Journal Articles (before-1995): Recent submissions

  • Reactions of Energetic Hydrogen Atoms with Simple Hydrocarbons Part 1.—The Effect of Moderators 
    Terry, R.; Baker, K. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (5), 1973)
    The reactions of recoil tritium atoms with ethane have been studied in the presence of N2 and CF^ moderators. The results suggest that collisional dissociation of excited HT, initially produced by direct reaction, may be ...
  • Infra-red Study of Hydrogen-bonding Interactions at the Solid/Liquid Interface 
    Griffiths, David M.; Marshall, Kenneth; Rochester, Colin H. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    An infra-red cell is described which enables the measurement of spectra of adsorbed species and the surfaces of powdered solids at the solid/liquid interface. The hydrogen-bonding interactions of acetone, ether and pyridine, ...
  • Kinetics of Ozone Formation in the Pulse Radiolysis of Oxygen+Ethylene Mixtures 
    Bevan, P. L. T.; Johnson, G. R. A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (5), 1973)
    Pulse radiolysis of O2+ C2H4 mixtures has been used to determine the rate constant of the reaction O + O2+ M → O3+ M (M = C2H4) the values, obtained from the kinetics of O3 formation and from the dependence of the O3 yield ...
  • Theoretical Analysis of Rates of Emulsion Polymerization 
    Gilbert, Robert G.; Napper, Donald H. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    The importance of emulsion and seeded polymerizations that proceed with a small average number of free radicals per particle (n) has recently been recognized. We now show how to generate analytical solutions to the set of ...
  • Relative Rate Constants for the Reaction of Hydrogen Atoms with Some Fluorinated Mono-olefins 
    Kilcoyne, John P.; Jennings, Keith R. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    Relative rate constants for the addition of hydrogen atoms to fluorinated ethylenes, propenes and butenes have been determined by a competitive technique. Values relative to C2H4= 1.00 are C2H3F = 0.44, CH2CF2= 0.36, ...
  • Chemistry of Recoil Tritium Atoms: Part 5.—Extension of the Estrup-Wolfgang Theory of Hot Atom Reactions to Mixtures of Reactive Components 
    Johnston, A. J.; Urch, D. S. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    The Estrup–Wolfgang theory for the analysis of data from hot-atom experiments is extended to include the case of two reactive components. Energy shielding (K) integrals are found which describe the way in which the reactions ...
  • Kinetics of Electrode Reactions in Liquid Ammonia: Part 2.—FeIII/FeII and CoIII/CoII redox couples 
    Brown, Oliver R.; Thornton, Sean A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    Polarisation data has been obtained for the CoII/CoIII and FeII/FeIII couples at rotating disc electrodes of platinum, gold and vitreous carbon at – 30°C in ammonia acid solution. In addition, metal wires and carbon rod ...
  • Hydrogenation of Ethylene on Metal Electrodes: Part 2.—Structure of the Adsorption Layer on Platinum at a Working Condition on Open Circuit 
    Fujikawa, Keikichi; Katayama, Akiko; Kita, Hideaki (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    The structure of the adsorption layer was studied by the potential sweep method on a platinum electrode in 1 N HC104 solution saturated with a reaction gas of various compositions (mixtures of H2, C2H4 and He). Results ...
  • Free Radical Addition to Olefins: Part 10.—Addition of Dibromofluoromethyl Radicals to Fluoroethylenes 
    Sloan, John P.; Tedder, John M.; Walton, John C. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (6), 1973)
    The gas phase photochemical addition of tribromofluoromethane to a series of fluoro-olefins has been studied over a range of temperatures. The products included those from addition of dibromofluoromethyl radicals to the ...
  • Photosensitization of Free-radical Polymerisation by Mn2(CO)10+C2F4 
    Bamford, C. H.; Mullik, S. U. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (6), 1973)
    A study has been made of the free-radical polymerization of methyl methacrylate at 25°C photo-initiated (λ= 435.8 nm) by Mn2(CO)10+ C2F4. The manganese and fluorine contents of the polymers are consistent with the view ...
  • Adsorption of Phenols from Non-polar Solvents on to Silica Gel 
    Davis, Keith M. C.; Deuchar, James A.; Ibbitson, Douglas A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (6), 1973)
    A series of p-substituted phenols have been adsorbed from benzene solution on to silica gel. With the exception ofp-t-butylphenol, limiting adsorptions of the solutes are almost equal in magni tude and suggest a ...
  • Homogeneous Gas Phase Pyrolysis of 7V-t-Butylacetamide 
    Maccoll, Allan; Nagra, Surgit S. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (6), 1973)
    The kinetics of the gas phase pyrolysis of N-t-butylacetamide have been studied in a static system over the temperature range 385–465°C. The decomposition occurs by two simultaneous, homogeneous and unimolecular processes. ...
  • Real Condition of Oxidized Platinum Electrodes: Part 2. —Resolution of Reversible and Irreversible Processes by Optical and Impedance Studies 
    Conway, Brian E.; Gottesfeld, Shimson (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (6), 1973)
    The reversible component in Pt surface oxidation (demonstrated in Part 1) has been characterised by means of electric modulated reflectance measurements and related to the electrochemical oxide formation and reduction ...
  • Appearance of Sulphatoferric Complexes in the Oxidation of Ferrous Sulphate Solutions: A Study by Pulse Radiolysis 
    Jayson, G. G.; Parsons, B. J.; Swallow, A. J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (6), 1973)
    The rate of the reaction between perhydroxyl radicals and ferrous ions, like that between hydroxyl radicals and ferrous ions, is little affected when the ferrous ions are associated with sulphate. However, sulphate ions ...
  • Abstraction of Chlorine Atoms from Alkyl Chlorides by the Trimethylsilyl Radical 
    Cadman, P.; Tilsley, G. M.; Dickenson, A. F. Trotman (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (5), 1973)
    The relative rates of chlorine atom abstraction from alkyl chlorides by the trimethylsilyl radical have been studied by a competitive technique between 400 and 580 K in the gas phase. These results have been put on an ...
  • Ordered Layers of Aliphatic Alcohols and Carboxylic Acids at the Pure Liquid/Graphite Interface 
    Findenegg, Gerhard H. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (6), 1973)
    The surface excess mass of pure hcxadecan-l-ol and of three pure monocarboxylic acids (decanoic, tctradecanoic, hcxadecanoic) at the liquid/Graphon interface has been measured as a function of temperature, using a ...
  • Surface Probing of Synthetic Faujasites by Adsorption of Carbon Dioxide: Part 1.—Infra-red Study of Carbon Dioxide Adsorbed on Na-Ca-Y and Na-Mg-Y Zeolites 
    Jacobs, Peter A.; Cauwelaert, Franz H. van; Vansant, Etienne F.; Uytterhoeven, Jan B. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (6), 1973)
    Infra-red spectroscopy of carbon dioxide adsorbed on Na-Ca(Mg)-Y faujasites is used to determine the distribution of Ca and Mg ions over the cation sites. Physisorption of CO2 provides a sensitive method for the detection ...
  • y-Radiolysis of Gaseous Hydrogen Sulphide in the presence of Hydrogen Chloride, Carbon Disulphide and Nitrous Oxide 
    Huyton, D. W.; Woodward, T. W. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (6), 1973)
    Addition of HC1 to H2S increases the radiation yield of H2 G(H2) 7.0->10.0 by an electron scavenging process involving HC1 and H2S. CS2 lowers the H2 yield in pure H2S probably by reaction with hot H atoms and also ...
  • Free Radical Yields in the Radiolysis of Gaseous Hexafluoroethane 
    Cooper, Ronald; Robert Haysom, Howard (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (5), 1973)
    The radiolysis of gaseous hexafluoroethane yields CF4(G= 2.5), C3F8(G= 0.31) and C4F10(G= 0.10) as major products. In the presence of Br2, Cl2 or HCl these products are scavenged and replaced by yields of CF3 and C2F5 ...
  • Surface Studies on Graphite: Desorption of Surface Oxide 
    Barton, Stuart S.; Harrison, Brian H. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (6), 1973)
    The kinetics of desorption of surface oxide as CO and CO2 from graphite have been followed, using a mass spectrometer system, allowing their activation energies of desorption to be measured as a function of the amount ...

Search DSpace


Advanced Search

Browse

My Account