Journal Articles (before-1995): Recent submissions

  • Transport and Kinetics in Two Phase Systems 
    Albery, W. John; Couper, A. Mottram; Hadgraft, Jonathan; Ryan, Charles (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    A new technique for investigating kinetics in and transport between two liquid phases is described. The interface of known area is established on the sinter in a Stokes diffusion cell. Transport to the interface is controlled ...
  • Kinetic Studies of Diatomic Free Radicals using Mass Spectrometry: Part 1.—System Description and Applications to F Atoms and FO Radicals 
    Clyne, Michael A. A.; Watson, Robert T. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    A system for sampling of free radicals from a discharge-flow system to a mass spectrometer is described. The molecular radicals FO, ClO, BrO, IO, OH, SF, NF2, and SF2, and the atoms N, O, Br, Cl and F have been detected ...
  • pH Effects on the Pulse Radiolysis of Deoxygenated Aqueous Solutions of Sulphur Dioxide 
    Eriksen, Trygve E. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    Dilute deoxygenated aqueous solutions of sulphur dioxide and its related anions HSO–3 and SO2–3 in the pH-range 2–11 were pulse irradiated and the time dependence of the transient optical absorptions and electrical conductance ...
  • Infra-red Study of the Reactions between Ethyl Isocyanate and the Surface of Magnesium Oxide 
    Eley, Daniel D.; Kiwanuka, Gerald M.; Rochester, Colin H. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    Ethyl isocyanate reacts at 306 K with isolated hydroxyl groups on the surface of magnesium oxide to form a urethane. The adsorption reaction is reversed by evacuation at high temperatures. Adjacent interacting hydroxyl ...
  • Low Temperature Gas-phase Oxidation of Aldehydes: Part 2.—Retardation by Formaldehyde above 120°C 
    Dixon, David J.; Skirrow, Geoffrey; Tipper, Charles F. H. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    The effect of added formaldehyde on the oxidation of acetaldehyde and propionaldehyde between 119 and 188°C has been studied using a static system. Formaldehyde retards the oxidation, and at 188°C the rate after 25 % ...
  • Low Temperature Gas-phase Oxidation of Aldehydes: Part 1.—The Reaction Below 120°C 
    Dixon, David J.; Skirrow, Geoffrey; Tipper, Charles F. H. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    The gas-phase oxidation of acetaldehyde, propionaldehyde and the butyraldehydes, in an unpacked and a packed vessel between 45 and 120°C, has been studied using a static system with a very small dead volume. Contrary to ...
  • Self-heating and Spontaneous Ignition in the Combustion of Gaseous Methylhydrazine 
    Gray, Peter; Sherrington, Malcolm E. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    The exothermic oxidation of gaseous monomethylhydrazine (CH3NHNH2) has been investigated in the gas phase over a temperature range 370–510°C in a 1-litre vessel. Critical conditions of pressure, temperature and reactant ...
  • Infra-red Study of Nitric Oxide Adsorption on Magnesium Oxide 
    Cerruti, Luigi; Modone, Eros; Guglielminotti, Eugenio (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    An i.r. study of nitric oxide adsorption on high area MgO (previously degassed at 800°C) at room temperature is reported. The adsorption of NO onto MgO produces i.r. bands at 800–900 cm–1, 1100–1250 cm–1, and 1350–1450 ...
  • Conductimetric Study of the Kinetics of Electrons in Pulse Irradiated n-Hexane and Cyclohexane at Room Temperature 
    Baxendale, John H.; Keene, John P.; Rasburn, Eric J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    Measurements of the ion current following an electron pulse have given values of kr/µ(where kr is the ion recombination rate constant and µ the electron mobility) and Gµ(extrapolated to zero field) of 1.00(± 0.08)× 10–6 V ...
  • Pulse Radiolysis Study of the Kinetics of Electron Reactions in Liquid n-Hexane at Room Temperature 
    Baxendale, John H.; Rasburn, Eric J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    The behaviour of solvated electrons, e–s, produced by the pulse radiolysis of n-hexane at 20°C has been followed using optical absorption techniques. Rate constants for the reaction of e–s with naphthalene, biphenyl, ...
  • Ionic solvation in water + Co-solvent mixtures: Part 2.—Free energies of transfer of single ions from water into mixtures of water with acetone, isopropanol, glycerol or methanol 
    Cecil F. Wells (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    The method used previously to calculate the free energy of transfer ΔG°t of the solvated proton from water into methanol + water mixtures is applied to mixtures of water with acetone, isopropanol or glycerol. ΔG°t(HCl) for ...
  • Absolute Enthalpy of Hydration of the Proton using Data for Doubly-charged Complex Ions 
    Lister, Maurice W.; Nyburg, Stanley C.; Poyntz, R. Barry (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    The method used by Halliwell and Nyburg to estimate the absolute enthalpy of hydration of the proton using data for singly-charged ions has been extended to larger, doubly-charged, complex ions. Certain heats of solution ...
  • Motional State of Sorbed Nitrogen in Mordenite 
    Takaishi, T.; Yusa, A.; Ogino, Y. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    Sorption isosteres of nitrogen in mordenite have been accurately measured by a gravimetric method over a temperature range – 50 to 25°C. Sorption isotherms at 25, 50 and 75°C have also been measured by the use of a high ...
  • Decomposition Reactions of Nickel Formate, Nickel Malonate, Nickel Maleate and Nickel Fumarate in Oxygen 
    Wheeler, Brian R.; Galwey, Andrew K. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    Decomposition of nickel formate, nickel malonate, nickel maleate and nickel fumarate in oxygen yields nickel oxide and carbon dioxide only. The shape of each fractional reaction-time curve is comparable with that for the ...
  • Rapid Flocculation Rates of Polystyrene Latex Dispersions 
    Hatton, William; McFadyen, Peter; Smith, Alec L. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    An automatic flow ultramicroscope particle counter with laser illumination has been employed to determine absolute rates of coagulation of monodisperse polystyrene latex dispersions in excess electrolyte. The particles ...
  • Reactions of Energetic Hydrogen Atoms with Simple Hydrocarbons: Part 3.—Bromine Scavenger Effects 
    Hall, Richard B.; Malcolme-Lawes, David J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    The effect of small amounts of bromine on the hot abstraction and substitution yields from recoil tritium atoms reacting with methane are examined in the presence of neon, argon and xenon. It is concluded that bromine ...
  • Various Reactions Catalyzed by the Electron Donor-Acceptor Complex of Polynaphthoquinone with Potassium 
    Iwasawa, Yasuhiro; Fujitsu, Hiroshi; Onishi, Takaharu; Tamaru, Kenzi (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    The H2-D2 exchange reaction, the synthesis of ammonia, hydrogen exchange reaction of propene with deuterium and the isomerization of butene over the electron donor-acceptor (EDA) complexes of potassium with metal-free ...
  • Adsorptive Elastic Moduli ol Kaolinite and Porous Glass, and the Structure of the Adsorbed Phase 
    Metcalfe, Alan; Wilcock, Robert J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    The changes in length of rods of kaolinite and porous glass when exposed to the vapours of H2O, CH3OH, CHCl3, and CCl4 have been studied. Differences in derived elastic moduli of the adsorbent with different adsorbates are ...
  • Second Limit of Hydrogen-I-Oxygen Mixtures: the Reaction H+HO2 
    Baldwin, Roy R.; Fuller, Margaret E.; Hillman, John S. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    Measurements of the second limit of H2+ O2 mixtures at very low O2 concentrations have shown that the results at 500°C cannot be interpreted on the assumption that the only reaction between H atoms and HO2 radicals is the ...
  • Charge transfer interactions of heteroaromatic compounds: Part 5.—Complexes between pyridine-1-oxides and halogens 
    Beggiato, Giancarlo; Aloisi, Gaetand G.; Mazzucato, Ugo (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    Charge transfer complexes between pyridine-1-oxides and halogens in CCl4 have been investigated spectrophotometrically. Stability constants are reported for complexes between Br2, I2, IBr and ICl as acceptors and substituted ...

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