoroethylene in the gas phase by CF2Br2 results in the formation of products of general formula Br[CF2]„Br n = 2-11. When CF3I was used the products were found to be CF3[CF2CF2]„I where n ...
Infra-red Determination of the Isotherm of Hydrogen Adsorption on a Pt/Al2O3 Catalyst

Primet, Michel; Basset, Jean-Marie; Mathieu, Michel-Vital (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

Of the various forms of hydrogen adsorbed on platinum only hydrogen weakly and reversibly adsorbed is detected by an infra-red band at 2120 cm-1. The preparation of a well dispersed sample of Pt/ALO? catalyst containing ...
Nuclear Spin-lattice Relaxation Times of Alkali Metal Counterions at Micellar Interfaces

Robb, Ian D.; Smith, Royston (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

Spin lattice relaxation rates of Li+, Na+, Rb+ and Cs+ have been measured by pulsed n.m.r. in both simple electrolyte solutions and solutions containing surfactant micelles. Relaxation rates for the ions adsorbed at ...
Effect of Hydrostatic Pressure on the Electrical Conductivity of Ag3SBr and £-Ag3SI

Hoshino, H.; Yanagiya, H.; Shimoji, M. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

The electrical conductivity of Ag3SBr and £-Ag3SI has been measured as a function of hydro static pressure up to 3.15xlOsNm-2 in the temperature range 293 to 373 K. The activation volumes obtained at 303 K are —1.2±0.6 ...
Electrical Properties of Molten T12S

Nakamura, Y.; Matsumura, K.; Shimoji, M. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)

The electrical conductivity and thermoelectric power of T12S have been measured as a'function of temperature. Non-stoichiometric and impurity doping effects have been investigated. The results for molten T12S containing ...

Now showing items 41-60 of 882

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