Journal Articles (before-1995): Recent submissions

  • Electron Spin Resonance Studies of Isotopically Labelled Oxygen Species Adsorbed on Supported Molybdenum 
    Che, Michel; Tench, Anthony J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    The molecular ion (O2)5 has been observed on the surface of the moIybdenum/SiO2 and molyb- denum/Al2O3 systems by e.s.r. Using oxygen isotopically enriched in 17O, two different hyperfine splittings were observed in ...
  • Proton and Deuteron Mobility in Normal and Heavy Water Solutions of Electrolytes 
    Roberts, Noel K.; Northey, Helen L. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    Proton and deuteron mobility in normal and heavy water solutions of some alkali halides (NaCl, KCI, KBr and KI) and tetra-alkylammonium bromides (where alkyl is Me, Et, Pr or Bu) is measured polarographically and the ...
  • Kinetics of the Thermal Isomerisation of Hexamethyldisilane 
    Davidson, Iain M. T. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    A kinetic investigation of the gas-phase isomerisation of hexamethyldisilane between 717 and 780 K with initial pressures of 10-125 mmHg is described, and discussed in relation to other work on the thermolysis of ...
  • Ellipsometric Investigation of Black Soap Films 
    Engelsen, Daan Den; Frens, Gerrit (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    Thin soap films of sodium dodecyl sulphate and sodium dodecyl bcnzenesulphonatc have been studied with a combination of ellipsometry and reflectometry. It is demonstrated that an optical three-layer model is superior ...
  • Intermediates in the Nanosecond Pulse Radiolysis of Triphenylamine Solutions in Cyclohexane 
    Zador, Erika; Warman, John M.; Luthjens, Leonard H.; Hummel, Andries (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    The pulse radiolysis of solutions of triphenylamine (TPA) in cyclohexane has been investigated using nanosecond time resolution. In addition to the transient absorption at 620 nm which has been previously observed in ...
  • Kinetics of Electrode Reactions in Liquid Ammonia: Part 2.—FeIII/FeII and CoIII/CoII Redox Couples 
    Brown, Oliver R.; Thornton, Sean A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    Polarisation data has been obtained for the CoH/CoHI and Fe'VFc111 couples at rotating disc electrodes of platinum, gold and vitreous carbon at -30°C in ammonia acid solution. In addition, metal wires and carbon rod ...
  • Hydrogenation of Ethylene on Metal Electrodes: Part 2.—Structure of the Adsorption Layer on Platinum at a Working Condition on Open Circuit 
    Fujikawa, Keikichi; Katayama, Akiko; Kita, Hideaki (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1974, 70 (1-6), 1974)
    The structure of the adsorption layer was studied by the potential sweep method on a platinum electrode in 1 N HC104 solution saturated with a reaction gas of various compositions (mixtures of H2, C2H4 and He). Results ...
  • Investigation of the Size Distribution of Non-ionic Micelles formed from a Polystyrene-Polyisoprene Block Copolymer in N, //-Dimethylacetamide 
    Booth, Colin; Naylor, Timothy D.; Price, Colin; Rajab, Naman S.; Stubbersfield, Rita B. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12), 1978)
    Solutions of a polystyrene–polyisoprene block copolymer in N,N-dimethylacetamide were studied by gel permeation chromatography. The effect of temperature on the equilibrium between free copolymer chains and micelles was ...
  • Static Relative Permittivity of some Electrolyte Solutions in Water and Methanol 
    Beek, Wim M. van; Mandel, Michel (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12), 1978)
    Experimental results are presented for the relative permittivity of several chlorides in water and methanol at 25°C measured at 5–20 MHz up to concentration of 0.1 mol dm–3. These permittivities are interpreted as the ...
  • Protonic Conductivity in Layered SnCl2 • 2H2O Single Crystal 
    Mognaschi, Ezio R.; Chierico, Angelo; Parravicini, Gianbattista (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12), 1978)
    The electric conductivity of stannous chloride dihydrate single crystals, measured both with injecting and with metallic electrodes, shows two contributions: a critical, frequency dependent behaviour around the phase ...
  • Open-end Capillary Method in Tracer and Mutual Diffusion of Electrolyte Solutions 
    M'Halla, Jalel; Turq, Pierre; Chemla, Marius (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12), 1978)
    In this study, we derive the general solution of the diffusion equation for multicomponent systems, even with non-constant diffusion coefficients, in the case of limiting conditions corresponding to the open-end capillary ...
  • Carbonylation of Methanol and Ethanol on a Rhodium-Zeolite Catalyst 
    Christensen, Bjarne; Scurrell, Michael S. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12), 1978)
    The carbonylation of methanol and ethanol on a rhodium-X zeolite has been studied. Particular emphasis has been placed on the effect of the concentration of the required alkyl iodide “promoter” on the selectivity of the ...
  • Reactions of Alkyl Radicals with Nitrogen Trifluoride 
    Cadman, Philip; Inel, Yuksel; Trotman-Dickenson, Aubrey F. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12), 1978)
    Photolysis of mixtures of nitrogen trifluoride with the appropriate ketones (in the temperature range 303–486 K) has enabled the reactions of CH3, CF3, C2H5, i-C3H7 and t-C4H9 radicals with nitrogen trifluoride to be ...
  • Self-reactions of Isopropylperoxy Radicals in the Gas Phase 
    Kirsch, Leslie J.; Parkes, David A.; Waddington, David J.; Woolley, Allan (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12), 1978)
    The photo-oxidation of 2,2′-azopropane has been studied in order to determine the overall rate constant for the second-order removal of isopropylperoxy radicals. Arrhenius parameters of log10(Aobs/dm3 mol–1 s–1)= 9.15 ± ...
  • Reflectance Spectra of Carbon Monoxide Adsorbed on Alkaline Earth Oxides 
    Zecchina, Adriano; Stone, Frank S. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12), 1978)
    The adsorption of carbon monoxide at room temperature on well-outgassed specimens of MgO, CaO, SrO and BaO gives rise to a strong absorption spectrum between ν= 15000 and ν= 40000 cm–1. The stronger the outgassing conditions, ...
  • Colloid Stability in Butanol 
    Cooper, W. David; Marsden, Robert S. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12), 1978)
    The stability ratio (W) of colloidal dispersions of Graphon and polystyrene dispersed in butanol containing varying amounts of HCl and LiCl has been determined. Rate constants for rapid flocculation are found to be in good ...
  • Adsorption of Gas Mixtures of 2,2-Dimethylpropane and n-Butane on Graphite and Application of Ideal Adsorbed Solution Theory 
    Hall, Peter G.; Müller, Shirley Ann (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12), 1978)
    Results for gas mixtures of 2,2-dimethylpropane and n-butane adsorbed in the region of monolayer coverage on graphite at 303 K, show that 2,2-dimethylpropane is preferred to n-butane over the whole range of compositions, ...
  • X-ray photoelectron spectroscopic (X-p.e.s.) studies on in situ photoinduced decomposition of inorganic molecular ions. Part 2.—Na[ClOx] system: mechanistic (x= 3, 4) and variable-temperature (x= 3) investigations 
    Copperthwaite, Richard G.; Lloyd, John (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12), 1978)
    The first-order rate constants for the decomposition of Na[ClO3] and Na[ClO4] when studied by X-p.e.s. are shown to have a linear dependence on the intensity of the ionising radiation used. A simple steady-state model, ...
  • Addition of i-Butane to Slowly Reacting Mixtures of Hydrogen and Oxygen at 480°C 
    Baker, Richard R.; Baldwin, Roy R.; Walker, Raymond W. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12), 1978)
    Analysis has been made of the products formed when small amounts of i-C4H10 and i-C4H8 are added to slowly reacting mixtures of H2+ O2 at 480°C. The variation of [C3H6]/[C4H8] with [O2], with i-C4H10 as additive, gives the ...
  • Competitive Preferential Solvation Theory of Weak Molecular Interactions 
    Nagy, Ottó B.; Muanda, Mukana Wa; Nagy, Jànos B. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1978, 74 (09-12), 1978)
    The use of linear Benesi–Hildebrand, Scott or Scatchard equations to characterize molecular interactions leads frequently to anomalous results which cannot be interpreted easily in terms of traditional concepts. The situation ...

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