Journal Articles (before-1995): Recent submissions

  • Tedder, J. M.; Walton, J. C.; Winton, K. D. R. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (1), 1972)
    The light-induced addition of perfluoropropyl iodide to fluoro-ethylenes in the gas phase C3F7·+ RCH[double bond, length as m-dash]CH2→ C3F7CH2ĊHR (2) has been studied, and activation parameters determined by a competitive ...
  • Cathro, W. S.; Mackie, J. C. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (1), 1972)
    The chemical relaxation of shock-heated water vapour in 8–10 % mixtures with argon has been studied over a temperature range of 2000–2400 K. The growth of H atom concentration was followed by introducing LiOH particles ...
  • Kunz, C. O.; Wright, A. N. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (1), 1972)
    Irradiation of C4Cl6 vapour at 0.135 Torr with u.-v. light produces a highly carbonaceous polymeric film on illuminated surfaces. The rate of film formation is linearly dependent on light intensity and exhibits an overall ...
  • Preist, T. W. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (4), 1972)
    where A is an atom and M* and M*' are differently excited states of a molecule. This process is particularly relevant to the discussion of the collisional ionization rates in flame systems, and estimates of the cross-sections ...
  • Tiddy, G. J. T. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (4), 1972)
    Proton and deuteron relaxation times have been measured for water in the lamellar phase of the ammonium perufloro-octanoate + water system. Changes in T1 and T2 with variation of temperature and composition have been ...
  • Yamamoto, Mikio; Nakamura, Yoshio; Shimoji, Mitsuo (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (1), 1972)
    The viscosities of solutions of Li and LiCl in methylamine have been measured with an Ubbelohde-type viscometer from –50 to –6.7°C as a function of concentration of the solutes. The observed viscosities increase with ...
  • Nauta, H; Huis, C. van (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (4), 1972)
    The solvation of electrons in pure hexamethylphosphoric triamide (HMPT) has been observed by transient infra-red absorption following pulse radiolysis. Addition of biphenyl (ϕ2) and anthracene (A) provided evidence of ...
  • Ferguson, K. C.; Whittle, E. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (4), 1972)
    The overall reactions CF3Br + HBr → CF3H + Br2, C2F5Br + HBr → C2F5H + Br2 have been studied competitively over the range 195–476°C. Reaction was initiated by bromine atoms generated both thermally and photochemically. ...
  • Parkes, David A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (4), 1972)
    A drift tube and mass filter have been used to measure the rates of some O– negative ion molecule reactions, thought to be important in the radiolysis of carbon dioxide. Measurements of the clustering reaction O–+ CO2+ M ...
  • Parkes, David A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (4), 1972)
    The reactions between O–, formed by dissociative attachment to oxygen, and H2, D2, CH4, C2H6, C2H4 and C2H2 have been studied using a drift tube and mass filter. Gas densities ranged over a factor of five about 1017 molecule ...
  • Tiddy, G. J. T. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (4), 1972)
    The phase diagram of ammonium perfluoro-octanoate+water has been determined over the temperature range 298-373 K using a polarizing microscope. Low angle X-ray scattering measurements confirmed the existence of one isotropic ...
  • Plunkett, T. J.; Clarke, J. K. A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (4), 1972)
    The hydrogenolysis of ethane has been studied on a series of copper-nickel film catalysts at temperatures greater than 320°C, where the alloys are single-phased. A gradual fall in activity with nickel content is found with ...
  • Elrick, D. E.; Smiles, D. E.; Wooding, R. A. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (4), 1972)
    A new technique for measuring diffusion coefficients utilizing two thin porous membranes separated by a spacer of known cross-sectional area and thickness is presented. The method permits absolute measurements of diffusion ...
  • Clark, K. P.; Stonehill, H. I. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (4), 1972)
    When aqueous solutions of anthraquinone-2-sodium-sulphonate (D) are photolyzed the quinone becomes hydroxylated and (in the absence of oxygen) reduced. On the basis of the kinetics of the photohydroxylation in air or oxygen ...
  • Byrne, M.; Kuhn, A. T. (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (2), 1972)
    The kinetics of the cathodic reduction of ethylene on platinum and ruthenium in aqueous acid and alkali solutions are reported. The reduction proceeds according to the stoichiometric equations C2H4+ 2H++ 2e → C2H6(acid), ...
  • Borrell, Peter; Cervenka, A (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (2), 1972)
    Additional results on the effect of additives on the product yields in the vapour-phase photolysis of trans-but-2-ene and cis-pent-2-ene are reported. They confirm, extend and reconcile our previous results with those of ...
  • Hackett, Peter A.; Phillips, David (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (2), 1972)
    The quenching of the excited singlet and triplet states of 1,3-dichloro-tctrafluoroacctone by various molecules is reported. Correlation of results with decomposition data indicate that for 310 nm excitation, some 25-30 % ...
  • Hackett, Peter A.; Phillips, David (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (2), 1972)
    Quantum yields of S1→ T1 intersystem crossing in 1,3-dichloro-tetrafluoroacetone have been measured using the technique of biacetyl sensitization. The vibrationally-relaxed singlet state of the molecule intersystem crosses ...
  • Hackett, Peter A.; Phillips, David (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (2), 1972)
    The variation of the fluorescence quantum yield of 1,3-dichloro-tctrafluoroacetone with pressure of ketone and added gases is reported for several different exciting wavelengths. Fluorescence decay times were also measured. ...
  • Barker, R (Journal of the Chemical Society : Faraday Transaction - I. The Chemical Society, London. 1972, 68 (2), 1972)
    Ammonia is decomposed in a microwave discharge to give hydrazine, nitrogen and hydrogen. Product yields have been measured as a function of ammonia flow-rate, pressure, power input, temperature and added allyl alcohol and ...

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