Journal Articles (before-1995): Recent submissions

Now showing items 601-620 of 882

Heat Capacity of the H2O/KNaX Zeolite Adsorption System

Berezin, G. I.; Kiselev, A. V.; Sinitsyn, V. A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (3), 1973)

The heat capacity of the H2O/KNaX zeolite system has been measured at 34°C for various amounts of adsorption. The dependence of measured heat capacity of this system and calculated average molar heat capacity of adsorbate ...
Branching Intermediates in the Cool Flames of Acetaldehyde and Simple Ketones

Hoare, Derrick E.; Lill, David E. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (3), 1973)

Contrary to the postulate of Halstead et al. our work suggests that peracetic acid is not the degenerate branching intermediate in the oxidation of acetaldehyde at temperatures where cool flames occur. It appears that ...
Electrons in Liquid Alcohols at Low Temperatures

Baxendale, J. H.; Wardman, Peter (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (3), 1973)

The spectra due to electrons in alcohols at temperatures near their melting points show absorptions in the far and infra-red which, in general, decay to produce increased absorptions in the visible. At these temperatures ...
Radiolysis of Benzene+Bromobenzene Solutions

Kumar, S. S.; Merklin, J. F. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (3), 1973)

Yields of γ-ray radiolysis products from benzene, bromobenzene and solutions of benzene and bromobenzene have been measured. The yield of biphenyl was larger in the solutions than in either of the pure solvents. Rate ...
Electron Spin Resonance Study of Intermolecular Cation Exchange Between Sodium Iodide and the Ion Pairs of Sodium Benzophenone and Sodium Naphthalene in Tetrahydrofuran

Bailey, J. C.; Colau, P. R.; Warhurst, E. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (3), 1973)

Intermolecular cation exchange between sodium iodide and sodium benzophenone and sodium naphthalene ion pairs in THF has been studied by e.s.r. linewidth measurements. For sodium benzophenone the plot of the reciprocal ...
Reaction of Hydrogen Atoms with Nitrous Oxide

Baldwin, R. R.; Gethin, A.; Walker, R. W. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (2), 1973)

The velocity constant of the reaction H + N2O → N2+ OH (22) has been obtained at 500°C by the addition of N2O to slowly reacting mixtures of H2+ O2+ He and measurement of the relative rates of formation of N2 and H2O. The ...
Studies in Ion Solvation in Non-aqueous Solvents and Their Aqueous Mixtures: Part 15.1—Free Energies of Transfer of Cadmium Chloride from Water to 10-40 % (w/w) Methanol-Water Mixtures at 25°C; Dissociation of CdCD; Use of Dilute Cadmium Amalgam Electrodes. The Group II Cations

Feakins, D.; Willmott, Alan S.; Willmott, Ann R. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (1), 1973)

The cell Cd(Hg) | CdCl2 | AgCl—Ag has been used to obtain the standard molar free energies of transfer, AGt, of cadmium chloride from water to 10 %, 20 % and 40 % (w/w) mcthanol-water mixtures. Cadmium chloride is a weak ...
Temperature Effect on Stearic Acid Monolayers on Water

Casilla, R.; Cooper, W. D.; Eley, D. D. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (2), 1973)

Measurements are described for the force-area curve of stearic acid on pure water at temperatures of 1.6, 3.0, 5.0, 10.0 and 20.0°C. The Ao values for both solid and liquid films increase with tempera ture at the same ...
Metal-ion Catalyzed Decarboxylation of Oxaloacetic Acid

Ito, Hiroo; Kobayashi, Hiroshi; Nomiya, Kenji (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (1), 1973)

Decarboxylation of oxaloacetic acid is accelerated by hydrated metal ions. The thermodynamic data of activation AG*, AH* and AS* for the rate-determining process were determined. The main species involved in autodecarboxylation ...
Heat of Dilution of Aqueous Solutions of Polyacrylates

Ise, Norio; Mita, Kazuei; Okubo, Tsuneo (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (1), 1973)

The heats of dilution (AH) of aqueous solutions of polyacrylates having various gegenions, i.e., sodium and tetra-alkylammonium (alkyl = methyl, ethyl, n-propyl and n-butyl), were measured. The (A//) value of the sodium ...
Homogeneous Catalysis by Pt(Il)-Sn(II) Chloride Complex: Part 2.—Mechanism of the Isomerization of n-Butenes

Hirabayashi, Kazuo; Saito, Shuji; Yasumori, Iwao (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (5), 1972)

The mechanism of the isomerization of n-butencs catalyzed by a methanolic solution of Pt(II)- Sn(II) chloride complex has been studied by kinetic, mass-spcctromctric and microwave-spectro scopic measurements. This ...
Radiation Chemistry and Photochemistry of Oxychlorine Ions: Part 3.—Photodecomposition of Aqueous Solutions of Chlorite Ions

Buxton, G. V.; Subhani, M. S. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (5), 1972)

The steady state and flash photolysis of aqueous solutions of chlorite ion has been investigated. The primary photodecomposition reactions are ClO–2[graphic omitted]ClO–+ O (a), ClO–2[graphic omitted]ClO–+ O–(b), ClO–2[graphic ...
Kinetics of the Oxidation of Isopropanol by Aquocobalt (III) Ions in Aqueous Perchlorate Media

R., Varadarajan; C. F., Wells (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (3), 1973)

The kinetics of the oxidation of isopropanol by CoIIIaq have been studied using conventional and stopped-flow spectrophotometry in aqueous perchlorate media at high values for the ratio (initial [isopropanol])/(initial[CoIIIaq]) ...
Nucleation in Salt Solutions

V. A., Garten; R. B., Head (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (3), 1973)

The nucleation of a number of sparingly soluble electrolytes has been studied by a precipitation method and interfacial free energies have been estimated using vapour nucleation theory. The results have been correlated ...
Properties of Monolayers at the Air/Water Interface Part 2.—Effect of Temperature on the Double Layer and Water Dipole Contributions to the Surface Potential of Sodium Octadecyl Sulphate

Mingins, J.; Pethica, B. A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (3), 1973)

Accurate surface potentials measured by the radioactive electrode method are given for monolayers of sodium octadecyl sulphate spread on several aqueous sodium chloride solutions. In the temperature range 5–18°C, the ...
Radiation Chemistry and Photochemistry of Oxychlorine Ions: Part 2.—Photodecomposition of Aqueous Solutions of Hypochlorite Ions

Buxton, G. V.; Subhani, M. S. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (5), 1972)

The photodecomposition of alkaline aqueous solutions of hypochlorite ion has been investigated using steady state and flash photolysis techniques. At 365 nm the primary products are O(3P), O–, Cl and Cl– formed by the ...
Catalysis by Polyelectrolytes of the Ag+, Hg2+, and Tl3+ Induced Aquations of Co(NH3)5Br2 +

Ise, Norio; Matsuda, Yoshinobu (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (1), 1973)

The aquation reaction of Co(NH3)5Br2+ was studied kinetically with Ag’, Hg2 *, and Tl3+ as inducing cations. Addition of polyethylene sulphonate, polystyrene sulphonate and polyphosphate markedly enhanced the reaction. The ...
Ionization of Moderately Strong Acids in Aqueous Solution: Part 2—Further E.m.f. Studies of the Dissociation of the Bisulphatc Ion

Covington, A. K.; Dobson, J. V.; Srinivasan, K. V. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (1), 1973)

New measurements on the cell: Pt,H2 | Na2SO4, NaHS04, NaCl | AgCl | Ag have failed to substantiate the original measurements made by Hamer forty years ago and subsequently reanalyscd many times. The range of values for ...
Electrochemical Behaviour of Mixtures of V02 and H202 in 1 M HCIO4 on Mercury and Platinized Platinum

Nucci, L.; Guidelli, R. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1973, 69 (1), 1973)

The electrochemical behaviour of mixtures of VO2 and H2O2 in perchloric acid media was studied both on platinized platinum and on mercury. From voltammetric measurements on platinized platinum it was possible to show that ...
Radiation Chemistry and Photochemistry of Oxychlorine Ions: Part 1.—Radiolysis of Aqueous Solutions of Hypochlorite and Chlorite Ions

Buxton, G. V.; Subhani, M. S. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (5), 1972)

The radiolysis of aqueous solutions of ClO– and ClO–2 has been investigated using pulse and steady state methods. The absorption spectrum of ClO has been identified (λmax= 280 nm) and the complete reaction mechanism has ...

Now showing items 601-620 of 882

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