Journal Articles (before-1995): Recent submissions

  • General solution to the Smith–Ewart equation for emulsion polymerization kinetics 
    Hawkett, Brian S.; Napper, Donald H.; Gilbert, Robert G. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (04), 1977)
    Using matrix methods, complete time-dependent solutions are derived for the Smith–Ewart equations describing polymerization in emulsion systems with a constant number of polymerizing loci, where the mechanisms of free ...
  • Melting of ice in porous solids 
    Rennie, George K.; Clifford, John (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (04), 1977)
    Differential scanning calorimetry (d.s.c.) and nuclear magnetic resonance (n.m.r.) techniques were used to study the melting of ice in porous solids. At low water contents (less than about three monolayers) no freezing ...
  • Application of the pressure-jump technique to the measurement of rates of fast reactions in non-aqueous solvents 
    Buschmann, Hans-J.; Knoche, Wilhelm; Day, Robert A.; Robinson, Brian H. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (04), 1977)
    Modifications to a pressure-jump autoclave are described which permit the measurement of rapid rates of reaction in aprotic solvents. In such solvents, a chemical system at equilibrium will generally be perturbed primarily ...
  • Photoreduction of 1,10-Phenanthroline 
    Bandyopadhyay, Baida N.; Harriman, Anthony (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (04), 1977)
    The effects of solvent polarity on the photophysical properties of 1,10-phenanthroline indicate the close proximity of (n, π*) and (π, π*) excited singlet states, whilst the lowest triplet state is (π, π*) in all solvents. ...
  • Transfer free energies and entropies of hydrobromic acid in ethanol + water mixtures: structure of aquo-alcoholic solvents 
    Das, Kaushik; Bose, Kumardev; Kundu, Kiron K. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (04), 1977)
    Standard potentials (E⊖) of the Ag–AgBr electrode obtained from e.m.f. values of the cell Pt, H2(g, 1 atm)/HBr(m), solvent/AgBr–Ag at seven temperatures (10–40°C) have been used to compute standard free energies (ΔG⊖t) and ...
  • Kinetics of electron transfer reaction between manganate and permanganate ions. Calculation of rate constant and activation energy 
    Dolin, Sergei P.; Dogonadze, Revaz R.; German, Ernst D. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (04), 1977)
    The rate constant and activation energy of the electron transfer reaction in a polar medium, between MnO–4 and MnO2–4 ions, are calculated in terms of the theory of nonadiabatic transitions. The dependence of the matrix ...
  • Reactions of hydrogen atoms and aliphatic radicals with monovalent cadmium and nickel ions as a source of hydrogen yield in some radiation chemical systems 
    Freiberg, Mira; Meyerstein, Dan (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (04), 1977)
    The effect of CdSO4 and NiSO4 on the radiolytic hydrogen yield and its isotopic composition in the systems H2O + CH3OH, H2O + CD3OH, D2O + CH3OD, H2O +(CH3)2CHOH, H2O +(CH3)2 CDOH and D2O +(CH3)2CHOD are reported. The ...
  • Reactions of hydrogen atoms and aliphatic radicals with monovalent cadmium and nickel ions as a source of hydrogen yield in some radiation chemical systems 
    Freiberg, Mira; Meyerstein, Dan (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (04), 1977)
    The effect of CdSO4 and NiSO4 on the radiolytic hydrogen yield and its isotopic composition in the systems H2O + CH3OH, H2O + CD3OH, D2O + CH3OD, H2O +(CH3)2CHOH, H2O +(CH3)2 CDOH and D2O +(CH3)2CHOD are reported. The ...
  • Infrared study of effects of sulphur-poisoning on the adsorption of carbon monoxide by nickel 
    Rochester, Colin H.; Terrell, Robert J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (04), 1977)
    The effects of preadsorbed hydrogen sulphide, n-propyl mercaptan, dimethyl sulphide, thiophene and carbonyl sulphide on the adsorption of carbon monoxide by silica supported nickel have been compared by study of the infrared ...
  • Infrared study of the adsorption of sulphur compounds on silica and silica-supported nickel 
    Rochester, Colin H.; Terrell, Robert J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (04), 1977)
    Hydrogen bonding interactions between isolated hydroxyl groups on silica and adsorbed hydrogen sulphide, n-propyl mercaptan, dimethyl sulphide and thiophene molecules have been detected by infrared spectroscopy. Chemisorption ...
  • Arrhenius activation energy of reactions that are almost diffusion-controlled 
    Logan, S. R. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (04), 1977)
    Expressions are derived for the Arrhenius activation energy (Ea) of bimolecular reactions in solution occurring on almost every collision, in terms of the parameter B from the temperature-dependence of the solvent viscosity. ...
  • Homogeneous catalysis of cathodic reduction of oxygen in copper–cystamine aqueous solutions 
    Bettelheim, Armand; Faraggi, Moshe; Hodara, Isaac; Manassen, Jost (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (04), 1977)
    The copper cystamine complex is a suitable system for the homogeneous catalysis of oxygen cathodic reduction in aqueous solutions. A steady state cathodic current density of 3.2 mA/cm2 at 0.2 V and an overvoltage decrease ...
  • Enthalpies and entropies of ionization of 2- and 3-substituted phenols in methanol + water mixtures 
    Rochester, Colin H.; Wilson, David N. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (04), 1977)
    Enthalpies of solution and enthalpies and entropies of ionization of three (Me, Cl and NO2) 2-substituted phenols, three (Me, Cl, NO2) 3-substituted phenols, and 3,5-dinitrophenol in methanol + water mixtures have been ...
  • Studies of the kinetics of nucleation and growth of pigment dispersions using a laser light-scattering apparatus in a flow system 
    Nobbs, James H.; Patterson, David (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (04), 1977)
    The shape and size distribution of pigment particles affects their physical properties, in particular their hue. A continuous coupling flow system has been developed to determine and study the factors that influence particle ...
  • Potentiometric studies of some lanthanide glycollate systems 
    Carpenter, Peter; Monk, Cecil B. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (04), 1977)
    Precise potentiometric titrations have been carried out on a number of lanthanide glycollate systems, using a technique which avoids junction potentials and the changes in glass electrode asymmetry potential due to replacement ...
  • Investigation of the decomposition and reduction of “nickel peroxide” by thermal analysis 
    Bond, Geoffrey C.; Tripathi, Jai B. P. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (04), 1977)
    The decomposition in air and the reduction by hydrogen of commercial “nickel peroxide” has been investigated by thermal analysis (d.t.a. and t.g.a.). It is probably Ni2O3· 2H2O: on heating in air, it loses water between ...
  • Note on the proton-donating ability of water in hydrogen-bonding reactions 
    Christian, Sherril D.; Tucker, Edwin E.; Mitra, A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (03), 1977)
    A vapour pressure method has been used to determine the partial pressure of water as a function of the concentrations of dissolved water and quinoline in the solvents diphenylmethane, n-hexadecane and several mixtures of ...
  • Effect of sulphuric acid on the cobalt-60 γ-ray induced oxidation of ferrous sulphate solutions 
    Matthews, Ralph W. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (03), 1977)
    The effects of variations in sulphuric acid and oxygen concentrations on the yields of ferric ion from cobalt-60 gamma irradiated solutions of ferrous sulphate have been studied. Various kinetic models, some derived from ...
  • Acridine: an investigation of its molecular and crystalline photophysical behaviour 
    Williams, John O.; Clarke, Brian P. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (03), 1977)
    The absorption spectrum of acridine in various solvents together with the fluorescence spectra and lifetimes in a rigid matrix confirms the presence of a weak, intrinsic π–π* emission in this material with its origin at ...
  • Solid state properties of copper containing spinel solid solutions (CuxMg1–xAl2O4) 
    Sharpe, Peter K.; Vickerman, John C. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1977, 73 (03), 1977)
    The solid state and surface properties of a series of copper containing spinel solid solutions (Mg1–xCuxAl2O4) have been studied using X-ray diffraction, magnetic measurements, e.p.r., reflectance spectroscopy, X-ray ...

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