Journal Articles (before-1995): Recent submissions

  • Solvent effect on the dimerization and hydration constant of benzoic acid 
    Fujii, Yukio; Sobue, Kozo; Tanaka, Motoharu (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (06), 1978)
    The hydration and dimerization of benzoic acid have been studied at 25°C by partition and solubility measurement of water in organic phase containing benzoic acid. Organic solvents used include n-hexane, cyclohexane, ...
  • Luminescence of 9-cyanoanthracene. Identification of new excimeric species 
    Ebeid, El-Zeiny M.; Morsi, Salah E.; El-Bayoumi, M. Ashraf; Williams, John O. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (06), 1978)
    From studies of the emission spectra of 9-cyanoanthracene (9 CNA) solutions, glasses, polycrystalline films and single crystals at 298 and 77 K a centrosymmetric excimeric species with emission maximum at ≈ 490 nm has been ...
  • Solubility of helium and hydrogen in some water + alcohol systems 
    Cargill, Robert W. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (06), 1978)
    The solubility of helium and of hydrogen in water + ethanol and in water + t-butanol mixtures has been measured over the whole range of mixture compositions and at several temperatures between 4 and 62°C. The thermodynamic ...
  • Isomerization of n-butenes on A-type zeolites studied by infrared spectroscopy. Part 1.—n-butene adsorption on zeolites containing alkali and alkaline earth cations 
    Förster, Horst; Seelemann, Rudolf (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (06), 1978)
    Adsorption of n-butenes on highly activated type A-zeolites containing alkali and alkaline earth cations is studied by infrared spectroscopy. The rate of adsorption is determined by the butene–zeolite interaction, depending ...
  • Adsorption/absorption characteristics of caesium on oxidised stainless steel 
    Woolley, Robert L. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (06), 1978)
    The transitions between gas, adsorbed state and absorbed state have been studied for the case of caesium deposited on oxidised stainless steel. The theoretical discussion takes account of detailed properties of the surface ...
  • Acid–base properties of molten oxides and metallurgical slags 
    Duffy, John A.; Ingram, Malcolm D.; Sommerville, Iain D. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (06), 1978)
    The application of the Lux–Flood concept to acid–base reactions in oxide systems is discussed in the light of spectroscopic information concerning the “state” of oxide ions. In slag systems (e.g. molten silicates) it is ...
  • Shock tube studies of the high temperature pyrolysis of acetylene and ethylene 
    Cundall, Robert B.; Fussey, David E.; Harrison, Andrew J.; Lampard, Desmond (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (06), 1978)
    Shock heating of acetylene and ethylene, under the conditions 1500–2500 K, 1–2 bar and molar fraction 0.07–2 % hydrocarbon in argon, has produced spectrographic evidence concerning the products of pyrolysis. Kinetic ...
  • Temperature and Pressure Effects on Surface Processes at Noble Metal Electrodes Part 2.—Volume of Adsorbed H and Oxygen Species at Pt and Au 
    Conway, Brian E.; Currie, John C. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (06), 1978)
    The multiple states of electrosorbed H and oxygen species at Pt, which arise below monolayer coverage, are of current interest in electrochemical surface science. The results of experiments on the effects of high hydraulic ...
  • Temperature and pressure effects on surface processes at noble metal electrodes. Part 1.—Entropy of chemisorption of H at Pt surfaces 
    Conway, Brian E.; Angerstein-Kozlowska, Halina; Sharp, William B. A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (06), 1978)
    The temperature dependence of underpotential deposition of H at Pt electrodes has been investigated. The four main states of chemisorbed H which can be distinguished in dilute, highly purified aqueous acid solutions have ...
  • Adsorption of water vapour by silica and the effect of surface methylation 
    Barraclough, Peter B.; Hall, Peter G. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (06), 1978)
    A comparative study of nitrogen (78 K) and water vapour (273–298 K) adsorption isotherms has been carried out with precipitated silica, a flame hydrolysis product (Cabosil) and with surface modified Cabosil obtained by ...
  • Heterocoagulation Part 3.—Interactions of Polyvinyl Chloride Latex with Ludox HS Silica 
    Bleier, Alan; Matijević, Egon (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (06), 1978)
    The stability of a mixed colloidal dispersion consisting of monodispersed PVC latex and Ludox HS silica particles in the presence of counterions of 1+, 2+ and 3+ charge has been studied by light scattering, electrokinetic ...
  • Vapour pressure measurements on some organic high explosives 
    Cundall, Robert B.; Palmer, T. Frank; Wood, Colin E. C. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (06), 1978)
    Equilibrium vapour pressures of 1,3,5-trinitrobenzene (TNB), 2,4,6-trinitrotoluene (TNT), 2,4,6-trinitro-m-xylene (TNX), 2,4,6-trinitromesitylene (TNM), 2,4,6-trinitroaniline (TNA), 2,4,6-trinitro-m-phenylene diamine (DATB), ...
  • Lennard-Jones 12:6 Parameters for Ten Small Molecules 
    Clifford, Anthony A.; Gray, Peter; Platts, Norman (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (2), 1977)
    Yalucs for Lennard-Jones parameters, calculated from recently measured viscosity data for temperatures between 200 and 500 K, are reported for ten small molecules.
  • Acidic Properties of Silica-Alumina Gels as a Function of Chemical Composition: Titration and Catalytic Activity Measurements 
    Damon, Jean-Pierre; Delmon, Bernard Delmon; Bonnier, Jane-Marie (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (2), 1977)
    The strength and number per unit surface area of acid sites on a series of silica—aluminas of composition ranging from 0 to 100 % in alumina have been investigated. The results of titration by n-butylamine in the presence ...
  • Evolution of the Acidic Properties of Silica—Alumina Gels as a Function of Chemical Composition: Infrared Approach 
    Scokart, Paul O.; Declerck, Francois D.; Sempels, Raymond E.; Rouxhet, Paul G. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (2), 1977)
    The adsorption of pyridine and CD3CN on silica–alumina gels covering the whole composition range (0–100 % Al2O3) has been studied by infrared spectroscopy, the amount adsorbed being measured by an electrobalance. The ...
  • E.S.R. Study of Ion Pairs Involving the Pyrene Anion 
    Claridge, Rodney F. C. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (2), 1977)
    An e.s.r. study of the ion pair formation between pyrene and alkali metals in various ether solvents has been carried out. Depending on the nature of the solvent and the alkali metal ion, various types of species are ...
  • Dissolution and Passivation of Nickel: X-ray Photoelcctron Spectroscopic Study 
    Dickinson, Thomas; Povey, Andrew F.; Sherwood, Peter M. A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (2), 1977)
    The presence and nature of surface species formed on a nickel electrode after polarisation in 0.5 mol dm~3 sulphuric acid and 0.5 mol dm-3 sulphuric acid + 0.005 mol dm-3 nickel sulphate has been investigated by X-ray ...
  • Kinetic and Thermodynamic Character of Reducing Species Produced on Pulse Radiolysis of Acetonitrile 
    Bell, Ian P.; Rodgers, Michael A. J.; Burrows, Hugh D. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (2), 1977)
    During nanosecond pulse radiolysis of liquid acetonitrile a transient optical absorption was observed in the spectral range 500 to 1500 nm. The extreme reactivity of this species towards solutes capable of accepting electrons ...
  • Calorimetric Evidence for a Bidimensional Phase Change in the Monolayer of Nitrogen or Argon Adsorbed on Graphite at 77 K 
    Rouquerol, Jean Rouquerol; Partyka, Stanislas; Rouquerol, Franchise (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (2), 1977)
    Nitrogen adsorption on a Sterling MT 3100 graphitized carbon black is followed by isothermal microcalorimetry at 77 K. A special feature of the curve of isosteric heats is a distinct peak recorded for a coverage close to ...
  • Solute Interactions in Dilute Solutions Part 2: A Statistical Mechanical Study of the Hydrophobic Interaction 
    Clark, Alan H.; Franks, Felix; Pedley, Michael D.; Reid, David S. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (2), 1977)
    The aqueous solution properties of aliphatic alcohols have been analysed in terms of pairwise hydrophobic interactions. The potential of average force hz(r) was obtained as the sum of the vacuum potential U(r), calculated ...

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