Journal Articles (before-1995): Recent submissions

  • Kinetic isotope effects: Part 7.—Ionization of (d)-phenylmethylacetophenone 
    Earls, D. W.; Jones, J. R.; Rumney, T. G. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (5), 1972)
    Measurements are reported on the hydroxidc-catalyzed ionization of (d)-phenylmethylaceto- phenone in the presence of varying amounts of dimethyl sulphoxide. The kinetic hydrogen isotope effect (kn/kr) increases with ...
  • Adsorption of neopentane on tungsten and palladium films 
    Ross, J. R. H.; Roberts, M. W.; Kemball, C. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (5), 1972)
    The adsorption of neopentane has been studied on tungsten and on palladium films; allied experiments were carried out with methane (W, Pd) and with propane (W). The evolution of hydrogen from each gas/metal system was ...
  • Infra-red studies of rutile surfaces: Part 3.—Adsorption of water and dehydroxylation of rutile 
    Jones, P.; Hockey, J. A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (5), 1972)
    There are two forms of adsorbed molecular water present on rutile surfaces under ambient conditions. One form is hydrogen bonded to surface hydroxyl ions and the other is held as a coordinating ligand to surface cations.3 ...
  • Infra-red study of the surface properties of rutile: Deuterium exchange, carbon dioxide and but-1-ene adsorption 
    Jackson, P.; Parfitt, G. D. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (5), 1972)
    Deuterium exchange with surface hydroxyl groups on rutile was studied using D2 and D2O; the former completely exchanges at 300°C (2 h) with evidence for surface reduction, while the latter does not achieve complete exchange ...
  • Effect of silica surface dehydroxylation on adsorption of aromatic hydrocarbons from solution in n-alkanes 
    Eltekov, Yu. A.; Khopina, V. V.; Kiselev, A. V. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (5), 1972)
    The adsorption of a series of aromatic hydrocarbons from solution in saturated hydrocarbons on hydroxylated and dehydroxylated silica surface has been investigated. Dehydroxylation of silica surface sharply diminishes the ...
  • Reactions of trifluoromethyl radicals with organic halides: Part 7.—Chloro- and fluorochloro-ethanes 
    Quick, L. M.; Whittle, E. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (5), 1972)
    The reactions of CF3 radicals with the compounds C2H5Cl, CH2ClCH2Cl, CH3CHCl2, CH3CCl3, CHCl2CHCl2, CF3CH2Cl, CF3CHCl2, CF3CCl3, CF2ClCFCl2 and CH3CF2Cl were studied. Arrhenius parameters were measured for abstraction of ...
  • Reactions of CF3 radicals with benzotrifluoride and the C—H bond strength in C6H5CF3 and C6H6 
    Bérces, T.; Márta, F.; Szilágyi, I. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (5), 1972)
    The reactions of CF3 with benzotrifluoride (BTF) were studied at 1029, 1070 and 1132 K. The RCF3H/R½C2F6[BTF] ratio was found to decrease with increasing benzotrifluoride pressure, which was interpreted as simultaneous ...
  • Electrical Conductance in Molten KC1, KI, TH and KI-TII 
    Buckle, E. R.; Tsaoussoglou, P. E. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (6), 1972)
    Specific conductance, x, in the ionic melts KC1, KI, Til and KI-T1I was measured by the a.c.- dispersion plateau method. The variation of z with temperature (T, C) in the pure melts is given to 0.1 % by empirical equations ...
  • Reactions of Group 3 Metal Alkyls in the Gas Phase: Part 9.—Addition of Propene to Trimethylaluminium 
    Egger, Kurt W. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (6), 1972)
    The thermal gas phase reaction of propene with monomeric trimethylaluminium has been studied at temperatures from 455 to 549 K using a static reaction system and Teflon coated reaction vessels. Initial propene pressures ...
  • Liquid State Thermal Conductivity of n-Paraffin Hydrocarbons 
    Kandiyoti, R.; McLaughlin, E.; Pittman, J. F. T. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (5), 1972)
    New measurements on the thermal conductivities of n-butane, n-pentane, n-heptane and n-octane in the liquid state at saturation pressure are reported. The results are discussed in terms of the dependence of thermal ...
  • Kinetics and Thermodynamics of the Formation of the Donor Acceptor Complex of Tetracyanoethylene with Hexamethyl benzene in Solution, by a Microwave Temperature-jump method 
    Caldin, E. F.; Crooks, J. E.; O’Donnell, D.; Smith, D.; Toner, S. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (5), 1972)
    The rate of formation of the donor-acceptor complex between tetracyanoethylene and hexamethylbenzene, in 1-chlorobutane as solvent, has been measured at –83°C by a temperature-jump method using microwave heating. Equilibrium ...
  • Oxygen Electrode Reaction: Part 2.—Behaviour at Ruthenium Black Electrodes 
    Burke, L. D.; O’Meara, T. O. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (5), 1972)
    Charging curves and cyclic voltammetry were used to investigate the nature of the interaction of oxygen with an active ruthenium surface. Rather vigorous corrosion was observed under highly anodic conditions and the products, ...
  • Thermodynamics of Adsorption of a Series of Related Organic Molecules on Graphite and a Carbon Black: Part 1—Heat of Adsorption 
    Dollimore, D.; Heal, G. R.; Martin, D. R. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (5), 1972)
    The isosteric heat of adsorption for a structurally related series of organic adsorbates has been determined at varying degrees of surface coverage on a graphite and a well-characterized carbon black using a gas-chromatographic ...
  • Absorption of Hydrogen by Palladium-Platinum Alloys under High Pressures of Hydrogen Gas 
    Baranowski, B.; Lewis, F. A.; Majchrzak, S.; Wisniewski, R. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (5), 1972)
    Effects of the absorption of hydrogen on the electrical resistance of a scries of palladium-platinum alloys have been studied at pressures of hydrogen up to 24 000 atm at 25°C. Effects indicative of significant absorption ...
  • Dissociation Equilibrium of Nitroform in Mixtures of Polar Solvents Studied by Pulse Radiolysis 
    Chaudhri, Shamim A.; Asmus, K. D. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (6), 1972)
    The dissociation equilibrium C(NO2)3H ; C(NO)2,+H sol and the related kinetics have been studied for mixtures of polar solvents. The dissociation constant is found to be essentially controlled by the rate constant for the ...
  • Adsorption of Xenon on Films of Gold, Aluminium and Silver 
    Bruce, Linda A.; Sheridan, Margaret H. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (6), 1972)
    A comparative study of the adsorption of xenon on films of gold, aluminium and silver prepared in an ultra-high vacuum system is reported. Sets of isotherms in the temperature range 77-90 K have been measured for two ...
  • Use of p-Nitroaniline to Determine Protonation Equilibrium Constants of Oxygen-containing Molecules in Aqueous Solution 
    Wells, C. F. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (6), 1972)
    Thccriticismscontaincd in a recent paper 1 of the interpretation in termsof protonation equilibria 2,3 involving (H20)4 Haq+ of the changes in optical density of acidic solutions of p-nitroanilinc on addition of organic ...
  • Flash Photolysis of Naphthalenedicarboxylic Anhydrides 
    Lohmann, J. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (5), 1972)
    The naphthalenedicarboxylic anhydrides (1,2-, 2,3- and 1,8-) do not decompose upon irradiation in a polymer-matrix. Their triplet-states are observed in emission and absorption. The half-lives of the triplet-states are ...
  • Adsorption of Krypton on Alkali Halide Crystals: Part 1.—Theory 
    Takaishi, T. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (5), 1972)
    The adsorption of krypton on alkali halide crystals with the NaCl-type structure has been studied theoretically in order to analyze detailed experimental data given in a succeeding paper. Emphasis was placed on the mutual ...
  • Mechanistic Conclusions from the Curvature of Solvent Isotope Effects 
    Albery, W. J.; Davies, M. H. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (1), 1972)
    The variation of kx/k0 with x the atom fraction of D in H2O/D2O mixtures is generally curved. Models of the transition state to fit this curve are described by fractionation factor theory. Nine general conclusions are drawn ...

Search DSpace


Advanced Search

Browse

My Account